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    Wyświetlanie 1-5 z 5
    Tytuł:
    Study on the mechanism of the difference in flotation performance between fine-grained crystalline SiO2 and amorphous SiO2
    Autorzy:
    Ma, Saisai
    Li, Jie
    Wang, Yonglun
    Wei, Bangqi
    Powiązania:
    https://bibliotekanauki.pl/articles/27323646.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation separation
    heteromorphism
    infrared spectrum calculation
    DLVO theory
    Opis:
    Numerous minerals found in nature contain silica, including quartz, cristobalite, opal, etc. They have the same chemical composition but different crystal structures, and this phenomenon is called “polymorphism” in mineralogy. For these polymorphic and multi-like minerals, in the flotation process, will it directly or indirectly affect the flotation effect. Based on this, this study mainly explores the difference between crystalline SiO2 and amorphous SiO2 in flotation. In this study, two crystal forms of SiO2 were subjected to flotation and adsorption capacity tests. FTIR, other test techniques, the chemical calculation of the flotation solution, and the theoretical calculation of the DLVO can all be used to provide an explanation. Finally, in the flotation experiment, the feedbacks of the two minerals to the change of the pH value of the pulp and the change of the concentration of the reagent are different. Through the comprehensive analysis of the adsorption capacity test and semi-quantitative calculation of the infrared spectrum, the adsorption capacity of crystalline SiO2 to drugs is about 23% higher than amorphous SiO2. Furthermore, during the flotation process, the amorphous SiO2 particles will agglomerate together and entrain into the foam through, resulting in concentrate pollution. So amorphous SiO2 will undoubtedly increase the difficulty of flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174567
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of pH value on effectiveness of biopolymer-based treatment of bauxite mine slurry
    Autorzy:
    Meng, Jian Ping
    Li, Shanmei
    Yan, Rongtao
    Wei, Changfu
    Powiązania:
    https://bibliotekanauki.pl/articles/24085778.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    pH
    biopolymer
    xanthan gum
    bauxite mine slurry
    flocculation
    Opis:
    Effective dehydration and flocculation of mine slurries or sludge is important for nonferrous metal industries and environmental engineering. However, the mechanisms for the flocculation of slurry remain largely unclear. This paper presents the results of a series of flocculation tests, which was conducted on the slurry suspensions treated by xanthan gum (flocculant) at different pH values. It is shown that the settlement rate of mine slurry particles can be accelerated by adding xanthan gum, and the maximum sedimentation rate was obtained at a pH value of 5.9, and the final volume of flocs is significantly increased due to the addition of the flocculant. In addition, the settlement rates of xanthan gum-treated slurry suspensions at the pH values of 3, 5 and 7 decrease slightly compared with the reference slurry suspensions with pH=5.9, and the slurries remained stable as suspensions at the pH value of 9 and 11. The zeta potential measurement and SEM image analysis show that flocculation occurs primarily due to electrostatic attraction between slurry particles and the flocculants, and the bridging effect between the carboxylic groups in the side chains of xanthan gum molecule and the suspension particles.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 3; art. no. 167949
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Enhanced effect of fine magnetite on the flotation performance of fine hematite in sodium oleate system
    Autorzy:
    Pei, Bin
    Luo, Ximei
    Yang, Wen
    Wei, Dayong
    Li, Chao
    Wang, Yunfan
    Powiązania:
    https://bibliotekanauki.pl/articles/2146908.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    magnetite
    hematite
    flotation
    magnetic aggregation
    Opis:
    In this work, the effect of magnetite with different particle sizes on the flotation performance of both coarse and fine hematite particles were investigated by using sodium oleate as a collector. The results showed that the magnetite particles with different particle sizes showed a negative effect on hematite (-106+45 μm) recovery, but the addition of magnetite with the same particle sizes as hematite during the direct flotation of -45 μm hematite was beneficial to improve the recovery of micro-fine hematite and the Fe grade of concentrate. The finer the magnetite particle was, the more obvious the agglomeration effect of hematite was. Therefore, the beneficial effect could be achieved by adjusting the particle sizes of particles. Moreover, sodium oleate was beneficial to promote the agglomeration of micro-fine magnetite and hematite. The results from the microscopic analysis, laser particle size analysis, and EDLVO calculation proved that there was an effective aggregation between fine magnetite and fine hematite particles, which increased the apparent size of hematite particles and the probability of the mineral particles adhering to bubbles, thus improving the hematite recovery.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 149673
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect and mechanism of depressant CK102 on flotation separation of fluorite and dolomite
    Autorzy:
    Li, Zhengyao
    Wang, Xuewen
    Xu, Chengyan
    Sun, Tichang
    Liu, Weiran
    Wei, Jinzhi
    Powiązania:
    https://bibliotekanauki.pl/articles/2146904.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    fluorite
    dolomite
    flotation
    depressant CK102
    adsorption
    Opis:
    For a low grade dolomite type fluorite ore in the Hebei province, it was observed that the depressant CK102, a mixture of sulfuric acid, sodium silicate and aluminum sulfate, can effectively inhibit the gangue mineral dolomite in the flotation of fluorite. However, the inhibition mechanism of the depressant is still unclear. In this paper, the flotation separation performance and underlying mechanism of CK102 inhibiting dolomite were investigated through mineral flotation tests, adsorption measurements, infrared spectroscopy, and X-ray photoelectron spectroscopy (XPS). The flotation results showed that the inhibition effect of CK102 on dolomite flotation was much more remarkable than that of fluorite flotation under optimum conditions. Adsorption measurements revealed that there was competitive adsorption between the depressant and collector and that the adsorption of the depressant CK102 prevented the collector modified sodium oleate from adsorbing onto the surface of minerals. The FT-IR and XPS results showed that the co-oxygen cross-linked component of the depressant CK102 chemisorbed on the surface of dolomite; the CaSiO3 precipitation was generated from the reaction of CK102 with Ca2+ groups on the surface of the dolomite; Al2MgO8Si2 precipitation was also generated from Mg2+ reacting with the sodium silicate and aluminum sulfate of CK102. The above adsorptions and reactions enhanced the hydrophilicity of the dolomite surface and the dolomite was effectively depressed.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 145796
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of the oxygen-containing functional group on the adsorption of hydrocarbon oily collectors on coal surfaces
    Autorzy:
    Wan, He
    Hu, Xianglin
    Luukkanen, Saija
    Qu, Juanping
    Zhang, Chonghui
    Xue, Jiwei
    Li, Hui
    Yang, Wei
    Yang, Shenghong
    Bu, Xianzhong
    Powiązania:
    https://bibliotekanauki.pl/articles/2146920.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    oxygen-containing functional groups
    hydrocarbon oily collectors
    molecular dynamics simulation
    coal surfaces
    adsorption
    Opis:
    The oxygen-containing functional groups (OCFG) on the coal surface affect the adsorption effect of hydrocarbon oily collectors (HOC). An investigation of the interaction between the HOC and OCFG in the absence and presence of water is conducive to understanding the effect of OCFG type on the adsorption of HOC on the coal surface. In this paper, FTIR analysis was used to analyze the OCFG type of coal surface. The adsorption behavior of HOC on different OCFG surfaces was investigated using molecular dynamics simulation. The results indicated the presence of OCFG such as -OH, -COOH, -C=O, and -COCH3 on the coal surface. In conditions without water, the effect of OCFG on HOC adsorption capability follows the order -COOH > -C=O > -OH > -COCH3. In an aqueous solution, the effect of OCFG on HOC adsorption capability follows the order -C=O>-COCH3>-OH>-COOH. Moreover, the hydrophilicity of OCFG is the key factor that affects the adsorption effect of HOC. In other words, the adsorption effect of HOC on the coal surface in an aqueous solution does not depend on the strength of the interaction between the OCFG and HOC in the absence of water, but on the hydrophilicity of the OCFG. The -COOH and -OH on the coal surface are not conducive to the adsorption of HOC onto the coal surface. Masking the -COOH and -OH of the coal surface is beneficial in improving the coal flotation performance with HOC as a collector.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 149937
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-5 z 5

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