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    Wyświetlanie 1-4 z 4
    Tytuł:
    Leaching kinetic study of Y and Eu from waste phosphors using hydrochloric acid solution containing hydrogen peroxide
    Autorzy:
    Yu, M.
    Jiang, Z.
    Mei, G.
    Chen, X.
    Powiązania:
    https://bibliotekanauki.pl/articles/949690.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    waste phosphors
    leaching
    kinetics
    rare earth elements
    Opis:
    The leaching kinetics of Y and Eu from waste phosphors using a hydrochloric acid (HCl) solution containing hydrogen peroxide (H2O2) were investigated. Characterization of the waste phosphors was performed using XRD to ascertain the phases as (Y0.95Eu0.05)2O3 (red phosphors), (Ce0.67Tb0.33)MgAl11O19 (green phosphors), (Ba0.9Eu0.1)Mg2Al16O27 (blue phosphors), and SiO2 (quartz). The influence of factors such as HCl concentration, addition amount of H2O2, temperature, and reaction time on the leaching performance of Y and Eu was investigated. The maximum leaching recoveries of Y (99.87%) and Eu (88.72%) were obtained at 4 M HCl, 0.2 cm3/g H2O2, 60 ℃ temperature, and 180 min of reaction time at a liquid-to-solid ratio of 7.5 cm3/g. Leaching kinetic results showed the best fit with the shrinking sphere model (1-(1-x)1/3)=kct), ensuring that the overall leaching process was governed by a chemical control mechanism. Activation energies of 42.35 and 33.28 kJ/mol were acquired for leaching of Y and Eu, respectively, at 40-70 ℃, which further supports the proposed chemical control leaching process.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 238-248
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influence of controlled dispersion on rheology of swelling clay suspensions in the presence of coal flotation reagents
    Autorzy:
    Zhang, M.
    Cao, Y.
    Chen, Y.
    Yu, W.
    Powiązania:
    https://bibliotekanauki.pl/articles/110619.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    swelling clay
    rheological properties
    controlled dispersion
    flotation reagents
    Opis:
    Swelling clay minerals, which are innately capable of dispersing into thin flakes in water, can significantly depress coal flotation. Some researchers partially attribute depression to pulp viscosity increments. This study sought to understand the role of swelling clay minerals in fine coal flotation, by investigating the rheological behavior of bentonite suspensions under controlled and uncontrolled dispersion conditions. The effect of collector, frother, and solution pH on rheological properties of the pulp was studied. Findings showed that at a natural pH, Newtonian flow properties were displayed when bentonite was directly added into a swelling suppressed solution containing calcium ions. The same process was repeated under uncontrolled conditions, and the suspensions transferred from Newtonian to non-Newtonian flows with pseudo-plastic characteristics, depending on the solid density. Further, pH value, methyl isobutyl carbinol (MIBC) and kerosene had the potential to alter the rheological behavior of controlled and uncontrolled systems, especially pH value in the uncontrolled system.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1148-1160
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation separation of rutile from almandine using octadecyl amine polyoxyethylene ether as collector
    Autorzy:
    Li, Hongqiang
    Zheng, Huifang
    Chen, Qian
    Kasomo, Richard M.
    Leng, Jiahao
    Weng, Xiaoqing
    Song, Shaoxian
    Xiao, Linbo
    Tian, Chengtao
    Powiązania:
    https://bibliotekanauki.pl/articles/1449410.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    rutile
    almandine
    flotation separation
    adsorption mechanism
    Opis:
    In this study, the flotation separation of rutile from almandine using cationic surfactant Octadecyl amine polyoxyethylene ether (AC1815) as a new collector was investigated. The adsorption mechanism of AC1815 on rutile was illustrated through zeta potential measurement, infrared spectrum and XPS analyses. The flotation experiments demonstrated that AC1815 exhibited an excellent collecting ability and selectivity for rutile. The results of zeta potential measurements and XPS analysis indicated that more AC1815 was adsorbed on rutile surface instead of almandine. The adsorption mechanism of AC1815on rutile was mainly attributed to the electrostatic interaction between the positively charged molecules of AC1815 and the negatively charged rutile surface, and the hydrogen bonding between the protonated $≡NH^+$, $≡N$ group of AC1815 and $Ti-OH$ on rutile surface.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 4; 653-664
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Reverse flotation of collophanite at natural pH using isooctyl polyoxyethylene ether phosphate as a collector
    Autorzy:
    Li, Hongqiang
    Zhang, Wen
    Chen, Qian
    Huang, Peng
    Kasomo, Richard M.
    Zou, Ze
    Weng, Xiaoqing
    He, Dongsheng
    Yang, Siyuan
    Song, Shaoxian
    Powiązania:
    https://bibliotekanauki.pl/articles/1445877.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    reverse flotation
    dolomite
    fluorapatite
    AEP
    selective adsorption
    Opis:
    Reverse flotation of collophanite at natural pH could significantly decrease the cost of pH regulators. In this study, isooctyl polyoxyethylene ether phosphate (AEP) was tested as a new surfactant in the reverse flotation of collophanite. Micro-flotation tests were conducted, and the adsorption mechanism of the new collector was analysed using X-ray photoelectron spectroscopy (XPS) and zeta potential analyses. The results of the flotation tests demonstrated that AEP could enable dolomite to float under natural pH (pH=7.2) and showed profound selectivity towards dolomite as opposed to fluorapatite. Based on the zeta potential and XPS results, the adsorption phenomena are mainly attributed to calcium active sites on both mineral surfaces. Dolomite possesses more magnesium active sites than fluorapatite, which tend to reinforce the interaction effect between AEP and dolomite. Furthermore, when compared to CO32- ions on the dolomite surface, PO43- ions on the fluorapatite surface tend to exhibit a stronger hindrance to the adsorption of AEP on the fluorapatite surface. This is attributed to their larger volumes and more charges on their surfaces, thereby causing a floatability difference between the two minerals.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 4; 78-86
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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