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Wyświetlanie 1-2 z 2
Tytuł:
Effect of direct reduction time of vanadium titanomagnetite concentrate on the preparation and photocatalytic performance of calcium titanate
Autorzy:
Li, Xiaohui
Kou, Jue
Sun, Tichang
Wu, Shichao
Tian, Yuechao
Powiązania:
https://bibliotekanauki.pl/articles/1449028.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
vanadium titanomagnetite concentrate
calcium titanate
direction reduction
metallic iron
photocatalytic performance
Opis:
Effects of direct reduction time of vanadium titanomagnetite concentrate (VTCE) on the preparation and photocatalytic performance of calcium titanate were investigated in this study. It was found that extending the reduction time could not only promote the formation of calcium titanate, but also facilitate the reduction of iron minerals in the reduction products. The optimum reduction time was 180min under the conditions of $CaCO_3$ dosage of 18wt%, reduction temperature of 1400℃ and lignite dosage of 70wt%. The reduced iron (Fe grade of 90.95wt%, Fe recovery of 92.21wt%) and calcium titanate were obtained via grinding-magnetic separation. Moreover, calcium titanate prepared via the direct reduction method could be used as a photocatalyst, where the degradation degree of methylene blue increased from 25.13% to 60.14% with the addition of calcium titanate. Furthermore, Langmuir Hinshelwood fitting results indicated that the degradation of methylene blue by the calcium titanate prepared under different reduction times conformed to first-order reaction kinetics, where the photocatalytic degradation rate of methylene blue was noted to be the highest for a reduction time of 180 min.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 75-86
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pr-doped TiO2. The effect of metal content on photocatalytic activity
Autorzy:
Reszczynska, J.
Arenas Esteban, D.
Gazda, M.
Zaleska, A.
Powiązania:
https://bibliotekanauki.pl/articles/110437.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
photocatalysis
rare earth metal
praseodymium
modified TiO2
phenol
Opis:
Pr-TiO2 nanoparticles were prepared by using a sol-gel method. As-prepared samples were characterized by BET measurements, X-ray powder diffraction analysis (XRD) and UV-Vis spectra. Visible and ultraviolet light photocatalytic activity of the sample was studied by photodegradation of phenol, while considering the influence of the dopant concentration. TiO2 doped with 0.25 mol% of praseodymium showed the highest photocatalytic activity under visible light irradiation. Pr-TiO2 had anatase structure. The surface area was higher for powders with higher content of rare earth metal ion, and ranged from 121 to 150 m2/g. Red shifts of absorption edge toward the visible region were observed for the doped samples compared to pure TiO2.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 2; 515-524
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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