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Wyświetlanie 1-8 z 8
Tytuł:
Habitat and hydrocarbon potential of the Kimmeridgian strata in the central part of the Polish Lowlands
Autorzy:
Więcław, D.
Powiązania:
https://bibliotekanauki.pl/articles/2060197.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Polish Lowlands
Kimmeridgian
source rock
hydrocarbon potential
biomarkers
carbon stable isotopes
Opis:
The quantity, genetic type and maturity of organic matter dispersed in the Kimmeridgian strata of the central part of the Polish Lowlands were determined on the basis of results of Rock-Eval, stable carbon isotope composition of bitumen, their fractions and kerogen, biomarker distribution in saturate and aromatic hydrocarbon fraction, elemental composition of kerogen, vitrinite reflectance and maceral composition analyses of 225 rock samples collected from 32 boreholes. The study was conducted separately for Lower and Upper Kimmeridgian rocks in the Szczecin-Miechów and Kościerzyna-Puławy synclinoriums and Mid-Polish Anticlinorium. The best source rocks with TOC up to 6.8 wt.%, were found in the vicinity of Gostynin in the Mid-Polish Anticlinorium. Generally, the Upper Kimmeridgian strata are fair and good potential source-rocks whereas the Lower Kimmeridgian strata have much lower hydrocarbon potential. Gas-prone, terrigenous Type-III kerogen predominates in the Lower Kimmeridgian strata. The contribution of oil-prone, marine Type-II kerogen increases in the Upper Kimmeridgian rocks. In the whole profile, only low-sulphur kerogen was recorded, although the situation, when high-sulphur Type-IIS kerogen was mixed with re-worked, non-generative Type-IV kerogen supplied to the sedimentary basin with rocks from eroded land, cannot be excluded. Sedimentary conditions of organic material were variable, usually anoxic and suboxic with domination of siliclastic material in mineral matrix. The maturity of the dispersed organic matter refers mostly to the final phase of the microbial process, or to the initial phase of the low-temperature thermogenic process (oil window). The most mature rocks, corresponding up to 0.75% in the vitrinite reflectance scale, were recognised in the deepest buried parts of the basin (axial part of the Mogilno-Łódź Segment of the Szczecin-Miechów Synclinorium). The most prospecting source rocks were recognised in this area.
Źródło:
Geological Quarterly; 2016, 60, 1; 192--210
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin of oils accumulated in the Middle Cambrian reservoirs of the Polish part of the Baltic region
Autorzy:
Kowalski, A.
Więcław, D.
Kotarba, M. J.
Powiązania:
https://bibliotekanauki.pl/articles/2059062.pdf
Data publikacji:
2010
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Baltic Region
Lower Paleozoic
oil origin
biomarkers
stable carbon isotopes
oil-oil correlation
Opis:
We have examined 21 samples of crude oils accumulated in the Middle Cambrian sandstone reservoirs from the Polish part of the Baltic region. All the crude oils have similar parameters and indices, which suggests generation from the same source rock. Evaporative fractionation and biodegradation processes were detected in oil collected from the B4-N1/01 borehole. All crude oils have high gravities and low-sulphur contents, less than 0.3 wt.%, which suggests that their source rock contained low-sulphur kerogen deposited in a clastic environment. A low asphaltenes content (below 0.3 wt.%) and high saturate/aromatic hydrocarbon ratios indicate long migration distances or high thermal maturities. The longest migration distance was probably attained by oils from the arnowiec and B16 deposits. The biomarker data indicate an algal origin for the source organic matter deposited under conditions of clastic sedimentation. The stable carbon isotope data support this observation. The maturity of the oils analysed varies from ca. 0.75 to ca. 1.05% on the vitrinite reflectance scale. Unlike the B6, B16, Dbki and arnowiec accumulations, oils from the B3 and B4 accumulations reveal the lowest maturity.
Źródło:
Geological Quarterly; 2010, 54, 2; 205-216
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Estimation of hydrous-pyrolysis kinetic parameters for oil generation from Baltic Cambrian and Tremadocian source rocks with Type-II kerogen
Autorzy:
Więcław, D.
Kotarba, M. J.
Lewan, M. D.
Powiązania:
https://bibliotekanauki.pl/articles/2059067.pdf
Data publikacji:
2010
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Baltic Region
Cambrian
Ordovician
hydrous pyrolysis
organic sulfur
kinetic parameters
type II kerogen
Opis:
Determining kinetic parameters for oil generation from a source rock by hydrous pyrolysis requires a considerable amount of sample (kilograms) and laboratory time (several weeks). In an effort to circumvent these requirements, hydrous-pyrolysis (HP) kinetic parameters for oil generation from Upper Cambrian and Tremadocian source rocks of the Baltic region are estimated by two methods: (1) organic sulfur content in kerogen and (2) HP experiments conducted at 330 and 355°C for 72 h. Estimates for the Upper Cambrian source rocks based on organic sulfur contents gave activation energies from 47 to 56 kcal/mole and frequency factors from 1.156 ' 1025>/sup> to 1.078 ' 1028 m.y.-1 . Tremadocian source rocks based on organic sulfur content gave estimated activation energies from 60 to 62 kcal/mole and frequency factors from 1.790 ' 1029 to 1.104 ' 1030 m.y.-1 . The estimates for the Tremadocian source rocks were less affected by thermal maturation because their low kerogen S/(S + C) mole fractions (< 0.018) remained essentially constant. Conversely, the higher kerogen S/(S + C) mole fractions (>>gt; 0.018) of the Upper Cambrian source rocks decreased with thermal maturation and resulted in overestimation of the kinetic parameters. The second method was designed to estimate kinetic parameters based on two HP experiments. The assumption that the maximum yield in calculating the rate constant at 330°C (k330°C could be determined by a second hydrous pyrolysis experiment at 355°C for 72 h proved not to be valid. Instead, a previously established relationship between Rock-Eval hydrogen index and maximum HP yield for Type-II kerogen was used to calculate k330°C from oil yields generated by the HP experiment at 330°C for 72 h assuming a first-order reaction. HP kinetic parameters were determined from relationships between k330°C and the HP kinetic parameters previously reported. These estimated HP kinetic parameters were in agreement with those obtained by the first method for immature samples, but underestimated the kinetic parameters for samples at higher thermal maturities. Applying these estimated HP kinetic parameters to geological heating rates of 1 and 10°C/m.y. indicated that the Upper Cambrian source rocks would generate oil notably earlier than the overlying Tremadocian source rocks. This was confirmed in part by available data from two neighboring boreholes in the Polish sector of the Baltic.
Źródło:
Geological Quarterly; 2010, 54, 2; 217-226
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Habitat and hydrocarbon potential of the Mesozoic strata in the Kraków–Rzeszów area (SE Poland)
Autorzy:
Kosakowski, P.
Więcław, D.
Kotarba, M. J.
Kowalski, A.
Powiązania:
https://bibliotekanauki.pl/articles/2058966.pdf
Data publikacji:
2012
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Carpathian Foredeep substratum
Mesozoic strata
Middle Jurassic source rock
petroleum geochemistry
quality of source rocks
Opis:
The Mesozoic strata in the southeastern Poland were geochemically characterized to determine their hydrocarbon potential on the basis of 483 core samples from 36 boreholes. The Lower and Middle Triassic, Middle and Upper Jurassic, and Lower and Upper Cretaceous turned out to be highly variable. Middle Jurassic rocks represent the highest geochemical quality. Their total organic carbon (TOC) contents range between 0.0 and 17.0 wt.%, with a median of 0.89 wt.%. The highest TOC was observed in the rocks of the Tarnawa 1 borehole. In the remaining boreholes analysed the organic carbon contents were much lower and usually did not exceed 1 wt.%. Gas-prone Type-III kerogen with an admixture of Type-II kerogen is present in the study area. The lowest TOC values were observed in the Cretaceous rocks, where median values were 0.05 wt.% and 0.04 wt.% for Upper Cretaceous and Lower Cretaceous strata respectively. Low TOC contents were also observed in the Lower Triassic and Upper Jurassic strata. Accordingly, those horizons could not be regarded as effective source rocks. The petroleum potential of these stratigraphic horizons is additionally significantly reduced by low maturity, below the threshold for the generation of hydrocarbons. The Mesozoic organic matter was found to be generally immature, i.e. below 0.5% of vitrinite reflectance.
Źródło:
Geological Quarterly; 2012, 56, 1; 139-152
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin and maturity of oils in the Ukrainian Carpathians and their Mesozoic basement
Autorzy:
Więcław, D.
Kotarba, M. J.
Kowalski, A.
Koltun, Y. V.
Powiązania:
https://bibliotekanauki.pl/articles/2058970.pdf
Data publikacji:
2012
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Ukrainian Carpathians
Carpathian Foredeep
biomarkers
stable carbon isotopes
Opis:
Geochemical characteristics of 25 oils collected from Skiba Unit of the Outer Carpathians, Boryslav-Pokuttya Unit of the Carpathian Foredeep and their Mesozoic basement in the western Ukraine are presented in the paper. The first recognised oil family consists of almost all oils accumulated in the flysch sequence of the Outer Carpathians and the Carpathian Foredeep which have very similar geochemical characteristics. These oils were generated from Type II or II/III kerogen deposited in clastic sediments. They are low-sulphur and migrated short distances. Slight biodegradation processes are visible only in oils accumulated in shallow deposits in the Skiba Unit. Their source rocks are the Oligocene Menilite Shales from the Boryslav-Pokuttya Unit. Oils from the Kokhanivka and Orkhovychi deposits (the Mesozoic basement of the Carpathian Foredeep) constitute the second family. These oils are extremely heavy, high-sulphur and were generated from high-sulphur Type IIS kerogen deposited in the carbonate environment. The most probable source rocks for these oils are the Upper Jurassic strata. Oil collected from the Vola Blazhivska deposit (the Boryslav-Pokuttya Unit) shows intermediate parameters between the oil families described above. It is characterized by the presence of oleanane and high sulphur content. It was generated from the Menilite Shales containing high-sulphur kerogen. All oils were generated at an early stage or the peak of oil window.
Źródło:
Geological Quarterly; 2012, 56, 1; 158-168
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Genetic correlation of source rocks and natural gas in the Polish Outer Carpathians and Paleozoic–Mesozoic basement east of Kraków (southern Poland)
Autorzy:
Kotarba, M. J.
Więcław, D.
Bilkiewicz, E.
Dziadzio, P.
Kowalski, A.
Powiązania:
https://bibliotekanauki.pl/articles/2060588.pdf
Data publikacji:
2017
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Polish Outer Carpathians
Paleozoic–Mesozoic basement
source rock potential
natural gas
biomarkers
stable carbon
hydrogen isotopes
nitrogen isotopes
Opis:
Natural gas-source rock correlations in the Polish Outer Carpathians and Paleozoic–Mesozoic basement in the Kraków–Brzesko–Nowy Sącz area (southern Poland) have been established. In the Dukla and Sub-Silesian units, mixed kerogen Type-II/III or III/II occurs. The organic matter is immature or low-mature. The Oligocene Menilite beds of the Silesian Unit are rich in TOC and contain gas-prone Type III kerogen of low maturity. In the Paleozoic–Mesozoic basement, the TOC content and residual hydrocarbon potential vary in the Middle and Upper Devonian strata, Mississippian carbonate and clastic facies and Middle Jurassic strata. The Paleozoic strata are capable of thermogenic hydrocarbon generation, while organic matter in the Middle Jurassic rocks is generally immature. Gaseous hydrocarbons accumulated both in the Silesian and Dukla units of the Polish Outer Carpathians and in the Mesozoic basement are genetically related to thermogenic and microbial processes. The Outer Carpathian natural gas was generated mainly from the Type-II/III kerogen of the Oligocene Menilite beds. The thermogenic gases from the Mesozoic basement were generated from Devonian and Mississippian (carbonate) Type-II and mixed II/III kerogens and probably from Silurian/Ordovician Type-II kerogen and Middle Jurassic Type-III/II kerogen occurring at more than 7 km depth. Microbial methane migrated into the Outer Carpathian flysch succession from the Miocene strata of the Carpathian Foredeep.
Źródło:
Geological Quarterly; 2017, 61, 4; 795--824
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Habitat and hydrocarbon potential of the lower Paleozoic source rocks in the Polish part of the Baltic region
Autorzy:
Kowalski, A.
Więcław, D.
Grotek, I.
Kotarba, M. J.
Kosakowski, P.
Powiązania:
https://bibliotekanauki.pl/articles/2059076.pdf
Data publikacji:
2010
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Baltic Region
northern Poland
source rock
hydrocarbon potential
Lower Paleozoic
Opis:
The quantity, genetic type and maturity of organic matter dispersed in the Lower Cambrian to the uppermost part of the Silurian (Pridoli) sequence of the Polish part of the Baltic region was determined based on the results of geochemical analyses of a total of 1377 rock samples collected from 38 onshore and offshore boreholes. The best source rocks were found in the Upper Cambrian-Tremadocian succession where present and initial total organic carbon (TOC) contents are up to ca. 18 and 20 wt.%, respectively. Caradocian (Ordovician) strata can be considered as an additional source of hydrocarbons. In the individual boreholes median present and initial TOC contents vary from 0.5 to 3.3 wt.% and from 1 to 6 wt.%, respectively. The Llandovery (Silurian) strata reveal moderate and locally high hydrocarbon potential of the source rocks. The present TOC content reaches locally 10 wt.% (usually 1-2 wt.%). Another source of hydrocarbons can be clayey intercalations within the Middle Cambrian strata. Their organic matter content rarely exceeds 1 wt.%, being often a result of advanced organic matter transformation. In all lower Paleozoic strata investigated from the Polish part of the Baltic region oil-prone, low-sulphur Type-II kerogen occurs, deposited in anoxic or sub-oxic conditions. The maturity of all source rocks changes from the initial phase of the low-temperature thermogenic processes in the northeastern part to the overmature stage in the southwestern part of the study area.
Źródło:
Geological Quarterly; 2010, 54, 2; 159-182
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin and migration of oil from the Ukrainian Outer Carpathians to their Mesozoic basement: a case of Lopushna traps
Autorzy:
Radkovets, N. Y.
Kotarba, M.
Koltun, Y.
Kowalski, A.
Kosakowski, P.
Więclaw, D.
Powiązania:
https://bibliotekanauki.pl/articles/2060167.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Ukrainian Carpathians
Lopushna oil field
oil origin
biomarkers
stable carbon isotopes
migration pathways
Opis:
Lopushna oil field has been discovered in Mesozoic-Paleogene strata of the platform basement under the Ukrainian Outer (Flysch) Carpathians. Oils from two main accumulations, occurring in the Upper Cretaceous sandstone and Upper Jurassic limestone reservoirs, have been analysed in order to identify their origin and relation to the known petroleum systems in the region of the Outer Carpathians and the basement of the Carpathian Foredeep. Results of geochemical investigations of oils, including biomarker and isotopic data, show a good correlation with oils, accumulated in the Carpathian flysch strata. Oils are low-sulphur and did not undergo significant degradation. They were generated from Type II or II/III kerogen, deposited in anoxic environments in clastic sediments. Generation occurred at the peak of “oil window”, probably in the temperature range of 122 to 126oC. The presence of oleanane indicates the Cretaceous or younger source rocks. Good correlation on biomarker and isotopic data with the organic matter dispersed in Oligocene Menilite Beds, occurring at the top of the Carpathian flysch succession, allowed authors to identify them as source rocks for oils of the Lopushna field, which thus can be regarded as an oil family of the Outer Carpathians. The migration distance for both Lopushna oils and oils accumulated in the Carpathian flysch strata was similar. A number of sub-vertical dislocations, on which the subsided flysch strata occur at the same depth level with the Jurassic and Cretaceous rocks of the platform, can be assumed as possible migration pathways from the mature source rocks of the Oligocene Menilite Beds of Boryslav-Pokuttya, Skyba or Krosno units to the Lopushna type traps, which suggests the possibility of existence of other hydrocarbon accumulations of this type. The Lopushna field so far is unique containing this type of oil found in the basement of the Ukrainian Carpathian Foredeep.
Źródło:
Geological Quarterly; 2016, 60, 1; 133--148
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-8 z 8

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