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Wyświetlanie 1-2 z 2
Tytuł:
Estimation of the Efficiency of Ammonia Oxidation in Anolyte of Two-Chamber Electrolyzer
Autorzy:
Gomelya, Mykola
Shabliy, Tetyana
Radovenchyk, Iaroslav
Overchenko, Tetyana
Halysh, Vita
Powiązania:
https://bibliotekanauki.pl/articles/123631.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
ammonia
electrolysis
anolyte
catholyte
anion exchange membrane MA-41
Opis:
In this study, the processes of electrochemical oxidation of ammonia in a two-chamber electrolyzer with anion exchange membrane MA-41 were investigated. An estimation of the efficiency of the process of oxidation of ammonia, depending on the chemical composition of the initial solution of anolyte and catholyte, current density and time of electrolysis was carried out. It was shown that the oxidation of ammonia in the anode chamber passes quickly and is accompanied by a significant decrease in pH due to the formation of nitrogen dioxide and nitrates. At the same time, the current output and the electrical conductivity of the dilute solutions was rather low. The effect of chlorides on the process of electrolysis was investigated. It was shown that the presence of chlorides in the anolyte catalyzes the processes of oxidation of ammonia. An increase in the concentration of chlorides in the anolyte increases output and reduces electricity consumption. The presence of chlorides in the catholyte does not accelerate oxidation. The presence of sulfates, both in the anolyte and in the catholyte, slows down the process of oxidation of ammonia as a result of the oxidation of sulfates to persulfates, which are quite passive to ammonium ions. At the same time, electricity consumption increases.
Źródło:
Journal of Ecological Engineering; 2019, 20, 5; 121-129
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assessment of Ras El Ma Karst Spring Features by Structural and Functional Approaches at the Region of Taza, Morocco
Autorzy:
Naoura, Jamal
El Kati, Imad
Benaabidate, Lahcen
Powiązania:
https://bibliotekanauki.pl/articles/1955574.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
karst aquifer
hydrogeological functioning
Ras El Ma spring
model of Mangin
Morocco
Opis:
This work performed by considering two complementary approaches for investigating the Karst system of Ras El Ma source: (1) The structural approach based on field studies, (2) The functional approach requiring inputs data (precipitations) as well as output data at the exit of the karstic system. The choice of the Ras El Ma source is justified by the fact that it constitutes the main outlet of the Liassic aquifer at the Southwest of Taza town. The structural approach highlighted that the impact of South Rifan and North Middle Atlas faults, oriented mainly NE-SW to ENE-WSW and NW-SE, tectonically linked to the Hercynian and late-Hercynian phases; these faults compartmentalized the karst into panels. The functioning of this karst system is based on the coupling of inputs and outputs, the analysis of interannual hydrograph, flood hydrographs, the recession curves and the analysis of hydrogeochemical results. Respectively, the obtained results are presented as follows: A close relationship between flow rates and precipitation, interannual hydrographs marked by a contrasting variation in flow rates and a periodicity that occurs between low water and high-water years. Concerning flood hydrographs, there are two types, a unit modal hydrographs type which generally occurs following time concentrated rainfall and a second multi modal hydrographs type which follows the repetitive rainfall in the basin. The study of recession curves reveals a clear complexity of the systems supplying the source. However, due to the low drying-off coefficients (7.66∙10-4), the aquifer seems to have a poorly developed drainage network in a flooded area. According to the Mangin method [1975], this karstic system is classified in the category of poor or complex karst systems taking into accounts two parameters (i) and (K), which characterize the functioning of the infiltration zone and the volume of flooded karst, respectively. The physicochemical parameters study highlighted the nature of drained rock by the sources. The correlation between conductivity and different chemical elements shows that bicarbonates and calcium are responsible for the mineralization of the waters of this source. It can be concluded that the low values of mineralization occur during the winter and spring floods. The spring regains its normal mineralization during the summer period.
Źródło:
Journal of Ecological Engineering; 2021, 22, 9; 32-47
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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