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Wyszukujesz frazę "phosphate adsorption" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Adsorption Kinetics of Edamame Soybean Peel Activated Carbon in Reducing the Level of Phosphate
Autorzy:
Eri, Iva Rustanti
Pramudinta, Namira Kholifatul
Nurmayanti, Demes
Powiązania:
https://bibliotekanauki.pl/articles/2027815.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorption kinetics
activated carbon
phosphate
Opis:
Domestic wastewater, such as detergent wastewater, causes the increase of the phosphate level that strongly contributes to eutrophication. Adsorption is a method that can be used to reduce the levels of phosphate. The natural ingredients that can be made as activated carbon include edamame soybean peel, because it contains a lot of celluloses. This research aimed to analyze the adsorption kinetics and adsorption capacity of edamame soybean peel activated carbon in reducing the phosphate levels. Adsorption was carried out with batch method with various concentrations of adsorbate (2 mg/L, 4 mg/L, and 6 mg/L) and stirring time (3 hours, 6 hours, 9 hours, and 12 hours). The results showed that the highest adsorption capacity was found in 6 mg/L of adsorbate concentration and 6 hours of stirring time. The results were validated by the Langmuir isotherm and pseudo-second-order adsorption kinetics model. The Langmuir isotherm indicated that adsorption occurred in monolayer. The maximum adsorption capacity was 0.43509 mg/g and the constant of adsorption kinetics was 1.5558 g/mg•min. Activated carbon from edamame soybean peel successfully reduced the levels of phosphate. The increase of adsorption capacity was correlated with the increasing concentration of adsorbate and stirring time until the equilibrium.
Źródło:
Journal of Ecological Engineering; 2022, 23, 2; 97-107
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Magnetite Oxide Nanoparticles and Tungsten Oxide Nanoparticles on Phosphate Removal from Aqueous Solutions
Autorzy:
EL-Baz, Amro
Mokhtar, Mona
Abdo, Ahmed
Powiązania:
https://bibliotekanauki.pl/articles/24201790.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
phosphate removal
nanoparticles
Fe3O4 NPs
WO3 NPs
adsorption
desorption
Opis:
Phosphate (P) removal from aqueous solutions were studied by a new mineral adsorbent, tungsten (VI) oxide (WO3) nanoparticles (NPs), which has not been the subject of much research in the field of removing P contaminants from agricultural wastewater. In this paper, P was removed from aqueous solutions by a new mineral adsorbent, WO3 NPs and it was compared with magnetite (iron IV) oxide (Fe3O4) nanoparticles (NPs) under the same ambient operating conditions i.e., The influence of the dosage of adsorbents, initial P concentration, contact time, pH and temperature. The values that achieved the best removal were recorded. It was concluded that the best limits for pH were at 2–3, contact time at 40 minutes, temperature at 45 °C and adsorbent dose at 1.0 g/L. Best results of the variables were applied on samples of real agricultural wastewater, which achieved removal ratio of 77.3% and 75.42% for Fe3O4 and WO3 NPs, respectively. SEM, EDX and FTIR images and analyses were conducted to describe the characteristics of nano-adsorbents used before and after P adsorption in aqueous solutions. The P adsorption kinetics for aqueous solutions were examined by fitting results of the experiment to both the first & second pseudo-kinetically models. The outcome indicated that kinematic data fit better with pseudo-second-order kinetic models. Moreover, the information captured from equilibrium adsorption was analyzed using isothermal methods (by Langmuir & Freundlich Forms). Their results showed that the Freundlich form is considered more suitable than Langmuir form in analyzing the biosorption of P ions. The thermodynamic demeanor of P adsorption by Fe3O4 and WO3 NPs was analyzed and evaluated, and the thermodynamic data analyses confirmed the process of P adsorption was spontaneous. The ΔG° value was negative, while ΔH° and ΔS° values found to be positive, which means that the adsorption of P was a spontaneous, random and endothermic operation. In general, Fe3O4 and WO3 nanoparticles had a high efficiency in removing phosphate from water. In addition, WO3 NPs has been identified as one of the most promising adsorbents due to its rapid and effective adsorption of pollutants.
Źródło:
Journal of Ecological Engineering; 2023, 24, 3; 287--303
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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