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Wyświetlanie 1-15 z 57
Tytuł:
Spectroscopic characteristics of FeI-phthalocyanine
Autorzy:
Kaczmarzyk, T.
Jackowski, T.
Dziliński, K.
Powiązania:
https://bibliotekanauki.pl/articles/148333.pdf
Data publikacji:
2007
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
iron phthalocyanine
reduction process
Mössbauer spectroscopy
EPR
DTF
Opis:
Results of Mössbauer and EPR study of a univalent-iron phthalocyanine complex (FeIPc) are presented in this paper. FeIPc has been obtained from FeIIPc by the chemical reduction method in tetrahydrofuran (THF) and dimethoxyethan (DME) solutions. Like in the case of FeI-porphyrin complexes, Mössbauer and EPR data as well as quantum calculations of electronic absorption spectra confirm in this case a low-spin configuration of FeI ions with an unpaired electron located at dz2 orbital. Interaction between FeIPc and THF molecules does not change significantly the electron configuration of FeI ions coordinated to phthalocyanine ligand.
Źródło:
Nukleonika; 2007, 52, supl. 1; 99-103
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamic and dynamical properties of dense ICF plasma
Autorzy:
Gabdullin, M. T.
Kodanova, S. K.
Ramazanov, T. S.
Issanova, M. K.
Ismagambetova, T. N.
Powiązania:
https://bibliotekanauki.pl/articles/146117.pdf
Data publikacji:
2016
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Coulomb logarithm
effective interaction potential
equation of state
stopping power
Opis:
In present work, thermodynamic expressions were obtained through potentials that took into consideration long-range many-particle screening effects as well as short-range quantum-mechanical effects and radial distribution functions (RDFs). Stopping power of the projectile ions in dense, non-isothermal plasma was considered. One of the important values that describe the stopping power of the ions in plasma is the Coulomb logarithm. We investigated the stopping power of ions in inertial confi nement fusion (ICF) plasma and other energetic characteristics of fuel. Calculations of ions energy losses in the plasma for different values of the temperature and plasma density were carried out. A comparison of the calculated data of ion stopping power and energy deposition with experimental and theoretical results of other authors was also performed.
Źródło:
Nukleonika; 2016, 61, 2; 125-129
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Asymmetry in Mössbauer spectra of FeIII-azaporphyrin complexes
Autorzy:
Kaczmarzyk, T.
Jackowski, T.
Dziliński, K.
Sinyakov, G.
Powiązania:
https://bibliotekanauki.pl/articles/148331.pdf
Data publikacji:
2007
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Mössbauer spectroscopy
iron porphyrins
azaporphyrins
asymmetry in Mössbauer spectra
spin-spin and spin-lattice relaxation
Opis:
Temperature dependence of asymmetry as well as isomer shift and quadrupole splitting values of Mössbauer spectra of trivalent iron complexes coordinated to porphyrin ligands such as octaethylporphyrin, monoazaethioporphyrin, diazaoctaethylporphyrin and phthalacyanine is discussed in this paper. All the above mentioned complexes have the chloride axial ligand at the fifth coordination site. Different temperature changes of asymmetry and other parameters of Mössbauer spectra of these complexes can be correlated with a number of methine bridges CH substituted by nitrogen atoms in the porphyrin macrocycle. The form of this asymmetry is such that the higher-energy component of the doublet is more broadened than the lower-energy one, while the areas (intensities) under each of two components are the same. The most distinct asymmetry is observed at room temperature. When temperature is decreasing, the spectrum becomes successively more symmetrical and at liquid helium temperature linewidths of both components of the quadrupole splitting are very close one another. The Mössbauer spectrum of the FeCl-monoazaethioporphyrin complex exhibits reversed asymmetry at liquid helium temperature in comparison with the spectra of the remaining complexes i.e. the lower-energy component of the doublet is slightly more broadened than the higher-energy one. The spin-spin and spinlattice relaxation mechanisms in the context of quantum mechanically mixed spin states S = 5/2 + 3/2 of FeIII ions are considered as a source of the observed asymmetry.
Źródło:
Nukleonika; 2007, 52, supl. 1; 93-98
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of nitrogen substitution in porphyrin ring on Mössbauer parameters of iron ions
Autorzy:
Kaczmarzyk, T.
Jackowski, T.
Dziliński, K.
Sinyakov, G.
Powiązania:
https://bibliotekanauki.pl/articles/147210.pdf
Data publikacji:
2004
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Mössbauer spectroscopy
iron porphyrins
azaporphyrins
trivalent-iron spin states
Opis:
Electron configuration changes of Fe(III) ions in porphyrin complexes with chloride axial ligands caused by the successive nitrogen substitution of CH methine bridges at meso positions of the porphyrin ring is discussed on the basis of Mössbauer spectroscopy results. It was shown that increase of a number of nitrogen atoms at the meso positions changes the character of quantum-mechanically mixed spin state of Fe(III) ions (S = 5/2 + 3/2) by the increase of the intermediate-spin (S = 3/2) contribution. This feature is reflected in Mössbauer spectra by an increase of quadrupole splitting values and the decrease of the asymmetry of quadrupole doublets, when the number of nitrogen atoms at the meso positions increases. Isomer shifts remain practically unchanged. These peculiarities are discussed in the light of spin relaxation mechanisms and the occupancy of d orbitals in Fe(III) ions coordinated to the porphyrin ring and chloride ligand. It has been noticed that Mössbauer parameters correlate qualitatively with EPR data.
Źródło:
Nukleonika; 2004, 49,suppl.3; 13-16
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mössbauer study of a tetrakis (pentafl uorophenyl) porphyrin iron (III) chloride in comparison with the fluorine unsubstituted analogue
Autorzy:
Kaczmarzyk, T.
Dziedzic-Kocurek, K.
Rutkowska, I.
Dziliński, K.
Powiązania:
https://bibliotekanauki.pl/articles/146091.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
catalytic activity
DFT calculations
electronic structure
iron(III)-[tetrakis (pentafl uorophenyl)]
Mössbauer spectroscopy
porphyrin chloride
Opis:
Mössbauer investigations, in association with density functional theory (DFT) calculations, have been conducted for the molecular and electronic structures of iron (III) [tetrakis (pentafl uorophenyl)] porphyrin chloride [(F20TPP)Fe:Cl], as a Fe(III)-tetraphenylporphyrin complex containing chloride axial ligand and substituted hydrogen atoms by fl uorine ones in the four phenyl rings, in comparison with its fl uorine unsubstituted analogue [(TPP)Fe:Cl]. It was found that the parameters of Mössbauer spectra of both complexes are close to one another, and correspond to the high-spin state of Fe(III) ions, but they show the different temperature dependence and the quadrupole doublets in Mössbauer spectra show different asymmetry at low temperatures. Results of DFT calculations are analyzed in the light of catalytic activity of the halogenated complex.
Źródło:
Nukleonika; 2015, 60, 1; 57-61
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of scattered radiation in the total body irradiation technique: evaluation of the spoiler and wall dose component in the depthdose distribution
Autorzy:
Piotrowski, T.
Adamska, K.
Malicki, J.
Powiązania:
https://bibliotekanauki.pl/articles/147640.pdf
Data publikacji:
2007
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
total body irradiation (TBI)
scattered radiation
leukaemia
Opis:
To determine the additional dose in layers of the body close to the skin during total body irradiation (TBI), due to radiation scattered off the treatment room walls and behind plexiglass spoilers applied to improve dose uniformity within the irradiated body. Large-field 6, 15 and 25 MV photon beams were generated by a Saturn 43 medical accelerator. A solid 30 ´ 30 ´ 30 cm3 PMMA (polymethylmethacrylate) phantom was used to represent radiation scattered from the body of the patient. Dose distributions were measured by a Farmer ionization chamber. The dose component arising from the spoiler was measured 5 mm below the phantom surface, over distances of 5-100 cm between the spoiler and the phantom surface. To measure the contribution of backscattered radiation from the walls, a small lead block was placed between the source and detector. Measurements were carried out in air with the PMMA phantom removed, to eliminate radiation backscattered from the phantom. As measured behind the spoiler, attenuation of the primary photon beam by the spoiler itself was by 8, 5 and 3% for 6, 15 and 25 MV beams, respectively. The highest dose contribution from the spoiler arose at 10 cm separation between the phantom surface and the spoiler. Assessed at a depth of 5 mm in the phantom, at spoiler-phantom separation of 10 cm, relative to case without spoiler and with wall backscatter subtracted, the dose enhancement due to the spoiler was by 8, 13 and 20% at beam energies 6, 15 and 25 MV, respectively. In these measurements, the distance between the source and the phantom surface was 300 cm and that between the source and the spoiler - 290 cm. The dose contributions due to radiation backscattered from the walls, relative to the case without any wall backscatter, estimated over the distal side of the phantom at a distance of 20 cm between the wall and that side of the phantom, were 5, 6 and 8% at beam energies 6, 15 and 25 MV, respectively. The use of a spoiler enhanced the dose in regions close to the phantom surface, compensating for the dose decrease over that area due to build-up effect. Radiation backscattered from the wall enhanced the dose in regions close to the phantom surface facing the wall.
Źródło:
Nukleonika; 2007, 52, 4; 153-158
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modification of the hydrogen bonding network at the reversed micelles interface by near infrared radiation
Autorzy:
Walski, T.
Gałecka, T.
Grzeszczuk-Kuć, K.
Komorowska, M.
Powiązania:
https://bibliotekanauki.pl/articles/148832.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
electron paramagnetic resonance (EPR)
hydrogen bonds
near infrared radiation (NIR)
cetyltrimethylammonium bromide (TCAB) reverse micelles
TEMPO-palmitate spin probe
water structure modification
Opis:
The purpose of this paper is to prove that near infrared radiation (NIR) modifies hydrogen bonds localized in the interface of reversed micelles. The degree of modification of the hydrogen bonds was monitored by TEMPO-palmitate spin probe introduced into the structure of reverse micelles formed by cetyltrimethylammonium bromide (CTAB) (TCAB/phosphate buffer/isooctane/hexanol and TCAB/NaCl/isooctane/hexanol (W = 15)). Electron paramagnetic resonance (EPR) spectra were performed on the argonated samples. The isotropic tumbling correlation time (τc) and the hyperfine coupling constant A+ = h0 – h+1 (h+1, and h0 correspond to the low-, and centre-field lines, respectively) were determined from the EPR spectra as a quantitative measure for monitoring the action of NIR radiation. A+ values depend on the composition of the water pool (1.640 mT for phosphate buffer and 1.630 mT for NaCl). NIR irradiation led to decrease in A+. This parameter reached the same value for both solutions (1.625 ± 0.003 and 1.626 ± 0.003 mT) after exposition to NIR. The tumbling correlation time after exposure to NIR decreased for TCAB/phosphate buffer/ isooctane/hexanol reversed micelles from 2.10 × 10–10 s to 1.44 × 10–10 s but did not change for TCAB/NaCl/isooctane/ hexanol). The results obtained confirm the possibility of modification of the hydrogen bonds by NIR radiation.
Źródło:
Nukleonika; 2013, 58, 3; 435-438
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mössbauer spectroscopy of reduced forms of a Fe-tetraphenylporphyrine complex
Autorzy:
Kaczmarzyk, T.
Rutkowska, I.
Dziliński, K.
Powiązania:
https://bibliotekanauki.pl/articles/148211.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
DFT calculations
electronic structure
iron-(tetraphenyl)porphyrin
Mössbauer spectroscopy
reduction process
Opis:
Molecular and electronic structure changes during successive reduction of a Fe-tetraphenylporphyrin chloride [Fe(III)(TPP):Cl] complex are reported on the basis of Mössbauer spectroscopy and DFT calculations. It is established that the attachment of additional electrons to a neutral Fe(III)(TPP):Cl molecule leads to signifi cant shortening of Fe-N distances at the fi rst stage of the reduction Fe(III)(TPP):Cl →Fe(II)(TPP) and lengthening of these bonds at the second stage Fe(II)(TPP)→Fe(I)(TPP). Changes of other bond lengths of the porphyrin ring also appear but in less degree. Interaction of Fe(II) and Fe(I)(TPP) with tetrahydrofuran (THF) solvent is considered. Electron configuration of Fe(II)(TPP) corresponds to intermediate-spin (S = 1) state and in the case of Fe(I)(TPP) low-spin state (S = ½) is observed. Electron density distribution in Fe(II)- and Fe(I)(TPP) complexes, in association with Mössbauer data, is analyzed. Good correlation between experimental and theoretical results was obtained.
Źródło:
Nukleonika; 2015, 60, 1; 51-55
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electron beam decomposition of pollutant model compounds in aqueous systems
Autorzy:
Ting, T. -M.
Dahlan, K. Z. M.
Powiązania:
https://bibliotekanauki.pl/articles/147660.pdf
Data publikacji:
2011
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
absorbed dose
concentration of solute
ionizing radiation
organic decomposition
Opis:
In this study, factors that limit the utilization of electron beam irradiation for decomposition of pollutants were investigated. Potassium hydrogen phthalate (KHP) was used as the model pollutant compound. The accumulated chemical oxygen demand (COD) removal below 2.4 kGy (applied for concentration at 85, 170, 255, 425 and 850 mg/l) was less than 10 per cent, whereas the accumulated COD removal at 215 kGy (applied for concentration at 85, 170, 255, 425 and 850 mg/l) was 198 per cent. At a lower concentration of KHP, 85 mg/l, the accumulated COD removal (for dose ranging from 0.5 to 215 kGy) was 236per cent. As the concentration of KHP increases to 850 mg/l, almost no COD removal was recorded (for dose ranging from 0.5 to 215 kGy). The results show that the removal efficiency and effectiveness of pollutants were influenced by the solute concentration and irradiation dose. When the concentration of KHP increases to a certain level, water radical species were not sufficient to form KHP radicals and, therefore, reduce the decomposition of KHP molecules. Removal of phthalate as measured by COD was restricted at a very high concentration, 850 mg/l. This indicates that the by-products have scavenged the radicals rapidly. This also suggests that, the limitation of radiolytic products of water to decompose KHP at higher concentration. A large quantity of KHP molecules would also stabilize the KHP radicals and resulting in lower removal of KHP. Similar removal trend was also observed for the actual industrial wastewater.
Źródło:
Nukleonika; 2011, 56, 4; 349-355
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural characterization of room-temperature synthesized fullerene nanowhiskers
Autorzy:
Miyazawa, K.
Minato, J.
Mashino, T.
Nakamura, S.
Fujino, M.
Suga, T.
Powiązania:
https://bibliotekanauki.pl/articles/146219.pdf
Data publikacji:
2006
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
carbon
C60
fullerene
nanowhisker
structure
TEM
Opis:
Structural properties of various kinds of room-temperature synthesized C60 fullerene nanowhiskers were investigated by TEM and XRD. The C60 nanowhiskers prepared by use of toluene lost their initial solvated hexagonal structure faster than the C60 nanowhiskers prepared by use of m-xylene. The hexagonal structure of C60 nanowhiskers prepared by use of toluene was stabilized by adding C60[C(COOC2H5)2]. These results suggest that large solute molecules in the C60 nanowhisker matrix stabilize their initially solvated hexagonal structure. Furthermore, the addition of a sufficient amount of C60(2-methoxycarbonyl-N-methylpyrrolidine) into the m-xylene solution of C60 produced the C60 nanowhiskers indicating the formation of ordered solid solution of C60 and C60(2-methoxycarbonyl-N-methylpyrrolidine).
Źródło:
Nukleonika; 2006, 51,suppl.1; 41-48
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of the generally available WIMS versions to modern PWRs
Autorzy:
Kulikowska, T.
Stadnik, A.
Andrzejewski, K.
Boettcher, A.
Powiązania:
https://bibliotekanauki.pl/articles/147884.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
reactor calculations
lattice spectrum code
resonance integrals
gadolinium bearing fuel
Opis:
The generally available versions of WIMS (Winfrith improved multigroup scheme) code have been used at the Institute of Atomic Energy POLATOM (IEA POLATOM, Otwock/Świerk, Poland) for a variety of reactor lattice analyses since 1974. With planned construction of new generation PWRs (power water reactors) in Poland, a question of WIMSD-5B version applicability to lattice calculations of strongly heterogeneous assemblies with gadolinium poisoned pins became actual. The present paper deals with modeling of the fuel assemblies using the version of WIMSD-5B extended at the IEA POLATOM. It was shown that with a careful choice of computational options the code properly describes main physical parameters of modern PWR fuel assemblies.
Źródło:
Nukleonika; 2012, 57, 1; 87-93
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Seasonal variability of the soil CO2 flux and its isotopic composition in southern Poland
Autorzy:
Gorczyca, Z.
Rozanski, K.
Kuc, T.
Michalec, B.
Powiązania:
https://bibliotekanauki.pl/articles/148390.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
carbon-14
carbon-13
isotopic composition
soil CO2
oxygen-18
Opis:
The flux and isotopic composition of soil CO2 has been monitored at three sites located in the southern Poland, during the time period: January 1998 - December 2000. The sites represent typical ecosystems appearing in central Europe: mixed forest, cultivated agricultural field and grassland. To monitor the flux and isotopic composition of soil CO2, the method based on the inverted cup principle was used. The flux of soil CO2 reveals distinct seasonal fluctuations, with maximum values up to ca. 20 mmolźm-2 h-1 during summer and around ten times lower values during winter. Also significant differences among the monitored sites were detected, the CO2 flux being the highest for the mixed forest site and ca. two times lower for the grassland site. The 13C content of the soil CO2 flux is nearly constant throughout the year, with d13C values essentially reflecting the isotopic composition of the soil organic matter and the vegetation type. The 18O content of the soil CO2 flux shows a remarkable seasonality, with distinctly less negative d18O values recorded during summer. This seasonality is highly reduced in the CO2 sampled from different depths of the soil. The radiocarbon content of the CO2 flux turned out to be non-distinguishable, within the uncertainty of the measurements, from current 14C levels in atmospheric carbon dioxide. However, significant reduction of the radiocarbon content was measured in the soil CO2 sampled at 80 cm, when compared to the uppermost layer, reflecting increasing age of soil organic matter with depth.
Źródło:
Nukleonika; 2003, 48, 4; 187-196
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Univalent iron monoazaetioporphyrin complexes studied by Mössbauer spectroscopy
Autorzy:
Kaczmarzyk, T.
Dziliński, K.
Sinyakov, G.
Egorova, G.
Powiązania:
https://bibliotekanauki.pl/articles/148854.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
EPR
iron porphyrins
Mössbauer spectroscopy
reduction reactions
Opis:
Results of Mössbauer and EPR studies of univalent-iron monoazaetioporphyrin complexes [Fe(I)(MAEP)] are presented in this paper. Fe(I)(MAEP) were generated using the chemical reduction method. Three forms of the univalent-iron monoazaetioporphyrin complexes were observed: (I) typical Fe(I)(MAEP), (II) with an additional electron on the porphyrin ligand [Fe(I)(MAEP•)]- and (III) the Fe(I)(MAEPh) phlorin structure. Electron configuration of Fe(I) ions in these complexes is (dxy)2(dxz ,dyz)4(dz 2)1. The [Fe(I)(MAEP•)]- structure is stable only in solution and it is transferred into Fe(I)(MAEP) in the solid state. Mössbauer parameters for all products of the reduction reaction are given.
Źródło:
Nukleonika; 2003, 48,suppl.1; 31-34
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of X-ray fluorescence method for elemental analysis of PM2.5 fraction
Autorzy:
Samek, L.
Furman, L.
Kawik, T.
Welnogorska, K.
Powiązania:
https://bibliotekanauki.pl/articles/971541.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
air pollution
energy dispersive X-ray fluorescence (EDXRF)
elemental analysis
particulate matter
Opis:
The scientific interest in air pollution comes from its influence on human health, the condition of cultural heritage and climate. The PM2.5 fraction (particles of a diameter of 2.5 mm or below), indirectly, has a significant impact on health which is associated with respiratory tract and blood vessel related diseases. However, not only the size, but also the content of the particles has a significant meaning. To determine the particulate matter contents, elemental analysis can be performed using numerous techniques, the most important of which is X-ray fluorescence. In this study, samples of PM2.5 fraction collected in Krakow, Poland were analyzed. The X-ray fluorescence method was used to perform elemental analysis. The gravimetric method was applied to determine the concentration of the PM2.5 fraction. Low detection limits of individual elements and precision of the X-ray fluorescence method were determined. The concentrations of the following elements: Cl, K, Ca, Cr, Mn, Fe, Cu, Zn, Br, Rb, Sr and Pb in the PM2.5 fraction samples collected in Krakow were evaluated. The homogeneity of the samples was also estimated. The concentrations of PM2.5 fraction collected in the summer of 2013 were in the range of 6–23 ng/m3. The concentrations of PM2.5 fraction collected in the winter of 2013 were in the range of 26–171 ng/m3. The precision of the method was found to be below 1% for elements with high concentration in the sample and 6–8 % for trace elements.
Źródło:
Nukleonika; 2015, 60, No. 3, part 2; 621-626
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure of the superficial region and mechanical properties of nitrided cast steels
Autorzy:
Górka, B.
Budzynowski, T. W.
Brzózka, K.
Powiązania:
https://bibliotekanauki.pl/articles/147910.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
cast steel
microhardness
Mössbauer spectroscopy
nitriding
wear resistance
Opis:
A series of cast steels were subjected to two-stage low-temperature nitriding. Mossbauer, XRD and mechanical investigations were carried out for both as-cast and nitriding materials in order to determine phase composition (especially the content of gamma'-Fe4N and epsilon-Fe2-3N), microhardness of the superficial region as well as tribological properties. It has been stated that the relative content of iron-nitrogen phases strongly depends on chemical composition of the cast steel and the effective thickness of the surface layer comprising iron nitrides is less than 0.015 mm. Considerable increase of surface microhardness and wear resistance of nitrided specimens in comparison with their as-cast counterparts has been observed. It has been found that the values of microhardness of nitrided samples at the surface are above twice larger than those in the core.
Źródło:
Nukleonika; 2013, 58, 1; 117-121
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 57

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