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Wyświetlanie 1-3 z 3
Tytuł:
Silicon and aluminium in groundwater of the Kłodzko Region (the Sudetes, )land) - partial geochemical equilibrium with secondary solid phases
Autorzy:
Dobrzyński, D.
Powiązania:
https://bibliotekanauki.pl/articles/2059234.pdf
Data publikacji:
2006
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Sudetes
groundwater geochemistry
aluminosilicate phases
hydroxyaluminosilicate HAS
silicon
aluminium
Opis:
The chemistry of shallow, cold groundwater in the eastern part of the Kłodzko Region (the Sudetes, SW Poland) was investigated, Groundwaters occur in the short turn-over time zone of the hydrogeological systems. The aquifers are composed of various bedrock types (metamorphic, igneous and sedimentary). Silicon and aluminium concentrations in the waters of particular aquifers are documented. The aqueous chemistry is interpreted in terms of the solubility of solid phases to indicate phases that are responsible for silicon and/or aluminium solubility control. Locally and/or periodically (seasonally) partial geochemical equilibrium between the groundwater and the secondary solid phases might be reached and maintained. In groundwater with a pH below 6.7, aluminium activity is usually controlled by the reversible congruent dissolution of A1(OH)3 forms, whereas silicon activity is probably controlled by the solubility the SiO2 form (chalcedony). At pHs above 6.7, the incongruent reaction between the hydroxyaluminosilicate colloid (HASB) and forms of Al(OH), controls both silicon and aluminium activities.
Źródło:
Geological Quarterly; 2006, 50, 3; 369-382
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Silica solubility in groundwater from Permian volcanogenic rocks (the Sudetes Mts., SW Poland) : the role of reversible aluminosilicate solids
Autorzy:
Dobrzyński, D.
Powiązania:
https://bibliotekanauki.pl/articles/2059124.pdf
Data publikacji:
2006
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Sudetes
groundwater chemistry
volcanic rocks
silicon
aluminium
hydroxyaluminosilicates (HAS)
allophanes
Opis:
The chemistry of groundwater in Permian volcanic rocks (rhyolitic tuffs, trachyandesites) in two small headwater catchments (the SudetesMts., SW Poland) has been investigated. The calculated transfer of silica released during weathering is greater than the real concentration in groundwater, and indicates that part of the silica is immobilized in secondary aluminosilicates. Silica solubility is interpreted in terms of the solubility of reversible secondary aluminosilicates (allophanes, hydroxyaluminosilicates). Partial chemical equilibrium of these phases is sometimes locally achieved. In groundwaters with pH above 6.7 from trachyandesites of the BukowiecMt. type, chemical equilibrium with respect to the hydroxyaluminosilicate HASB is probably maintained. Its solubility constant, calculated accordingly to the method given by Schneider et al. (2004), is lgK HASB = –44.74 (۪.52), and indicates that this "field" HASB has a solubility lower than the published experimental value (lgK HASB = –40.6 ۪.15) for synthetic HASB (op.cit.). Non-equilibrium with respect to aluminosilicates in groundwaters from rhyolitic tuffs and from trachyandesites of the Stożek Wielki Mt. type is caused by the short turn-over time of groundwater in the systemand by the poor neutralisation capacity of the bedrock. The silica concentration in these groundwaters results from steady-state conditions achieved between weathering release, hydrological removal and precipitation of secondary phases. The hydrogeochemical data are conducive to the presence of allophane minerals in the weathered rhyolitic tuffs.
Źródło:
Geological Quarterly; 2006, 50, 4; 407-417
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Estimation of inorganic carbon sources in groundwater recharge by inverse geochemical modelling (Carboniferous aquifer, the Intra-Sudetic Basin, SW Poland)
Autorzy:
Dobrzynski, D.
Powiązania:
https://bibliotekanauki.pl/articles/2060223.pdf
Data publikacji:
2008
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Polska
Sudetes
inverse geochemical modelling
radiocarbon activity
groundwater chemistry
Opis:
Geochemical modelling was applied in quantification of chemical reactions responsible for the chemistry of groundwater in the recharge zone of a Carboniferous aquifer (the Sudety Mts., SW Poland). Calculation of the contribution of dissolved in organic carbon (DIC) sources allowed estimation of the initial radiocarbon activity in the recharge to groundwater. The 14C activity calculated upon the results of geochemical modelling is consistent with the 14C activity measured in groundwater. Geochemical modelling can be applied for estimation of the initial 14C activity in recharge water as well as the 14C activity in groundwater along the flow path. Methods of geochemical modelling have an advantage over empirical methods because they combine the effects of various chemical reactions occurring in the geochemical system.
Źródło:
Geological Quarterly; 2008, 52, 2; 191-191
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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