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    Wyświetlanie 1-6 z 6
    Tytuł:
    Influence of synergistic effect between dodecylamine and sodium oleate on improving the hydrophobicity of fluorapatite
    Autorzy:
    Cao, Q.
    Luo, B.
    Wen, S.
    Cheng, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/109587.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    fluorapatite
    hydrophobicity
    synergistic effect
    mixed collector
    Opis:
    The influence of synergistic effect between dodecylamine (DDA) and sodium oleate (NaOl) on the hydrophobicity of fluorapatite (FA) was investigated with contact angle, surface tension, XPS and zeta potential studies. The role of pH and the mixing ratio of surfactants on the synergistic behavior were considered. Basing on the contact angle results the suitable pH for the NaOl-DDA mixture was pH 9.5. A further study indicated that the 3:7 DDA-NaOl mixtures could notably improve the contact angle comparing to that only with DDA or NaOl. In the solution of this mixture, the DDA cation and DDA molecule both adsorb at the FA surface as revealed by the XPS spectra results. The zeta potential analysis further suggested that the adsorption of oleate at the FA surface was also improved. The presence of DDA cation and DDA molecule was expected to result in a uniform packing of surfactants at the FA surface.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 1; 42-55
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Kinetics and mechanism of one-step reductive leaching of manganese oxide ores by EDTA/EDTA-2Na
    Autorzy:
    Zhang, C.
    Wang, S.
    Cao, Z.
    Zhong, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/109834.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    kinetics
    EDTA
    reductive leaching
    manganese oxide ores
    EDTA-2Na
    Opis:
    In this research, the kinetics and mechanism of one-step reductive leaching of manganese oxide ores by ethylenediaminetetraacetic acid (EDTA) or its disodium salt (EDTA-2Na) in an aqueous medium have been investigated. The kinetic data of this reductive leaching process may be described by the Avrami model, and the apparent activation energy was determined to be 15.8 kJ·mol-1/7.9 kJ·mol-1 for leaching by EDTA/EDTA-2Na with a reaction order of -1.7/2.0. The EDTA/EDTA-2Na leach liquor characterized and analyzed by X-ray photoelectron spectra (XPS), Fourier transform infrared spectra (FTIR), and total organic carbon (TOC) determination denoted that the oxidation-reduction reaction happened between manganese(IV) and EDTA/EDTA-2Na, and a coordination complex, EDTA-manganese(II/III) formed. This new process can be easily used to leach manganese from manganese oxide ores in a moderate environment with the pH range of 5–8.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 858-867
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The surface features of activated stibnite surface with copper or lead ion
    Autorzy:
    Cao, Q.
    Huang, Y.
    Zou, H.
    Wen, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/110393.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    stibnite
    flotation
    activation
    active layer
    Opis:
    Cu2+ and Pb2+ are widely used as activators for the flotation of stibnite. In this work, by the treatment of Cu2+ or Pb2+, the activation product and the thickness of activation layer on the stibnite surface were both investigated. Based on the flotation results, zeta potential analysis and X-ray photoelectron spectroscopy (XPS) study, it was found that Cu2+ was reduced to Cu+ at the stibnite surface and a layer of Cu2S was formed at the surface. While, a PbS layer presenting at the stibnite surface is responsible for the activation flotation of stibnite with Pb2+. Time of flight secondary ion mass spectrometry (TOF-SIMS) analysis further implies that, when stibnite was activated with 5×10-5 mol/dm3 of CuSO4 or Pb(NO3)2, the thickness of Cu2S layer on the Cu-activated surface was close to 2.7 nm, while the thickness of PbS layer was about 1.8 nm on the Pb-activated surface.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 763-770
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation behavior of hard-to-separate and high-ash fine coal
    Autorzy:
    Xing, Y.
    Gui, X.
    Liu, J.
    Cao, Y.
    Zhang, Y.
    Li, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/110585.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation behavior
    fine coal
    Fuerstenau upgrading curve
    energy input
    selectivity
    Opis:
    The flotation behavior of hard-to-separate and high-ash fine coal was investigated using conventional flotation with constant power input. A new flotation process, based on energy input and distribution, was designed to lower the ash content of concentrate. The results obtained using Fourier transform infrared (FTIR) analysis show that the coal samples have good floatability because of many hydrophobic and few hydrophilic functional groups. Under a constant power input, a large number of ash-forming materials floated into a froth product at the start of flotation. Based on the Fuerstenau upgrading curves, it was determined that the 0.25-0.074 mm size fraction range showed the worst selectivity when compared with 0.50-0.25 mm and -0.074 mm size fractions. The desired concentrate with an ash content of 13.98%, 27.59% of ash recovery, and 80.01% combustible matter recovery could be obtained by transferring the excess energy of the flotation-conditioning stage to the pre-conditioning stage and increasing the power input step-by-step in the flotation-conditioning stage at equal total energy consumption.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 2; 703-717
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of intergrown particle liberation on difficult-to-separate coking coal flotation
    Autorzy:
    Gui, X.
    Liu, J.
    Cao, Y.
    Xing, Y.
    Deng, Y.
    Li, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/109875.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    liberation
    particle size
    coking coal
    hydrophobicity
    Opis:
    Flotation tests with intergrown particle liberation were conducted to explore a separation method of difficult-to-separate coking coal from the Tangshan Kailuan mine in China. The particle size distribution, density and coal petrography were investigated. The difficult-to-separate coking coal sample resulted in intergrown particles, such as non-liberated coal and rocks. Thus, intergrown coal particle liberation and re-separation tests were conducted. The results showed that grinding time had a great effect on the flotation performance. Grinding prompted coal to dissociate and improve the surface hydrophobic properties of minerals. However, heterogeneous fine silt covered the surface of coal particles when coal was ground too long. The inorganic mineral particles were over-ground and reduced the contact angle of coal. The results of coal rock dissociation and laboratory re-separation tests showed that clean coal combustible recovery increased through intergrown particle liberation and re-separation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 1; 279-294
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Adsorption behavior of Zn(II) onto natural minerals in wastewater. A comparative study of bentonite and kaolinite
    Autorzy:
    Chai, W.
    Huang, Y.
    Su, S.
    Han, G.
    Liu, J.
    Cao, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/109926.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    adsorption
    Zn(II)
    wastewater
    clay minerals
    structural properties
    Opis:
    In order to remove the harmful metal ions in lead-zinc mineral processing wastewater, two natural clay minerals (bentonite and kaolin) were used as adsorbents and Zn(II) ions were the emphasis in this work. The adsorption behaviors including kinetics and isotherms were investigated by batch experiments. In addition, the adsorption mechanisms were studied by means of zeta potential testing, optical microscope and XRD analysis. The results show that the adsorption process can be best described as the pseudo-second order kinetic model. The adsorption equilibrium data of bentonite and kaolinite can be respectively fitted best by Langmuir and Freundlich models. Thermodynamic studies display that the adsorption of Zn(II) onto clays is non-spontaneous and endothermic. The maximum capacity of Zn(II) adsorbed on bentonite and kaolinite respectively reaches to 79.2 mg·g-1 and 6.35 mg·g-1 at 25 °C. The structural differences of bentonite and kaolinite result in the differences in adsorption behavior and mechanism. The interaction mechanisms of Zn(II) with bentonite and kaolinite involve electrostatic attraction, cation exchange, surface complex and precipitation. Bentonite as adsorbent has the potential to remove Zn2+ better than kaolinite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 1; 264-278
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

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