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Wyszukujesz frazę "oil-water emulsion" wg kryterium: Temat


Wyświetlanie 1-5 z 5
Tytuł:
Spectrum of light absorption as the indicator of lubricate oil dispsersed in the natural water
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/247346.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
lubricate oil
absorption
absorption spectra of dispersed oil oil-in-water emulsion
Opis:
Oil pollutants in the natural water masses – especially in the seawater column – can be found in two forms, namely as dissolved oil or as dispersed one. With a broad set of methods, for studying the complex structure of petroleum products, due to the ability of petroleum products to absorb UV-light, absorbance spectra could be a relevant indicator to oil identification in aquatic environment and could support methods provided by the fluorescence technique. The intention of the study described in this article is to characterise the absorption properties of lubricate oil possible to found in the marine environment. Two types of oil as the representative of lubricate oils using in the ship engines are considered. One form of oil possible to found in the marine environment – oil-in-water emulsion was taken into account for analysis. Dispersed in water lubricate oil samples were prepared for several oil concentration for each type of oil. Spectrofluorometer Aqualog Horiba was used to register the absorbance spectra of oils. Based on the Lambert-Beer law the absorbance spectra were derived and specific parameter – absorption coefficient – for each wavelength of excitation, in the range 240-600 nm, was determined. Obtained results indicate decreasing of the oil absorbance value when excitation wavelength increases. Moreover, basing on the absorbance spectra it could be concluded that the main maximum for this kind of oils is located below 240 nm. However, in the considered range of excitation wavelength small flat peak, centred about 265 nm for both types of oils, was detected. Therefore one could conclude that absorbance of oils could be used as the indicator to detect of oil pollution in the natural environment omitting the labour intensive chemical methodology.
Źródło:
Journal of KONES; 2016, 23, 1; 61-66
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Light absorption properties of ‘Petrobaltic’ oil-in-water emulsion present in seawater
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246640.pdf
Data publikacji:
2018
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
crude oil, absorbance
absorption spectra of dispersed oil
absorption coefficient
oil-in-water emulsion
Opis:
In the article, the characteristic of crude oil ‘Petrobaltic’ potentially present in the Baltic Sea water masses is considered in relation to the protection of marine environment. The main spectroscopic method to characterize various oils (crudes and refinery products like fuels and lubricating oils) is fluorescence. However, the absorbance measurements of oils are necessary due to the partial overlapping the spectra of natural seawater components and oil substances. Therefore, properties of crude oil are considered to expand the basis of spectroscopic properties of oils – typical marine organic pollutants – based on absorption measurements. Oils potentially found in the marine environment are, in addition to surface forms, also in-depth ones as oil-in-water emulsion. Therefore, in the article crude oil as oil-in-water emulsion form is considered. As a solvent demineralised water with salinity, corresponding to Baltic Sea salinity was used. Several concentrations of dispersed crude oil were prepared. The absorbance spectra in the UV and visual range of the light in the range from 240 to 600 nm, for each prepared samples are discussed. Based on the Lambert-Beer law for each wavelength of excitation, in the range 240-600 nm, the specific parameter absorption coefficient was determined. Obtained results indicate the rapid decreasing of the absorbance for this kind of oil in the wavelength range from 240 nm to 420 nm. However, in the shape of absorbance spectra is observed the characteristic wide and flat peak located at 260 nm for excitation wavelength, which could be a specific point for this kind of oil.
Źródło:
Journal of KONES; 2018, 25, 3; 59-64
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Emulsified fuels of machine origin in seawater - a contribute to remote detection
Autorzy:
Rudz, K.
Powiązania:
https://bibliotekanauki.pl/articles/246040.pdf
Data publikacji:
2011
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil pollution
remote sensing reflectance
Monte Carlo simulation
radiative transfer
oil-in-water emulsion
Opis:
Development of industry and trade in the last few decades caused a huge increase in the pollution of the world's oceans. Substantial contributors to marine pollution come with the rivers from land-based sources including the by products of industry, run-off from agriculture activities such as biocides as well as effluents from urban areas. Moreover, a significant amount of marine pollution is caused by shipping and maritime activities. The operation of ship plants gives a real possibility for engine oils and fuels to reach the marine environment. Discharge waters contain a certain amount of petroleum derivatives in the form of dispersed droplets (oil-in-water emulsion). The presence of oil emulsion cause measurable changes in the optical properties of seawater. It is conceptually possible to detect these changes using a standard radiance or irradiance reflectance meter. Hence, a set of radiative transfer simulation has been carried out. This paper presents a computed photon trace simulation based on the Monte Carlo code, applied to the marine environment. The results are presented as reflectance spectra for the models of Baltic Sea and ocean water both pure and polluted by oil emulsion. It is shown that even small amounts of petroleum pollution raise the values of irradiance reflectance and cause a spectral shift by certain conditions. A possibility for remote evaluation of oil pollution is discussed as well as the perspective for improving the interpretation of shipboard and offshore light field analyses.
Źródło:
Journal of KONES; 2011, 18, 3; 375-381
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Emulsified fuels of machine origin in seawater - a contribute to remote detection
Autorzy:
Rudz, K.
Powiązania:
https://bibliotekanauki.pl/articles/242232.pdf
Data publikacji:
2011
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil pollution
remote sensing reflectance
Monte Carlo simulation
radiative transfer
oil-in-water emulsion
Opis:
Development of industry and trade in the last few decades caused a huge increase in the pollution of the world's oceans. Substantial contributors to marine pollution come with the rivers from land-based sources including the by-products of industry, run-off from agriculture activities such as biocides as well as effluents from urban areas. Moreover, a significant amount of marine pollution is caused by shipping and maritime activities. The operation of ship plants gives a real possibility for engine oils and fuels to reach the marine environment. Discharge waters contain a certain amount of petroleum derivatives in the form of dispersed droplets (oil-in-water emulsion). The presence of oil emulsion cause measurable changes in the optical properties of seawater. It is conceptually possible to detect these changes using a standard radiance or irradiance reflectance meter. Hence, a set of radiative transfer simulation has been carried out. This paper presents a computed photon trace simulation based on the Monte Carlo code, applied to the marine environment. The results are presented as reflectance spectra for the models of Baltic Sea and ocean water both pure and polluted by oil emulsion. It is shown that even small amounts of petroleum pollution rise the values of irradiance reflectance and cause a spectral shift by certain conditions. A possibility for remote evaluation of oil pollution is discussed as well as the perspective for improving the interpretation of shipboard and offshore light field analyses.
Źródło:
Journal of KONES; 2011, 18, 2; 385-390
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modelling of seawater polluted by light and heavy crude oil droplets
Autorzy:
Rudź, K.
Darecki, M.
Toczek, H.
Powiązania:
https://bibliotekanauki.pl/articles/246668.pdf
Data publikacji:
2012
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil pollution
remote sensing reflectance
Monte Carlo simulation
radiative transfer
oil-in-water emulsion
Opis:
Significant amounts of crude oil transported from offshore fields to the refineries using tankers or pipelines, demand increased control of seawater pollution. Tanker accidents resulting in oil spills drive much attention, as they influence local marine life and coastal industry. However, the most significant annual amount of crude oil enters the sea in the form of oilin- water emulsion as a result of standard tanker operations, offshore oil extraction and daily work of refineries. Many branches of science are challenged to provide new methods for oil detection, less expensive, more sensitive and more accurate. Remote satellite or airborne detection of large oil spills is possible using joint techniques as microwave radars, ultraviolet laser fluorosensors and infrared radars. Some methods are capable to deal with oil streaks detection and estimation of oil thickness. Although there is currently, no method to detect small concentration of oil droplets dispersed in seawater. Oil droplets become additional absorbents and attenuators in water body. They significantly change seawater inherent optical properties, which imply the change of apparent optical properties, detectable using remote sensing techniques. To enable remote optical detection of oil-in-water emulsion, a study of optical properties of two types of crude oil was conducted. Radiative transfer theory was applied to quantify the contribution of oil emulsion to remote sensing reflectance (Rrs). Spectra of Rrs from in situ measurements in Baltic Sea were compared to Rrs spectra of seawater polluted by 1 ppm of crude oil emulsion, collected using radiative transfer simulation. The light crude oil caused a 9-10% increase of Rrs while the heavy one reduced Rrs up to 30% (model accuracy stayed within 5% for considered spectral range). Results are discussed concerning their application to shipboard and offshore oil content detection.
Źródło:
Journal of KONES; 2012, 19, 2; 473-480
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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