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Wyszukujesz frazę ""elements"" wg kryterium: Temat


Tytuł:
Tectonic discrimination of siliciclastic sedimentary record of the northern Tethyan margin at the end of the Triassic
Autorzy:
Vďačný, Marek
Michalík, Josef
Lintnerová, Otília
Powiązania:
https://bibliotekanauki.pl/articles/2058608.pdf
Data publikacji:
2019
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
sedimentology
geodynamics
major elements
trace elements
palaeogeography
Opis:
Tectonic setting of both the uppermost Triassic Tomanová and the lowermost Jurassic Dudziniec formations can be characterized by a series of diagnostic discrimination diagrams. High-silica and low-silica multi-dimensional diagrams indicate that the sediments could have been deposited in the continental collision/rift setting. Diagrams of K2O/Na2O versus SiO2, SiO2/Al2O3 versus K2O/Na2O and Th-Co-Zr/10 as well as Th-Sc-Zr/10 determine an origin from the tectonically active and/or passive continental margin setting. REE parameters indicate predominantly a passive margin tectonic setting of the sediments. The most probable source of clastic admixture in the Scythian to Domerian sediments in the Tatric Unit was situated in a remnant of the Variscan collisional orogen - the Vindelician Highlands. Occasional monsoonal rains occurring in orbitally controlled cycles transported weathered material from the source area down river valleys on the seaward slopes of the Variscan Vindelician Mountains towards the Tethyan Sea. The input of this material influenced also the marginal parts of the Fatricum (e.g., Vysoká or Havran units).
Źródło:
Geological Quarterly; 2019, 63, 1; 30--38
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Vertical distribution patterns of trace and major elements within soil profile in Lithuania
Autorzy:
Gregorauskiene, V.
Kadunas, V.
Powiązania:
https://bibliotekanauki.pl/articles/2058924.pdf
Data publikacji:
2006
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Lithuania
complete soil profile
accumulative elements
removable elements
total element contents
variability
Opis:
The vertical distribution of the total contents assayed by Dc-Arc ES analysis of 28 trace elements and 6 major elements measured by ICP-MS within 53 complete soil profiles in Lithuania are presented. Models of the soil profiles were created, each having the master soil horizons A, E, B and C. Median values of elements in the master horizons of different texture were used in place of missing samples, while aberrant samples were discarded. The absolute average deviation () was taken to measure the variability of the data subsets and thus to check the reliability of location of the element contents within the soil profile. Within the context of the different actions of the various soil-forming processes (podzolization, lessivage, gleyfication, humification and so on) the general patterns of vertical element distribution were revealed. Element depletion is dominant in the soils of Lithuania. Themost easily removed are the alkaline elements Ca and Mg, while U, B, Th, As, Co, Cr, Sr, Y, Mo, La, Sc, Yb, Ti, P and K are depleted through the whole soil profile. Ag, Pb, Sn and Mn were defined as the accumulative elements in the surface A-horizon and might be influenced by anthropogenic or biogenic processes. A relative accumulation of Zr, Ba and Nb was observed in the surface A-horizon, and this seems to be related to the weathering of resistant minerals. Levels of Fe, Li, Al, V, Zn, Ga, Ni, Cu and Rb were ascribed to elements precipitated in the soil illuvial B-horizon due to soil formation processes. Na, K, Sr, B, U, As, Co Rb and Yb were found to be the most immobile elements within typical soil profiles, while Ag, Zn, Sc, Ba, Cu, Zr, Fe La, Th and Ca are themostmobile elements and affected by a variety of natural and human factors.
Źródło:
Geological Quarterly; 2006, 50, 2; 229-237
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Indium in polymetallic mineralisation at the Gierczyn mine, Karkonosze-Izera Massif, Poland : results of EPMA and LA-ICP-MS investigations
Autorzy:
Foltyn, Krzysztof
Bertrandsson Erlandsson, Viktor
Kozub-Budzyń, Gabriela Anna
Melcher, Frank
Piestrzyński, Adam
Powiązania:
https://bibliotekanauki.pl/articles/2058542.pdf
Data publikacji:
2020
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Gierczyn
indium
trace elements
metamorphism
Opis:
Cassiterite and base-metal mineralisation from the Gierczyn mine on the Karkonosze-Izera Massif, Poland has been studied using electron microprobe and LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) techniques in order to determine the content of indium in the ore minerals. The main carriers of this element are sphalerite (up to 433 μ/g of In), chalcopyrite (up to 117 μ/g of In) and cassiterite (up to 0.02 wt.% In). Trace element contents of sulphides, especially Ga in chalcopyrite intergrown with sphalerite in comparison with chalcopyrite without sphalerite, may indicate metamorphic re-equlibration and suggests that the ore minerals might recrystallized and underwent metamorphism in conditions of greenschist/amphibolite facies. Although the deposits in the Stara Kamienica Schist Belt are not of economic value, they can contribute to better understanding of the relations between trace element partitioning and the formation of ore minerals.
Źródło:
Geological Quarterly; 2020, 64, 1; 74--85
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemical and morphological characterization of polymetallic (Mn-Fe) nodules from the Clarion-Clipperton Zone in the Pacific Ocean
Autorzy:
Kozłowska-Roman, Agata
Mikulski, Stanisław
Powiązania:
https://bibliotekanauki.pl/articles/2058694.pdf
Data publikacji:
2021
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
polymetallic nodules
critical elements
rare earth elements
deep-sea mining
Clarion-Clipperton Fracture Zone
Pacific
Opis:
Geochemical studies (WD-XRF, ICP-MS, and GF-AAS) have shown that polymetallic nodules from the eastern Clarion-Clipperton Zone (CCZ) in the Pacific Ocean are enriched in several metals such as Cu (mean 1.16%), Ni (1.15%), Co (0.15%), and Zn (0.14%), as well as remarkable contents of Mo (0.059%), V (0.04%), Ce (0.019%), Nd (0.011%), Li (0.015), and Pt (43 ppb). The average content of REE, together with Y and Sc, is 620 ppm. In nodules from the CCZ metal concentrations are often much higher than those reported in nodules from other ocean basins in the world. The bulk-nodule mean value of the Mn/Fe ratio is 5.3, which is characteristic for a mixed (hydrogenetic and diagenetic) origin of the nodules. Microprobe investigation revealed two different chemical compositions of the layers, and ascertained their general metal content. The nodules analyzed are composed mainly of concentric-collomorphic laminae of Mn and Fe (oxy)hydroxides which crystallized around mineral nuclei (e.g., quartz, clay minerals), bioclasts or rock fragments. They are from 3.3 to 7.6 cm in diameter. The chemical and physical properties of the laminae allowed distinction of two genetic types: hydrogenetic and diagenetic. Those formed as a result of hydrogenesis had increased values of Co, Si, Cl and S, while formed diagenetically showed increased levels of Cu, Ni, Mg, Zn and K. These lamina types are characterized by different growth structures, reflectivity, density and Mn/Fe ratios. The ratio of the diagenetic layers to hydrogenetic layers (192/53) in representative polymetallic nodules shows that the nodules of this study are of mixed hydrogenetic-diagenetic type. A mixed genesis was also shown by discriminant diagrams, with these CCZ samples being located at the transition between typical hydrogenetic and diagenetic fields.
Źródło:
Geological Quarterly; 2021, 65, 4; 177--194
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemical composition of soil and lake sediments - an indicator of geological processes in Lithuania
Autorzy:
Gregorauskiene, V.
Kadunas, V.
Powiązania:
https://bibliotekanauki.pl/articles/2059444.pdf
Data publikacji:
2000
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Lithuania
trace elements
soil
lake sediments
geoindicators
Opis:
Long-term multipurpose geochemical studies in Lithuania show that the chemical composition of surface sediment can be used as an indicator of geological process: duration of weathering, soil formation and thickness of sediment. The chemical composition of upper and lower soil layers and of lake sediments gives information on past sedimentation: the type and age of Quaternary deposits and the location and depth of Pleistocene glaciolacustrine basins. We therefore have a baseline to predict changes in surface chemistry provoked by current anthropogenic pressures.
Źródło:
Geological Quarterly; 2000, 44, 4; 347-354
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Lithologically-related rare earth element variations the Mio-Pliocene Poznań Formation (Poland)
Autorzy:
Retka, J.
Powiązania:
https://bibliotekanauki.pl/articles/2059369.pdf
Data publikacji:
2018
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Poznań Formation
rare earth elements
clay lithotypes
Opis:
Concentrations of rare earth elements (REEs) were determined in 129 clay samples collected from the Mio-Pliocene Poznań Formation in Poland. The REEs occur in a relatively wide range from 58.2 to 1,709 mg/kg. Low North American Shale Composite (NASC)-normalized total REE contents with heavy rare earth element (HREE) depletion were noted in most of the samples analysed. Small variations were detected in the REE contents in the lithologies distinguished. Red clays are characterised by slightly lower REE concentrations relative to green and grey clays. All the Poznań Formation clays exhibit a negative Eu anomaly when normalized to the average of chondrites. Values increase according to the following sequence: grey clays < red clays < green clays. The NASC-normalized REE concentration curves show a positive Eu anomaly. The LaNASC/YbNASC ratio indicates HREE depletion. A small variation in this ratio was observed in the sequence green clays > grey clays > red clays. The variability of the REE contents of the Poznań Formation decreased from west to east.
Źródło:
Geological Quarterly; 2018, 62, 1; 146--154
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Controls on the distribution of rare earth elements in the Kupferschiefer series of SW Poland
Autorzy:
Oszczepalski, S.
Chmielewski, A.
Mikulski, S.
Powiązania:
https://bibliotekanauki.pl/articles/2060523.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
rare earth elements (REE)
redistribution
Kupferschiefer
Zechstein
SW Poland
Opis:
This study deals with the spatial distribution and the PAAS-normalized patterns of rare earth elements (REE) studied by ICP-MS in the Kupferschiefer series of SW Poland. The most characteristic feature is a progressive enrichment in REE content (including Y and Sc) outward from the rocks with pyritic and Pb-Zn mineralisation, across the rocks with copper mineralisation, towards the oxidized (Rote Fäule) areas. The same trend can also be observed with respect to LREE, MREE and HREE. Whereas REE distribution diagrams for shales with pyrite and Pb-Zn mineralisation are almost flat, diagrams for shales with hematite and copper mineralisation are convex-upward and the strongest convexity is attributed to the transition from hematitic alteration to copper-rich rocks. REE distribution diagrams normalized to PAAS show strong MREE enrichment relative to LREE and HREE, which is typically the highest in the hematite zone, lower in shale with copper mineralisation, and the lowest in shales with Pb-Zn and pyrite mineralisation. The systematic increase in the concentration of REE towards the Rote Fäule, and the strong enrichment in MREE in the transition zone are indicative of variable intensity of leaching and formation of the REE enrichments (including MREE) by MREE>HREE>LREE fluids, as evidenced by the MREE-enriched signatures. Overprinting of secondary enrichments over the original REE pattern due to redistribution along the pathways of expanding fluids are postulated to account for the apparent differences in the distribution and concentration of REE (including the MREE-enriched trend) between the oxidized rocks, copper-bearing rocks, and reduced lithologies barren in copper.
Źródło:
Geological Quarterly; 2016, 60, 4; 811--826
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Trace element geochemistry of the Early to Late Cretaceous deposits of the Grajcarek thrust-sheets - a palaeoenvironmental approach (Małe Pieniny Mts., Pieniny Klippen Belt, Poland)
Autorzy:
Wójcik-Tabol, P.
Oszczypko, N.
Powiązania:
https://bibliotekanauki.pl/articles/2058965.pdf
Data publikacji:
2012
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Western Carpathians
Grajcarek thrust-sheets
black flysch
trace elements geochemistry
Opis:
The chemical composition of the Cretaceous deposits of the Grajcarek thrust-sheets (Pieniny Klippen Belt, Poland) has been investigated to provide information on palaeoenvironment and provenance of pelagic and turbiditic particles. The material studied shows large variations in terrigenous and biogenic content. Phyllosilicates (mirrored in amounts of Al2O3, average 15 wt.%) and carbonates (6 wt.% of CaO) are common mineral components of the deposits excluding the Cenomanian radiolarian shales (CRS) that are enriched in silica "Immobile" elements may be accommodated by phyllosilicates and accessory minerals (i.e. zircon, xenotime, apatite and Ti-oxides). Heavy minerals are significant within the Szlachtowa Fm. High field strength elements (HFSE) in the Malinowa Fm. are housed in secondary apatite and Fe-oxides. Lithophile trace elements (LILE) concentrations in the material studied are lower/comparable to Post-Archean Australian Shale (PAAS). Ba concentration in the CRS probably reflects enhanced bioproductivity. Interaction between major oxides, distributions of "immobile' and lithophile elements suggest that variation in trace elements through the succession was mainly controlled by the terrigenous input. The material studied was sourced from intermediate to felsic rocks of the Czorsztyn (Oravic) Ridge. The Szlachtowa Fm. and CRS are more mature than others due to low contents of clay minerals. The Szlachtowa Fm. also contains recycled material. The CRS correspond to the oceanic anoxic event 2 (OAE 2) whereas the "Black Flysch" of the Szlachtowa and Opaleniec formations may be related to the Early Cretaceous OAE 1
Źródło:
Geological Quarterly; 2012, 56, 1; 169-186
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Geochemical signatures of pervasive meteoric diagenesis of Early Miocene syn-rift carbonate platform, Red Sea, NW Saudi Arabia
Autorzy:
Al-Ramadan, K.
Powiązania:
https://bibliotekanauki.pl/articles/2060345.pdf
Data publikacji:
2017
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
meteoric diagenesis
carbonate
stable isotopes
trace elements
Red Sea
Miocene
Opis:
Different diagenetic environments have been recognized in the Early Miocene carbonate platform of Musayr Formation in the Red Sea rift area. Early marine diagenesis includes micritisation that occurs as thin envelope around skeletal and non-skeletal grains in low-energy mud dominated facies and isopachous fibrous calcite in high-energy grain-dominated facies. Pervasive meteoric water diagenesis resulted in cementation of the carbonates by coarse-crystalline blocky-drusy calcite and meniscus cements. Depletion of oxygen (avg. –9.08‰), carbon (avg. –1.6‰) isotopes and trace elements concentrations (avg. values of Fe: 1387 ppm; Mn: 1444 ppm; Sr: 419 ppm; Na: 1194 ppm) in conjunction with negative correlation between Mn2+ and oxygen isotope data suggest variable degrees of fluid-rock interactions and pervasive meteoric diagenesis. The formation of meteoric diagenesis in the Musayr Formation can be explained by two subsequent mechanisms: (1) the presence of meteoric lenses during the time of deposition might have been associated with active freshwater input from the hinterland (NE) due to fall in the relative sea level; (2) later uplift episode during Plio-Pleistocene may have also contributed to the pervasive meteoric diagenetic alterations of the carbonates of the Musayr Formation. The first mechanism is supported by the cement stratigraphy where the blocky-drusy cements postdate the meniscus cement. The latter mechanism seems to have more pronounced effect on the alteration of Musayr carbonate sequence by observing the occurence of late cements such as blocky calcite in most of the samples. The impact of meteoric diagenesis on the studied samples suggest that dissolution is less severe than cementation, hence the visible porosity is very low. Understanding the timing of meteoric diagenesis provides useful information about the reservoir quality distribution in syn-rift carbonate sequences.
Źródło:
Geological Quarterly; 2017, 61, 1; 239--250
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Podiform chromitites from the Variscan ophiolite serpentinites of Lower Silesia (SW Poland) : petrologic and tectonic setting implications
Autorzy:
Wojtulek, P. M.
Puziewicz, J.
Ntaflos, T.
Bukała, M.
Powiązania:
https://bibliotekanauki.pl/articles/2060165.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
ophiolite
chromitite
platinum group elements
PGE
supra-subduction setting
Variscan orogeny
Opis:
The Gogołów-Jordanów Serpentinite Massif (GJSM) and the Braszowice-Brzeźnica Massif (BBM) are the largest serpentinite outcrops in the Fore-Sudetic Block (NE part of the Bohemian Massif, Central Europe). The GJSM is a peridotitic member of the Variscan Ślęża Ophiolite (SW Poland). Podiform bodies (veins and pockets) of chromitite are found on the Czernica Hill (GJSM) and on the Grochowiec Hill (BBM) within strongly serpentinized harzburgites which occur several hundred metres below Paleo-Moho. Chromitites consist of rounded chromite grains up to 3 cm across, and of chlorite filling the interstices. The veins are embedded in serpentine-olivine-chlorite aggregates. Relics of Mg-rich olivine (Fo95-96) occur in massive chromitite in the BBM. The bulk-rock total PGEs content is very low (42-166 ppm) and the PGE pattern is negatively sloped towards Pt and Pd and depleted relative to chondrite. The primary chromite I is aluminous (Cr# 0.50-0.52, Mg# 0.60-0.70). The highly aluminous and magnesian (Cr# 0.38, Mg# 0.80) chromite Ia occurs locally in the BBM. The secondary chromite II is enriched in Cr and impoverished in Al (Cr# 0.57-0.69), it replaces chromite I. Both chromite I and II contain small amounts of Ti (<0.14 wt% TiO2). Silicate inclusions in chromite are scarce. The composition and mode of occurrence of both the GJSM and the BBM chromitites are similar, thus they were formed probably under the same conditions. Textures of the chromitites suggest their magmatic origin. Their current geological position indicates their emplacement and crystallization in the uppermost mantle harzburgites occurring below the Moho Transition Zone (MTZ). The chromitites and hosting harzburgites were subjected to the greenschist-facies metamorphic overprint. The moderate Cr# and low PGEs contents suggest that the chromitites originated in the arc setting, thus their host ophiolite is of supra-subduction type.
Źródło:
Geological Quarterly; 2016, 60, 1; 56--66
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The stability of xenotime in high Ca and Ca-Na systems, under experimental conditions of 250–350°C and 200–400 MPa : the implications for fluid-mediated low-temperature processes in granitic rocks
Autorzy:
Budzyń, B.
Kozub-Budzyń, G. A.
Powiązania:
https://bibliotekanauki.pl/articles/2060298.pdf
Data publikacji:
2015
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
xenotime
yttrium fluorapatite
yttrium silicate
rare earth elements (REE)
experimental petrology
Opis:
he stability of xenotime was tested by experiments in the presence of a silicate mineral assemblage and two different fluids, 2M Ca(OH)2 or Na2Si2O5 + H2O, under P-T conditions of 200-400 MPa and 250-350°C. The xenotime was stable in runs with 2M Ca(OH)2, replicating the low-temperature metasomatic alterations of granitic rocks, except in experiment at 350°C and 400 MPa, where some (Y,REE)-rich fluorapatite formed. Experiments with Na2Si2O5 + H2O resulted in significant xenotime alteration and partial replacement by an unknown (Y,HREE)-rich silicate, and in the formation of minor amounts of (Y,REE)-rich fluorapatite. The latter indicate preferential partitioning of Y and REE into silicates over phosphates during low-temperature, metasomatic processes in a high Na-Ca system, similar to peralkaline granitic rocks.
Źródło:
Geological Quarterly; 2015, 59, 2; 316-324
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Trace element variations as a proxy for reconstruction of palaeoenvironmental changes during the Late Aeronian faunal and carbon isotope perturbations: new data from the peri-Gondwanan region
Autorzy:
Pašava, J.
Frýda, J.
Štorch, P.
Powiązania:
https://bibliotekanauki.pl/articles/2060353.pdf
Data publikacji:
2017
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Aeronian
graptolite mass extinction
redox-sensitive trace elements
Barrandian area
Bohemian Massif
Opis:
Trace element variations in the Upper Aeronian (Llandovery, Lower Silurian), deep-water, black shale succession of the Barrandian area (Perunica) were studied across an interval associated with a graptolite mass extinction and global, positive carbon isotope anomaly. The main aim of the paper is to test whether distinct changes in graptolite diversity during Late Aeronian were linked with changes in deep sea water oxygenation. Using multiple geochemical proxies we documented high-frequency changes in oxygenation of sea water from sediments of the convolutus to linnaei (guerichi) biozones. Detailed comparison of graptolite diversity with those high-frequency oxygenation changes suggests that the long-term and step-wise Late Aeronian graptolite crisis was not significantly influenced by changes in oxygen level and thus it probably resulted by another causes. The collapse of global carbon cycle during the Late Aeronian probably only temporarily increased extinction rate of the long-term graptolite crisis and considerably decreased evenness of the uppermost Aeronian graptolite communities. The Aeronian graptolite mass extinction was thus primarily driven by other biotic and/or abiotic causes
Źródło:
Geological Quarterly; 2017, 61, 1; 91--98
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rare earth elements distribution in fine-grained deposits from the uppermost Triassic and Lower Jurassic of the Polish Basin : provenance and weathering of source area
Autorzy:
Brański, P.
Mikulski, S. Z.
Powiązania:
https://bibliotekanauki.pl/articles/2059878.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
rare earth elements (REE)
provenance
palaeoweathering
uppermost Triassic
Lower Jurassic
Polish Basin
Opis:
Nineteen samples of uppermost Triassic and Lower Jurassic claystones and mudstones, which were formed in the epicontinental Polish Basin, were analysed by inductively coupled plasma mass spectrometry (ICP-MS) for rare earth elements (REE) and other selected trace elements (Sc, Y, Th, Zr and U). The results indicate that the source of most of the claystones and mudstones studied were sedimentary rocks of the upper continental crust of old cratonic areas, where the protolith had a mainly felsic character. However, in the latest Triassic a characteristic layer formed, implying significant input from mafic volcanic protolith. It was also found that moderately intense chemical weathering usually favoured increased concentration of the rare earths. Extremely strong hydrolysis, related to episodes of very hot and humid climate (greenhouse events), caused conspicuous impoverishment in REE in residual clays. Weathering and recycling processes modified the composition of REE to some extent, but generally did not obliterate the original characteristics of the protolith. In some samples, enrichment in rare earth elements was observed, caused by admixtures of accessory minerals (being a main carrier of REE) and/or increased sorting during recycling.
Źródło:
Geological Quarterly; 2016, 60, 2; 441--450
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Climatic disaster at theTriassic–Jurassic bound ary – a clay minerals and major elements record from the Polish Basin
Autorzy:
Brański, P.
Powiązania:
https://bibliotekanauki.pl/articles/2059743.pdf
Data publikacji:
2014
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Triassic–Jurassic boundary
clay minerals
major elements
weathering regime
palaeoclimatic shifts
Polish Basin
Opis:
The Triassic-Jurassic boundary interval (ca. 201 Ma) was a time of sudden global environmental changes triggered by Pangea breakup and Central Atlantic Magmatic Province development. The bulk-rock mineralogy, clay mineralogy and major element geochemistry of 87 continental mudrock samples collected from four borehole cores yield information on Rhaetian-earliest Hettangian palaeoclimatic changes in the Polish Basin. During the Rhaetian, smectite preponderance was replaced by kaolinite and illite domination. This fundamental shift in clay mineral assemblages (supported by major element data) indicates very significant change in climate humidity. Moreover, some beds in the Zagaje Formation (Upper Rhaetian-Lower Hettangian) are particularly rich in kaolinite indicating extreme chemical weathering in humid-subtropical to tropical climate episodes in the aftermath of powerful warming and abundant rainfall. Importantly, the first distinct kaolinite enrichment appears already in the Lower Rhaetian Wielichowo Beds. In addition, abrupt and episodic shifts in the kaolinite-illite ratio and in values of weathering indices point to profound climate destabilisation and a sequence of frequent, catastrophic climatic reversals in the Late Rhaetian and at the Triassic-Jurassic boundary. These results are generally consistent with carbon isotope records in sections worldwide.
Źródło:
Geological Quarterly; 2014, 58, 2; 291--310
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The use of gadolinium and europium concentrations as contaminant tracers in the Nida River watershed in south-central Poland
Autorzy:
Migaszewski, Z. M.
Gałuszka, A.
Powiązania:
https://bibliotekanauki.pl/articles/2060198.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
are earth elements
wastewater effluent
Nida River drainage system
anthropogenic gadolinium
geogenic europium
Opis:
This paper presents the results of rare earth element (REE) determinations in the Nowiny wastewater treatment plant (NWWTP) effluents and Nida River system waters of the southeastern Kielce Region (south-central Poland). Of the REE examined, gadolinium and europium turned out to be very useful for pinpointing anthropogenic and geogenic sources. Anthropogenic gadolinium (Gdanth), used as a contrasting agent in magnetic resonance imaging (MRI), is released from the NWWTP into the river drainage system. This micropollutant is traced downstream over the distance of about 15 km. This river stretch is characterized by a strong positive NASC-normalized Gdanth anomaly with the GdNASC/GdNASC* ratio above 1.1 (1.80–15.57) and the Gdanth input varying from 44 to 94%. Two additional positive Gdanth anomalies recorded in the rivers Bobrza and Nida point out to mixing of effluents derived from the NWWTP and other local wastewater treatment plants. In contrast, the Gdanth-uncontaminated waters upstream, or downstream far away from the NWWTP display a distinct positive NASC-normalized Eu anomaly highlighted by a high Eu/Eu* ratio in the range of 2.87 to 29.70. The lack of Gdanth anomaly upstream from the NWWTP also indicates that there is no leakage of municipal sewage from the sanitary collector sewer into the Silnica River. Thus Gd as a contaminant may be effectively used as a tracer in similar pollution studies because it is relatively simple and cost-effective to discriminate between contaminant concentrations and normal background concentrations.
Źródło:
Geological Quarterly; 2016, 60, 1; 67--76
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł

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