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    Wyświetlanie 1-12 z 12
    Tytuł:
    Galvanic contacting effect of pyrite on xanthate adsorption on galena surface: DFT simulation and cyclic voltammetric measurements
    Autorzy:
    Ke, B.
    Chen, J.
    Li, Y.
    Chen, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/110904.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    adsorption
    DFT
    galvanic interaction
    pyrite surface
    galena surface
    cyclic voltammetric measurements
    Opis:
    The effect of galvanic interaction between pyrite and galena on xanthate adsorbing on the galena surface has been investigated by means of density functional theory (DFT) and cyclic voltammetric measurements. The calculated results show that differences in the contact site and contact distance between galena and pyrite can affect the intensity of the galvanic interaction, and the relationship between the intensity of galvanic interaction and the adsorption ability of xanthate on galena surface has been studied in detail. In general, the galvanic interaction between pyrite and galena surface can enhance the adsorption of xanthate on the galena surface. The adsorption energies of xanthate on the galena surface decrease with the decrease of contact distance, and when the contact distance is lower than 4 Å, the adsorption energies decrease significantly at Pb-Pb, Pb-S and S-S sites. In particular, at the contact distance of 3 Å, a sharp decrease of adsorption energy is observed at the Pb-Pb contact site; in this case, the negative shift of the Pb-S bonding range and DOS non-locality at Pb-Pb contact site are significantly greater than that of the S-S or Pb-S contact sites. The cyclic voltammetric measurements reveal that the galvanic interaction between galena and pyrite improves the adsorption of xanthate on galena surface, which is in good agreement with the DFT results.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 826-836
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation separation of scheelite from calcite using sodium polyacrylate as depressant
    Autorzy:
    Zhang, Y.
    Chen, R.
    Li, Y.
    Wang, Y.
    Luo, X.
    Powiązania:
    https://bibliotekanauki.pl/articles/110896.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    scheelite
    calcite
    flotation
    sodium polyacrylate
    selective depression
    Opis:
    The depressing properties of sodium polyacrylate (PA-Na) for calcite from scheelite were studied by microflotation experiments, zeta potentials, X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculation. Flotation results revealed that the selective depression effect of PA-Na was better than that of sodium silicate (Na2SiO3), and PA-Na can depress calcite more effectively than scheelite. The flotation recovery of scheelite and calcite kept at about 75% and 15% respectively at the pulp pH 9.3~9.6 and PA-Na concentration from 37.5 mg/dm3 to 50 mg/dm3. The zeta potentials of the minerals were significantly altered and the zeta potential of calcite became more negative than scheelite. XPS analysis deduced the occurrence of chemisorption between PA-Na and mineral surfaces, and the chemisorption of PA-Na on calcite was stronger than on scheelite. The results from DFT calculation demonstrated that the absolute value of the adsorption energy in the presence of PA-Na on the surface of calcite {104} was larger than on the surface of scheelite {111}. With the combination of the analysis, it could be concluded that calcite was more easily depressed than scheelite, and this finding remarkably matched with the microflotation experimental results. Furthermore, by using PA-Na as depressant, the flotation separation of scheelite from calcite can be achieved by controlling the flotation pH and PA-Na dosage.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 505-516
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influence of controlled dispersion on rheology of swelling clay suspensions in the presence of coal flotation reagents
    Autorzy:
    Zhang, M.
    Cao, Y.
    Chen, Y.
    Yu, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/110619.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    swelling clay
    rheological properties
    controlled dispersion
    flotation reagents
    Opis:
    Swelling clay minerals, which are innately capable of dispersing into thin flakes in water, can significantly depress coal flotation. Some researchers partially attribute depression to pulp viscosity increments. This study sought to understand the role of swelling clay minerals in fine coal flotation, by investigating the rheological behavior of bentonite suspensions under controlled and uncontrolled dispersion conditions. The effect of collector, frother, and solution pH on rheological properties of the pulp was studied. Findings showed that at a natural pH, Newtonian flow properties were displayed when bentonite was directly added into a swelling suppressed solution containing calcium ions. The same process was repeated under uncontrolled conditions, and the suspensions transferred from Newtonian to non-Newtonian flows with pseudo-plastic characteristics, depending on the solid density. Further, pH value, methyl isobutyl carbinol (MIBC) and kerosene had the potential to alter the rheological behavior of controlled and uncontrolled systems, especially pH value in the uncontrolled system.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1148-1160
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Phase change of chlorite in reducing atmosphere
    Autorzy:
    Liu, X.
    Yu, Y.
    Chen, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/110704.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    chlorite
    phase change
    magnetizing
    reducing roasting
    magnetite
    Opis:
    Magnetizing roasting is an important pre-treatment technique for beneficiation of hematite and limonite ores. Reduction mechanisms of these iron minerals have been fully studied while the mechanism of reduction of chlorite is not well understood. In this study, a reduction roasting study examining the phase change of chlorite with roasting temperature was undertaken. The major finding from this study was that chlorite partially was reduced to magnetite by carbon at 750 ⁰C, and the newly formed magnetite was finely disseminated within quartz and olivine. It was demonstrated that these locked magnetite particles would be reported to iron concentrate by low intensity magnetic separation resulting in high impurity content, especially SiO2 and Al2O3 contents in the concentrate.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2014, 50, 2; 607-614
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Experimental study on triboelectrostatic beneficiation of wet fly ash using Microwave Heating
    Autorzy:
    Li, H.
    Chen, Y.
    Zhang, X.
    Zhao, Y.
    Tao, Y.
    Li, C.
    He, X.
    Powiązania:
    https://bibliotekanauki.pl/articles/110399.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    wet fly ash
    triboelectrostatic beneficiation
    microwave heating
    efficiency
    Opis:
    Triboelectrostatic beneficiation, as a physical method, of fly ash cannot only meet the technical requirements of fly ash application but also recycle of an unburned carbon as a useful energy source. The aim of this study was to investigate the feasibility of improving efficiency of triboelectrostatic beneficiation of wet fly ash using microwave heating. The wet fly ash with different moisture contents had an average loss-on-ignition of 12.56%. The fly ash samples were heated in a microwave oven before the experiments. The experimental conditions were electric field voltage of 40 kV and air flux ranging from 12 to 30 m3/h. The influence of the microwave heating on the wet fly ash triboelectrostatic beneficiation was discussed under the conditions of different microwave intensity and irradiation time. The results indicated that the removal rate and recycle rate of the unburned carbon showed a significant increase performance as the wet fly ash was processed by the microwave heating which was attributed to changes of moisture contents and dielectric constants caused by the microwave heating. The feasibility had been verified according to the experimental study on fly ash with different moisture contents. It can be concluded that the microwave heating process was efficiently applied for the wet fly ash triboelectrostatic beneficiation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 1; 328-341
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Comparison of mechanical flotation cell and cyclonic microbubble flotation column in terms of separation performance for fine graphite
    Autorzy:
    Bu, X.
    Zhang, T.
    Chen, Y.
    Peng, Y.
    Xie, G.
    Wu, E.
    Powiązania:
    https://bibliotekanauki.pl/articles/110791.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    mechanical flotation
    column flotation
    Fuerstenau upgrading curve
    graphite
    Opis:
    Comparison of flotation performance between the flotation column and mechanical flotation was carried out to promote the grade and economic value of the graphite ore (15.40% ash content). The ash content of the concentrate of the mechanical flotation was 10.77% at the yield of 79.34%. In contrast, the yield of the concentrate of the column flotation was increased to 88.93% with 10.55% ash content. Comparative study of the Fuerstenau upgrading curves indicated that the column flotation was more efficient for cleaning the graphite ore in the presence of the centrifugal force field, nanobubbles (generated by hydrodynamic cavitation), and the thicker froth layer in comparison with the mechanical flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 732-740
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation behavior and adsorption mechanism of sodium lauroamphoacetate to cassiterite
    Autorzy:
    Chen, Y.
    Lv, H.
    Tong, X.
    Xie, X.
    Powiązania:
    https://bibliotekanauki.pl/articles/109885.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    sodium lauroamphoacetate
    flotation behavior
    adsorption mechanism
    cassiterite
    Opis:
    The flotation behavior and adsorption mechanism of cassiterite using sodium lauroamphoacetate (SLA) as a collector were investigated by adsorption tests, micro-flotation tests, zeta potential measurements, Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis. Adsorption test results indicated that the adsorption of SLA on the cassiterite surface increased continually with the increase of SLA concentration. Micro-flotation test results demonstrated that SLA had a stronger collecting ability to cassiterite than salicylhydroxamic acid (SHA) and sodium oleate (NaOL) in the pH range of 2-12, and showed a higher selectivity in the separation of cassiterite-quartz than in cassiterite-clinochlore. The zeta potential measurement results indicated that the isoelectric point (IEP) of cassiterite minerals changed from pH 3.9 to 3.4, suggesting the adsorption of SLA on cassiterite surface. The FTIR spectra and XPS analysis further confirmed that SLA chemically adsorbed on cassiterite surface.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 386-394
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Hydrochloric acid leaching for upgrading flotation concentrate from a low-grade bauxite ore
    Autorzy:
    Guan, C.
    Chen, L.
    Zheng, Y.
    Sun, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/110259.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    bauxite ore
    hydrochloric acid leaching
    concentrate upgrading
    carbonate minerals
    Opis:
    Bauxite is the major raw material for alumina production, and its Al2O3 grade improvement or desilication is a necessary process for production of high-grade alumina concentrates from bauxite ores. In practice, flotation presents an effective method for the processing of such ores. However, it is not sufficient to produce a concentrate product with high Al2O3 grade from the ores with a single flotation process, especially from these containing abundant carbonate minerals. In this investigation, hydrochloric acid leaching was used to remove dolomite impurity from the flotation concentrate of a bauxite ore, to improve its Al2O3 grade and Al2O3/SiO2 (A/S) ratio. Effects of three dominant parameters on the leaching performance, that is leaching time, leaching temperature and hydrochloric acid concentration, were investigated in details. When these parameters were optimized, the aluminum concentrate assaying 67.41% Al2O3 with 66.84% recovery and 7.44 A/S ratio was obtained from the bauxite ore assaying 42.94% Al2O3 with 2.48 A/S ratio. It was concluded that hydrochloric acid leaching proved an effective method for upgrading of flotation concentrate from a low-grade bauxite ore containing carbonate minerals.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1038-1046
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effects of colloidal montmorillonite particles on froth flotation of graphite, galena and fluorite
    Autorzy:
    Chen, T.
    Zhao, Y.
    Li, H.
    Song, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/110589.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    montmorillonite
    graphite
    galena
    fluorite
    slime coating
    entrainment
    Opis:
    The effect of colloidal montmorillonite (MMT) on froth flotation of graphite, galena and fluorite was investigated in this work. The results showed that the presence of sufficient amount of colloidal MMT particles in the mineral slurry would be detrimental of flotation by reducing the recovery of minerals. This observation was attributed to slime coating of MMT on the coarse valuable mineral particles and entrainment of MMT particles in the froth product together with water in the triangle froth zones. The former would reduce the recovery of the valuable minerals because of hydrophilic MMT coating. The latter would decrease the concentrate grade. The degree of slime coating depended on slurry pH, while the degree of entrainment was closely related to water recovery. It was also found that slime coating was a dominant factor in mineral flotation in acidic pH regions in the presence of colloidal MMT particles.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 699-713
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of modified starch on separation of fluorite from barite using sodium oleate
    Autorzy:
    Chen, Z.
    Ren, Z.
    Gao, H.
    Qian, Y.
    Zheng, R.
    Powiązania:
    https://bibliotekanauki.pl/articles/109938.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    fluorite
    barite
    modified starch
    flotation
    Opis:
    In this study, a modified starch was utilized to selectively separate barite from fluorite. The results of flotation tests showed that highly selective separation of fluorite from barite was obtained when 250 mg/dm3 of modified starch and 13.16×10−5 mol/dm3 sodium oleate was used in neutral solutions. FTIR spectra results showed that the modified starch can adsorb on the fluorite and barite surfaces. Zeta potential analyses indicated that the modified starch had little effect on adsorption of sodium oleate on the fluorite surface, although it interfered with the adsorption of sodium oleate on the barite surface. Contact angle measurements results corresponded well with the flotation results.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 228-237
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Contribution on fluid inclusion abundance to activation of quartz flotation
    Autorzy:
    Yuan, Y.
    Zhang, L.
    Guan, J.
    Zhang, C.
    Wu, J.
    Chen, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/110067.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    recovery
    flotation
    mineralogy
    fluid Inclusions
    fluid inclusion abundance
    Opis:
    In this study, comparative experiments were conducted on the recovery of quartz using flotation with different fluid inclusion abundances. A large number of fluid inclusions with various sizes have been found in natural quartz. Micrographs, inductively coupled plasma, electron probe microanalysis, homogenization temperature, Raman spectra, zeta potentials, X-ray photoelectron spectroscopy, scanning electron microscope, and energy dispersive spectrometer were used to characterize the fluid inclusions and quartz, as well as the adsorption tests and single mineral flotation experiments to investigate its floatability. The results demonstrated that it was more likely for quartz with higher fluid inclusion abundance to connect with Fe3+ sufficiently to achieve a high level of flotation recovery, due to the powerful collecting ability by sodium dodecyl sulphonate to Fe3+. Furthermore, the mechanism indicated that the adsorption between quartz and Fe3+ was a process of chemisorption.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 981-991
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Evaluation of sodium petroleum sulfonates with different molecular weights for flotation of kyanite ore
    Autorzy:
    Chen, B. Z.
    Gao, H.
    Li, Y.
    Jin, J.
    Ren, Z.
    Wang, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/109492.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    evaluation
    sodium petroleum sulfonate
    kyanite
    flotation kinetics
    entrainment
    Opis:
    The flotation performance of sodium petroleum sulfonates with different molecular weights was evaluated for flotation of a kyanite ore, by investigating valuable mineral recovery-grade, flotation kinetics and gangue entrainment. The results indicated that the higher molecular weight of agent, the higher final cumulative kyanite recovery was, with the maximum value of 72% being obtained with KY-3 with the molecular weight of 438. The final cumulative kyanite grade initially increased, and then decreased with the molecular weight increasing. In other words, the maximum final cumulative kyanite grade (i.e. 89.05%) was obtained with KY-2 with the molecular weight of 392. The kyanite flotation kinetics followed the first order kinetics well, while the modified flotation rate constant showed a decreasing trend after the initial increase as the molecular weight increased. In addition, the overall entrainment degree decreased with decreasing molecular weight of sodium petroleum sulfonates. The use of KY-2 in kyanite flotation was an attractive option in comparison with KY-1 and KY-3.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 956-968
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-12 z 12

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