Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Centralna Biblioteka Wojskowa Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaCentralna Biblioteka Wojskowa

Wyszukujesz frazę "thermodynamic" wg kryterium: Temat

  Lista filtrów
Wyrównaj
    Wyświetlanie 1-6 z 6
    Tytuł:
    Solubility of a pharmacological intermediate drug Isatin in different solvents at various temperatures
    Autorzy:
    Baluja, S.
    Bhalodia, R.
    Bhatt, M.
    Vekariya, N.
    Gajera, R.
    Powiązania:
    https://bibliotekanauki.pl/articles/412531.pdf
    Data publikacji:
    2013
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    Isatin
    solubility
    Thermodynamic parameters
    Opis:
    The solubility of isatin in different solvents was studied by a gravimetrical method from (298.15 to 318.15) K under atmospheric pressure and the solubility data were correlated against temperature. The solvents selected for the present study are: water, methanol, ethanol, 1-butanol, dichloromethane, dichloroethane, chloroform and carbon tetra chloride. Among chlorinated solvents, solubility is observed to be maximum in 1, 2-dichloroethane and minimum in dichloromethane whereas in alcohols, maximum solubility is observed in methanol. In water, solubility is found to be minimum. Further, some thermodynamic parameters such as Gibb’s energy (ΔGsol), heat of solution (ΔHsol) and entropy of solution (ΔSsol) have also been evaluated.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2013, 12; 36-46
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Acoustical studies of binary liquid mixtures of p-chlorotoluene in benzene at different temperatures
    Autorzy:
    Kumar, G. P.
    Babu, Ch. P.
    Samatha, K
    Jyosthna, A. N.
    Showrilu, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/412275.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ultrasonic velocity
    thermodynamic parameters
    p-chlorotoluene
    molecular interactions
    Opis:
    Ultrasonic velocities (U), densities (ρ), and coefficient of viscosities (η) are measured for binary mixtures containing (i) p-chlorotoluene and (ii) benzene at 303.15 K, 308.15 K, 313.15 K and 318.15 K to understand the molecular interaction. Various acoustical parameters such as adiabatic compressibility (βad), free length (Lf), acoustic impedance (Z), free volume (Vf), molar volume (Vm), Rao’s constant (R), Wada’s constant (W) and internal pressure (πi), are calculated from the measured values of U, ρ, and η. The trend in acoustical parameters also substantiates to asses strong molecular interactions.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 10; 25-37
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Chalcones: A Solubility study at different temperatures
    Autorzy:
    Bhalu, A. A.
    Bhesaniya, K. D.
    Vekariya, N. J.
    Baluja, S. H.
    Powiązania:
    https://bibliotekanauki.pl/articles/412118.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    Chloroform
    dichloromethane
    thermodynamic parameters
    dissolution enthalpy
    Gibb’s energy and en tropy
    Opis:
    Some new chalcones are synthesized by the condensation of aryl ketones with aromatic aldehydes and solubility of these synthesized chalcones is determined in chloroform and dichloromethane at temperatures ranging between 293.15 K and 313.15 K by gravimetric method. The experimental data was correlated well with modified Apelblat equation. Further, from the experimental solubility data, some thermodynamic parameters such as dissolution enthalpy, Gibb’s energy and entropy etc. were evaluated using van’t Hoff equation. The positive Gibb’s energy and negative entropy suggests spontaneous dissolution and more ordered structure in solution.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 12; 7-19
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Ion-exchange reaction thermodynamics to study the selectivity behaviour of nuclear and non-nuclear grade anion exchange resins
    Autorzy:
    Singare, P. U.
    Patange, A. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412083.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ionic selectivity
    uni-univalent exchange
    thermodynamic equilibrium constant
    enthalpy
    nuclear grade ion exchange resin
    Auchlite ARA-9366
    Auchlite A-378
    Opis:
    In the present investigation, attempts were made to understand the difference in bromide ion selectivity of the two closely related anion exchange resins Auchlite ARA-9366 and Auchlite A-378 in chloride form. The selectivity difference was predicted based on the thermodynamic equilibrium constants and enthalpy values of Clˉ/Brˉ ion exchange reactions performed by using the two resins. During Clˉ/Brˉ exchange reactions, with rise in temperature from 30.0 °C to 45.0 °C, the equilibrium constant (K) values were observed to decreases from 8.15x10-2 to 6.06x10-2 for Auchlite ARA-9366 resins and from 2.16x10-2 to 1.10x10-2 for Auchlite A-378 resins. The decrease in K values with rise in temperature, indicate exothermic ion exchange reactions having enthalpy values of -36.14 and -18.38 kJ/mol respectively. The high K and low enthalpy values obtained for Auchlite ARA-9366 resins indicate their greater selectivity for the bromide ions in the solution as compared to Auchlite A-378 resins.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 6; 8-15
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermodynamics of Ion-exchange reaction in predicting the ionic selectivity of Auchlite ARA-9366 and Auchlite A-378 anion exchange resins
    Autorzy:
    Singare, P. U.
    Patange, A. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412499.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ionic selectivity
    uni-univalent exchange
    thermodynamic equilibrium constant
    enthalpy
    nuclear grade ion exchange resin
    Auchlite ARA-9366
    Auchlite A-378
    Opis:
    The paper deals with predicting the iodide ion selectivity of nuclear and non-nuclear grade anion exchange resins. The ionic selectivity prediction was made on the basis of thermodynamic data of Clˉ/I ˉ ion exchange reaction. It was observed that with rise in temperature from 30.0 °C to 45.0 °C, the equilibrium constant (K) values were observed to decreases from 59.77x10-2 to 23.77x10-2 for Auchlite ARA-9366 resins and from 9.01x10-2 to 4.05x10-2 for Auchlite A-378 resins. The decrease in K values with rise in temperature, indicate exothermic ion exchange reactions having enthalpy values of -47.87 and -39.51 kJ/mol respectively. The high K and low enthalpy values obtained for Auchlite ARA-9366 resins indicate their greater selectivity for the iodide ions in the solution as compared to Auchlite A-378 resins, when both the resins are present in chloride form.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 6; 1-7
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermodynamic Characteristics of Solid
    Autorzy:
    Pluta, Z.
    Hryniewicz, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/411946.pdf
    Data publikacji:
    2013
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    thermodynamic characteristics
    interstate space
    hermodynamics
    solid
    potential field
    specific proper heat energy
    specific gained heat energy
    energetic band
    heat work
    source characteristics of entropy growth
    entropy constant
    Opis:
    The paper is to present the developed thermodynamic characteristics of a solid. The existent description of dependence of temperature on the proper entropy (thermal capacitance) was used as the beginning point of the considerations. A critical evaluation of the picture of that dependence was a consecutive link of the considerations. Furthermore, an adequate description of the discussed heat phenomenon, taking into account the detailed characteristics of the entropy growth characteristics, has been presented. This characteristics indicates a clear quantum character of the studied reality, reflected by the potentials, proper and gained, respectively. These magnitudes are the measures of the proper and gained specific energies of this thermodynamic factor. The dependence of temperature on the specific energy has been described to formulate a formula on the heat work. At the end the dependence between the specific heat and the entropy constant is derived. In conclusion, a quantum nature of macroscopic reality has been noticed together with the definition of the heat energy notion. The necessity of noticing the description of any other reality in this scale has been indicated.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2013, 2; 60-71
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

      Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies