- Tytuł:
-
Ewaluacja sweet spotów w polskich formacjach łupkowych w odniesieniu do wybranych parametrów geochemicznych
Evaluation of sweet spots in Polish shale formations in relation to the selected geochemical parameters - Autorzy:
-
Matyasik, Irena
Janiga, Marek
Spunda, Karol - Powiązania:
- https://bibliotekanauki.pl/articles/1834245.pdf
- Data publikacji:
- 2020
- Wydawca:
- Instytut Nafty i Gazu - Państwowy Instytut Badawczy
- Tematy:
-
sweet spot
substancja organiczna
dojrzałość termiczna
gaz z formacji łupkowych
skład izotopowy
organic matter
thermal maturity
shale gas
isotopic composition - Opis:
- The article focuses on the geochemical parameters of key importance to the assessment of the hydrocarbon potential of shale formations (the content of organic matter and its thermal maturity and degree of transformation). A comparative analysis of the measurements of gas obtained in the process of core desorption with the analysis of saturations obtained from Rock-Eval pyrolysis was performed. Percentage of retained free hydrocarbons in source levels at the calculated generation was determined. Large discrepancies were observed between the measured reflectance values of vitrinite-like macerals or on zooclasts and the calculated VR values from the Tmax parameter. This means limited applicability and universality of Jarvie formula (Wüst, 2013). A new conversion formula was calculated based on a large sample population. Additionally, the article presents the results of isotopic composition analyzes. Large differences in the δ13C methane, ethane and propane values were stated between the wells. The content of higher hydrocarbons in the gas composition is very high, which may indicate thermogenic origin. Most samples are oil-related gas and mixed gas, one sample is condensate related gas (Peters chart). The gas generation from both wells corresponds to the range of the oil window to the beginning of the gas window (VR from about 0.6 to about 1.35%) (Peters et al., 2005). In addition, using data from degasification experiments (total gas quantities) and pyrolysis parameters obtained from Rock Eval analyzes (Tmax and TOC), it was found that the correlation between the maturity of the source organic matter (determined on the basis of Tmax) and the amounts of gas is small (r = 0.37 for total gas). In contrast, the correlation between the organic carbon content (TOC) and the amounts of gas is high for total gas (r = 0.70).
- Źródło:
-
Nafta-Gaz; 2020, 76, 2; 76-90
0867-8871 - Pojawia się w:
- Nafta-Gaz
- Dostawca treści:
- Biblioteka Nauki
Artykuł