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Tytuł:
Lignite cleaning in NaCl solutions by the reverse flotation technique
Autorzy:
Zhang, H.
Liu, Q.
Powiązania:
https://bibliotekanauki.pl/articles/110516.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
lignite
reverse flotation
NaCl
kinetics
coal preparation
Opis:
A cleaning possibility of low (BD) and high ash content (IM) lignites in NaCl solutions using a reverse flotation technique was studied. Preliminary test results indicated that BD lignite cannot be cleaned effectively in the traditional manner because gangue was floated first rather than a combustible material. Further studies indicated that the lignite cleaning in NaCl solutions using the reverse flotation technique is possible. However, a large quantity of dodecyl amine hydrochloride (DAH) was required. A lower ash content in a concentrate can be obtained by addition of NaCl. A concentrate yield can be im-proved by addition of starch. Under the test conditions, for BD lignite with the ash content in the feed 15.19%, the ash content in the concentrate 11.44% and the concentrate yield 67.38% were obtained. Similarly, for IM lignite with the ash content in the feed 57.40%, the ash content in the concentrate 32.90% and the concentrate yield 25.08% were obtained. The flotation rate constant k and maximum ash recovery ε∞ significantly increased with the NaCl concentration.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 695-706
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental study on electrokinetic of kaolinite particles in aqueous suspensions
Autorzy:
Min, F.
Zhao, Q.
Liu, L.
Powiązania:
https://bibliotekanauki.pl/articles/110918.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
kaolinite
zeta potential
pH
immersion time
electrophoresis
Opis:
Influence of aqueous phase properties and process parameters on kaolinite particle zeta potential was quantified by electrophoresis experiments. The results indicated that pH strongly altered the zeta potential of kaolinite and it decreases at the beginning and then increases in the range of pH = 2–13. The activity of different cations changes the zeta potential and has the following tendency of Al3+ > Ca2+ > Mg2+ > Na+ and the zeta potential increases due to heterocoagulation of different mineral particles in suspension. It was found that the zeta potential of kaolinite particles increases after the suspension was stirred and decreases at the beginning, and then increases with soaking time. The FTIR results showed that the zeta potential takes into account ion adsorption and the change of Si–O, Al–O and Al–OH groups on the surface of the kaolinite particles.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 2; 659-672
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oil-assisted flotation of fine hematite using sodium oleate or hydroxamic acids as a collector
Autorzy:
Li, H.
Liu, M.
Liu, Q.
Powiązania:
https://bibliotekanauki.pl/articles/109749.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
hematite
sodium oleate
kerosene
Batch Flotation
Octyl hydroxamic acid
Oleoyl hydroxamic acid
Opis:
Micro-flotation and batch flotation tests were carried out on fine (-20 µm) hematite to investigate the influences of non-polar oil when sodium oleate, octyl hydroxamic acid, or oleoyl hydroxamic acid was used as a collector. Both micro-flotation and batch flotation tests were performed using single hematite mineral and/or artificial mixed minerals (hematite:quartz = 1:1), and kerosene was utilized as the neutral oil. The experimental results showed that the addition of a kerosene emulsion benefited hematite recovery in the micro-flotation tests where a froth layer did not exist. In the batch flotation where a froth layer existed, kerosene behaved differently when used in conjunction with the three collectors. Kerosene helped improve the batch flotation when sodium oleate or oleoyl hydroxamic acid was used as a collector. However, it reduced concentrate weight yield, grade and recovery to a noticeable extent when octyl hydroxamic acid was used as a collector, especially at low dosages. In addition, single hematite batch flotation kinetics tests coupled with water recovery measurement were carried out to study the role of kerosene at different collector dosages. It was observed that water drainage and the resulting froth destabilization by kerosene was dominant at low collector dosages, especially in the flotation using octyl hydroxamic acid. At higher collector dosages, the water drainage and froth destabilization effect by kerosene was possibly counter-balanced by the higher hematite surface hydrophobicity and bubble surface tension gradient, which led to more stable froth layer.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 4; 1130-1145
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pre-concentration of graphite and LiCoO2 in spent lithium-ion batteries using enhanced gravity concentrator
Autorzy:
Zhu, X,-N.
Tao, Y.-J.
He, Y.-Q.
Zhang, Y.
Sun, Q.-X.
Powiązania:
https://bibliotekanauki.pl/articles/109609.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
spent lithium-ion batteries
electrode material
resource utilization
pre-concentration
enhanced gravity concentrator
Opis:
The pre-concentration of electrode material of spent lithium-ion battery has great significance on the resource utilization and environmental protection. The feasibility of separation of graphite and LiCoO2 based on density difference using the enhanced gravity concentrator was verified in this paper. Combustion characteristics of LiCoO2 and graphite were used to propose a simple evaluation index of separation efficiency. Separation tests were carried out to specify the influence of operating parameters on the separation efficiency. Moreover, the effect of particle size on the separation performance was studied. Combustion characteristics results showed that mass loss of graphite was much greater than that of LiCoO2. Thus, mass loss were used to evaluate the purity of product. Effective separation of graphite and LiCoO2 was achieved by the enhanced centrifugal separator. Separation results showed that increasing centrifugal force decreased the overflow yield and increased the graphite content of the overflow stream. In addition, yield of overflow grew an increase in fluidization water pressure, while the purity of graphite in overflow decreased. The effect of particle size on the separation efficiency was also significant, the separation efficiency decreased with the decreasing of particle size.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 2; 293-299
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, structure and performance of calcium silicate ion exchangers from recycled container glass
Autorzy:
Coleman, N. J.
Li, Q.
Raza, A.
Powiązania:
https://bibliotekanauki.pl/articles/109960.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
tobermorite
sorbent
hydrothermal synthesis
cullet
recycling
ion exchange
Opis:
Numerous technical, economic and societal factors limit the recycling of waste soda-lime-silica glass back into the primary production process and accordingly alternative applications for this material are sought. This study demonstrates that waste soda-lime-silica container glass is a suitable feedstock material for the production of tobermorite, a calcium silicate cation exchanger. Tobermorites were synthesised at 100 °C from stoichiometric mixtures of container glass and lime under alkaline hydrothermal conditions. Increasing concentrations of sodium hydroxide (between 1.0 M and 4.0 M) in the reaction mixture promoted the formation and crystallisation of tobermorite, and also resulted in greater fragmentation of the silicate chains along the b-axis direction. The maximum removal capacities of these tobermorite specimens for Cd2+ (441 mg g-1) and Zn2+ (122 mg g-1) compared well with those of other waste-derived sorbents. Superior Cd2+- and Zn2+-uptake capacities and kinetics were observed for the least crystalline tobermorite specimen, indicating that stacking defects facilitate the transport and exchange of cations within the lattice.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 1; 5-16
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synergistic effect of a mixture of dodecylamine and kerosene on separation of magnetite ore
Autorzy:
Liu, A.
Fan, M.-Q.
Li, Z.-H.
Powiązania:
https://bibliotekanauki.pl/articles/109849.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
DDA-kerosene
magnetite ore
quartz
flotation
Opis:
In this study, it was discovered that a mixture of dodecylamine (DDA)-kerosene demonstrated a stronger collecting ability for pure quartz and higher selectivity for magnetite ore. The relationship between the DDA-kerosene composition and mineral flotation performance on reverse flotation of magnetite ore was investigated. The results showed that floatability of the floating material increased when the DDA consumption increased. Specifically, during flotation, the fine particles (-0.074 mm fraction) selectively floated with DDA-kerosene. The difficult to float coarser particles (+0.074 mm fraction) with high content of quartz, required higher DDA dosage. However, higher DDA input during the flotation process did not necessarily yield better outcomes. The best results were obtained for 40/60 amine-to-oil ratio, as the quartz floated markedly with smaller magnetite loss and the flotation behavior was superior to pure DDA. Magnetite concentrates with 1.83% SiO2 and 71.04% Fe were produced using 120 g/Mg of DDA-kerosene (WDDA=40%).
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 647-661
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of synergistic effect between dodecylamine and sodium oleate on improving the hydrophobicity of fluorapatite
Autorzy:
Cao, Q.
Luo, B.
Wen, S.
Cheng, J.
Powiązania:
https://bibliotekanauki.pl/articles/109587.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
fluorapatite
hydrophobicity
synergistic effect
mixed collector
Opis:
The influence of synergistic effect between dodecylamine (DDA) and sodium oleate (NaOl) on the hydrophobicity of fluorapatite (FA) was investigated with contact angle, surface tension, XPS and zeta potential studies. The role of pH and the mixing ratio of surfactants on the synergistic behavior were considered. Basing on the contact angle results the suitable pH for the NaOl-DDA mixture was pH 9.5. A further study indicated that the 3:7 DDA-NaOl mixtures could notably improve the contact angle comparing to that only with DDA or NaOl. In the solution of this mixture, the DDA cation and DDA molecule both adsorb at the FA surface as revealed by the XPS spectra results. The zeta potential analysis further suggested that the adsorption of oleate at the FA surface was also improved. The presence of DDA cation and DDA molecule was expected to result in a uniform packing of surfactants at the FA surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 1; 42-55
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Role of sodium hexametaphosphate in flotation of a nickel ore
Autorzy:
Feng, B.
Wang, P.
Lu, Y.
Feng, Q.
Powiązania:
https://bibliotekanauki.pl/articles/109887.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
nickel ore
lizardite
flotation
concentration process
pentlandite
Opis:
In this work, a role of sodium hexametaphosphate (SHMP) in the flotation performance of a nickel ore was studied and mechanism was discussed in detail. The results showed that the presence of lizardite interferes with the flotation performance of pentlandite. The adsorption of SHMP at the lizardite/solution interface and the removal of magnesium ions from lizardite surface overcompensated the positive charge on the lizardite particle, and made its zeta potential negative. The interaction between lizardite and pentlandite changed from attractive to repulsive in the presence of SHMP. Thus, the addition of SHMP made the mixed sample of pentlandite and lizardite more dispersed, and significantly reduced the adverse effect of lizardite on the flotation of pentlandite. However, when the content of lizardite in the mixed ore was increased, the effect of SHMP weakened. Therefore, in flotation of a nickel ore containing a large amount of lizardite (46% w/w), SHMP usage is not suitable at the roughing stage due to the fact that lizardite in the pulp will consume most of the SHMP, and hence the removal of lizardite slimes from pentlandite surface become impossible. Based upon the results, SHMP usage is found to be suitable at the cleaning stage to improve the grade of concentrate.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 170-181
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Recovery mechanisms of sericite in microcrystalline graphite flotation
Autorzy:
Li, H.
Ou, L.
Feng, Q.
Chang, Z.
Powiązania:
https://bibliotekanauki.pl/articles/110055.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
microcrystalline graphite
sericite
flotation
entrainment
entrapment
Opis:
Sericite is the main contaminant of concentrate in commercial microcrystalline graphite ore flotation. It was necessary to identify its recovery mechanisms so that the appropriate solution can be selected. In this study, the influence of sericite on flotation selectivity of microcrystalline graphite ore and its recovery mechanisms were investigated. Artificial mixtures flotation test suggested that sericite seriously reported into concentrate leading to poor flotation selectivity of microcrystalline graphite ore. However, the aggregation/dispersion behavior of artificial mixtures indicated that a large repulsive energy existed between sericite and microcrystalline graphite particles at pH 7.4, and sericite was not likely to report into graphite concentrate by slime coating. The results obtained from contact angle measurements and a technique of Warren showed that the floated sericite reached the froth via a combination of both entrainment and entrapment mechanisms, not via true flotation.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 387-400
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The surface features of activated stibnite surface with copper or lead ion
Autorzy:
Cao, Q.
Huang, Y.
Zou, H.
Wen, S.
Powiązania:
https://bibliotekanauki.pl/articles/110393.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
stibnite
flotation
activation
active layer
Opis:
Cu2+ and Pb2+ are widely used as activators for the flotation of stibnite. In this work, by the treatment of Cu2+ or Pb2+, the activation product and the thickness of activation layer on the stibnite surface were both investigated. Based on the flotation results, zeta potential analysis and X-ray photoelectron spectroscopy (XPS) study, it was found that Cu2+ was reduced to Cu+ at the stibnite surface and a layer of Cu2S was formed at the surface. While, a PbS layer presenting at the stibnite surface is responsible for the activation flotation of stibnite with Pb2+. Time of flight secondary ion mass spectrometry (TOF-SIMS) analysis further implies that, when stibnite was activated with 5×10-5 mol/dm3 of CuSO4 or Pb(NO3)2, the thickness of Cu2S layer on the Cu-activated surface was close to 2.7 nm, while the thickness of PbS layer was about 1.8 nm on the Pb-activated surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 763-770
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of grinding characteristics in high-pressure grinding roller (HPGR) and cone crusher (CC)
Autorzy:
Liu, L.
Tan, Q.
Li, W.
Lv, L.
Powiązania:
https://bibliotekanauki.pl/articles/951829.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
HPGR
grinding kinetics
grinding technical efficiency
ultra-crushing
classified grinding
Opis:
We comparatively studied the ball mill grinding characteristics of comminuted hematite products using a high-pressure grinding roll (HPGR) and a conventional cone crusher (CC). The major properties, including grinding kinetics and technical efficiency (Et), were investigated. The parameters in m-th order grinding kinetics were analyzed, and grinding specific rates were visualized. Ore particles experienced three inherent stages in ball grinding mills, that is i) rapid grinding of coarse fraction, ii) dynamic grinding of medium size fraction, and iii) single grinding of medium size fraction. Particles with size -0.043+0.031 mm were used into dynamic grinding stage earlier than particles -0.105+0.043 mm, and then over-grinding of fines occurred easily. Compared with CC products, HPGR products had significantly shorter turning time points in three breakage stages, implying that HPGR products were ground faster with earlier occurrence of fines over-grinding. HPGR products gave lower Et at a decreasing rate than the CC products for -2.0 mm and -0.5 mm feeds. Then, it showed a slightly higher value of Et for -2.0+0.5 mm feed. This indicated that fines over-grinding in HPGR full-size products were more serious under the condition of coarse grinding, whereas the efficiency was higher, and over-grinding weakened significantly in HPGR coarse products because of screening-out fines.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1009-1022
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Relationship between flotation and Fe/Mn ratio of wolframite with benzohydroxamic acid and sodium oleate as collectors
Autorzy:
Yang, S.
Feng, Q.
Qiu, X.
Gao, Y.
Xie, Z.
Powiązania:
https://bibliotekanauki.pl/articles/109666.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
wolframite
flotation
collector mixture
benzohydroxamic acid
sodium oleate
Opis:
Several studies revealed that flotation of wolframite changes with different Fe/Mn ratios, but they did not reach a consensus. This relationship in the presence of benzohydroxamic acid (BHA) and sodium oleate (NaOl) as collectors was studied in this paper through comparison of probability distribution curve of wolframite with different Fe/Mn ratios between the raw ore and the flotation concentrate, the pure mineral flotation and solution chemistry of flotation. The results showed that wolframite with high Fe/Mn ratio showed higher flotation with BHA as a collector while the flotation behavior of wolframite was completely opposite with NaOl as a collector. Besides, the calculations of chemical equilibrium in the solution were plotted as ΔG°-pH graphs. The results revealed that the flotation of wolframite may be determined by the interaction between BHA and ferric(II) ion or between NaOl and manganous ion. From the perspective of collector mixture, the results also explain the high collecting capability of the BHA/NaOl collector mixture, which can be defined as “functional complementation”.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 2; 747-758
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of pH on surface characteristics and flotation of sulfidized cerussite
Autorzy:
Feng, Q.
Wen, S.
Zhao, W.
Liu, J.
Liu, D.
Powiązania:
https://bibliotekanauki.pl/articles/110234.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cerussite
sulfidization
excessive sulfide ions
pH
surface analysis
Opis:
The effect of pH on surface characteristic and flotation of sulfidized cerussite was studied by micro-flotation tests, dissolution experiments, scanning electron microscopy (SEM) energy dispersive spectrometer (EDS), and X-ray photoelectron spectroscopy (XPS). The micro-flotation tests demonstrated that higher recovery of cerussite was achieved in acidic solutions than that in alkaline solutions. Despite the addition of high collector concentrations, cerussite flotation did not improved in alkaline solutions. The dissolution performance of sulfide-treated cerussite at different pH values indicated that the lead sulfide layer on the surface of sulfide-treated cerussite could exist in acidic solutions and it was more stable at acidic pH than in alkaline solutions. This finding was proved by the SEM-EDS and XPS analyses.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 676-689
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of leaching kinetics of cerussite in sodium hydroxide solutions
Autorzy:
Feng, Q.
Wen, S.
Wang, Y.
Zhao, W.
Deng, J.
Powiązania:
https://bibliotekanauki.pl/articles/110621.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cerussite
sodium hydroxide
leaching
kinetics
activation energy
Opis:
The leaching kinetics of cerussite in alkaline medium was investigated with respect to experimental variables such as sodium hydroxide concentration, temperature, particle size and stirring speed. The results showed that leaching reagent concentration and reaction temperature exerted significant effects on the extraction of lead, whereas particle size and stirring speed exhibited a relatively moderate effect on the leaching rate. The leaching process followed the kinetic law of the shrinking core model, and the dissolution rates were controlled by the surface chemical reaction with an apparent activation energy value of 43.79 kJ/mol. A corresponding dissolution kinetic equation was also proposed to describe the dissolution reaction. The results indicated that sodium hydroxide could be used as an effective leaching reagent for extracting lead from cerussite.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 491-500
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanisms for the improved flotation of inherently hydrophobic graphite in electrolyte solution
Autorzy:
Lai, Q.
Liao, Y.
Liu, Z.
He, Y.
Zhao, Y.
Powiązania:
https://bibliotekanauki.pl/articles/110761.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
graphite
low-grade
electrolyte
Opis:
It is well documented that unavoidable ions in a pulp such as Mg2+, Ca2+, and K+ have a significant effect on the interaction for particles, especially for flotation of metallic sulfide minerals and clay minerals. In this study, the effect of electrolytes on the flotation of inherently hydrophobic mineral-graphite was studied. It was found that the zeta potential showed a dramatic decrease, and the reagent adsorption capacity of mineral enhanced in the present of electrolytes. The possible mechanism responsible for improved recovery was investigated by electrokinetic, surface tension and ions adsorption tests. It is likely that the hydrophobic force is stronger than the electrostatic force due to the reduced potential of graphite. This might be in favor of the formation of hydrophobic oil film leading to an increase in the graphite floatability. The experiments provided a new spectacle to study inherently hydrophobic mineral processing with electrolyte solution.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 944-954
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł

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