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Wyświetlanie 1-13 z 13
Tytuł:
Influence of Ce3+ doping on the algal inhibiting properties of copper/sepiolite nanofibers
Autorzy:
Zhang, C. C.
Duan, X.
Ding, Y.
Srinivasakannan, C.
Powiązania:
https://bibliotekanauki.pl/articles/207260.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
copper
x ray diffraction
alga
miedź
dyfrakcja rentgenowska
glon
Opis:
Algal inhibiting materials were synthesized by the co-impregnation method. Cerium was taken as an algal inhibiting agent with copper/sepiolite utilized as the carrier. The algal growth inhibition was assessed based on the form of presence and distribution of Cu2+ and Ce3+ ions on the surface of sepiolite using X-ray diffraction (XRD) and SEM analysis. The results indicate that at 5 wt. % Cu content, 0.8 wt. % Ce and after heat treatment at 400 °C, the materials exhibit the best algal inhibiting capacity of 83.11%.
Źródło:
Environment Protection Engineering; 2017, 43, 4; 253-263
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Utilization of cement and other additives for solidification/stabilization of soil contaminated simultaneously with Cd2+ and Pb2+ ions
Autorzy:
Xi, Y.
Wang, H.
Guo, L.
Zhang, M.
Powiązania:
https://bibliotekanauki.pl/articles/208172.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cement
soil pollution
X-ray diffraction
dyfrakcja rentgenowska
zanieczyszczenie gleby
Opis:
Various additives, including cement, quicklime, fly ash, montmorillonite, sepiolite and their proportions were employed to stabilize/solidify artificially prepared soils contaminated simultaneously with two kinds of ions such as Cd2+ and Pb2+. The unconfined compressive strength of the stabilized soils was measured to estimate the possibility of recycling. The efficiency of Cd2+ and Pb2+ immobilization in contaminated soils was also evaluated using the US EPA TCLP toxicity test. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to elucidate the mechanisms responsible for the immobilization of heavy metals. The experimental results demonstrate that in terms of soils simultaneously polluted with Cd2+ and Pb2+ ions, the curing effect of fly ash is better than that of montmorillonite and sepiolite. When Cd2+ and Pb2+ coexist in soil specimens, the curing is more difficult than for Cd2+ or Pb2+ alone, which is antagonistic mechanism. Also, the leaching concentration of Cd2+ and Pb2+ gradually decreases upon increasing pH when pH < 8. For pH ≥ 8, the leaching concentration of Cd2+ and Pb2+ reached a minimum. Besides, the results of XRD and SEM are in agreement with those of the strength and leaching tests.
Źródło:
Environment Protection Engineering; 2018, 44, 1; 61-73
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of long-term storage of phosphate sludges on their physicochemical properties, the distribution and mobility of heavy metals, and acid generation
Autorzy:
Arroug, Lamya
Elaatmani, Mohamed
Zegzouti, Abdelouahad
Afqir, Mohamed
Ibnoussina, Mounsif
Babram, Mohammed Ait
Powiązania:
https://bibliotekanauki.pl/articles/2032922.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
phosphate sludge
X-ray diffraction
soil
contamination
osad fosforowy
dyfrakcja rentgenowska
gleba
zanieczyszczenie
Opis:
Some phosphate sludges (Ps) were collected in 2009, 2014, and 2018. Results of their analyses by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM-SED), differential thermal and thermogravimetric analyses (TG-DTA) and X-ray fluorescence spectrometry (XRF) confirmed that the Ps are highly carbonated. Descriptive and exploratory statistical procedures for heavy metals (HM) concentrations and chemical parameters were performed and revealed the differences between the Ps of three different ages. The results indicate that there are three sources responsible for the behavior of Ps over years: common origin and accumulation of HIM and solar radiation exposure. The sequential extraction shows that the residual fractions of Cd, Ni, Zn, Pb, and Cr were predominant The mobility factor was quite low and did not change over the years, except for Cd. The net acid generation pH for the three samples was greater than 4.5 classifying the Ps as non-acid-generating.
Źródło:
Environment Protection Engineering; 2021, 47, 2; 59-81
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Towards a viable method of reusing silicon carbide. Physicochemical analyses in the studies on the industrial application of the material
Autorzy:
Niemczyk-Wojdyla, Anna
Fornalczyk, Agnieszka
Willner, Joanna
Zawisz, Rafał
Powiązania:
https://bibliotekanauki.pl/articles/2032847.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
silicon carbide
X-ray spectroscopy
Acheson process
węglik krzemu
spektroskopia rentgenowska
proces Achesona
Opis:
The paper presents an investigation on the feasibility of recovery of the highly valuable silicon carbide (SiC) from the slurry waste generated from silicon wafer production in the photovoltaic and semiconductor industry. Compared to the other techniques of recycling, a facile and low-cost method of waste treatment via heat drying followed by low-energy mixing in a shaker mixer was proposed. As the result of the treatment, the slurry waste was converted into a powdered form with dominant content of SiC. Separated SiC material was characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray powder diffraction, and sieve analysis. In addition, analyses of the bulk density, moisture content and melting test were carried out. As was confirmed by the physicochemical analyses, the dominant sieve fraction was in the range of 0.1-0.06 mm, the purity level was a minimum 99% mass of SiC, the moisture content - 0.3%, the bulk density - 1.3 g/cm3. The physicochemical characteristics of the material were crucial for understanding the material performance, assessment of the material quality and determining the perspective directions of the industrial application. The studies revealed that the material exhibited a high application potential as abrasive, especially in abrasive grinding and waterjet cutting.
Źródło:
Environment Protection Engineering; 2021, 47, 4; 43-52
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Elemental composition and origin of PM10 in a fire station in Poland. Real-time results from the XRF analysis
Autorzy:
Mach, Tomasz
Rogula-Kozłowska, Wioletta
Bihałowicz, Jan Stefan
Rybak, Justyna
Powiązania:
https://bibliotekanauki.pl/articles/24201037.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
particulate matter
heavy metals
X-ray fluorescence spectrometry
pył zawieszony
metale ciężkie
spektrometria fluorescencyjna
Opis:
This work presents the first results of the metal in particulate matter PM10 analysis and source apportionment in one of the fire station garages in Poland. The study’s novelty includes the high temporal resolution of the elemental composition of PM-bound metals since the gamma-ray fluorescence spectrometer with the high temporal resolution was used in the study. The concentrations of PM10 were measured at the same time using the method of beta-ray attenuation. The concertations of PM10 and PM-bound metals were analyzed with a temporal resolution of 4 h. To identify the source apportionment of metals, three commonly used models were applied: principal component analysis (PCA), EPA UNMIX, and EPA PMF (positive matrix factorization). The concentrations of the investigated metals have high temporal variations while the concentrations of PM10 were low in the garage. The enrichment of PM10 was very high or high, especially in sulfur, zinc, arsenic, nickel, cadmium, and lead. PCA analysis, as well as UNMIX and PMF, showed a high impact of factors related to sulfur on the variability. It showed the impact of combustion, including combustion of liquid fuels, in fire engines may have a crucial impact on air pollution in the fire station. The PMF analysis allowed us also to identify factors responsible for external anthropogenic emissions on concentrations inside the garage. Other identified sources of PM10 and PM10-bound elements are mineral dust, and road dust related to non-exhaust emission, originating inside the firehouse (resuspension and abrasion) as well as from outside.
Źródło:
Environment Protection Engineering; 2023, 49, 1; 57--72
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristic of mercury on the surface of ash originating from electrostatic precipitators of lignite and bituminous coal-fired power plants
Autorzy:
Veselý, Václav
Szeliga, Zbyszek
Vávrová, Zuzana
Čech, Bohumír
Regucki, Paweł
Krzyżyńska, Renata
Powiązania:
https://bibliotekanauki.pl/articles/207736.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
electrostatic precipitators
brown coal
mercury
X-ray fluorescence
XRF
elektrofiltry
węgiel brunatny
rtęć
fluorescencja rentgenowska
Opis:
Mercury concentrations in ash taken from electrostatic precipitations (ESPs) installed in bituminous coal and lignite power plants have been analyzed by the X-ray fluorescence (XRF) method and leaching test supported by detailed coal and ash compositions’ analyses, surface scans and particles size distribution studies. The results showed that mercury was present on the surface of ash particles. Its concentration decreased upon increasing size of ash particles. Leaching tests showed that only small part of mercury was removed with water which suggests the fact that it occurred mostly in the form of insoluble compounds such as Hg, HgO, HgS and Hg2Cl2. There existed ash particles of the diameters from 50 to 60 μm, characterizing by the maximum capability to adsorb mercury and its compounds. The authors suggest that metals like copper and lead formed ash active centers that were preferably occupied by molecules containing atoms of mercury. It was highly possible to expect that content of these elements in ash would have a significant effect on sorption of mercury from combustion gases.
Źródło:
Environment Protection Engineering; 2019, 45, 4; 45-59
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effectiveness of fly ash on the stabilization/solidification of Zn-contaminated soil
Autorzy:
Chen, Yan
Zhu, Shengyuan
Fang, Wei
Huang, He
Qin, Hao
Hu, Shengtao
Wu, Yuzhao
Powiązania:
https://bibliotekanauki.pl/articles/27323977.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
fly ash
soil
heavy metals
X-ray diffraction
Zn2+
popiół lotny
gleba
metale ciężkie
dyfrakcja rentgenowska
Opis:
As a solid waste, the associated disposal cost of fly ash is really high. Previous studies suggested that the utilization of fly ash to treat heavy metal-contaminated soils was a new cost-effective method of disposal of it. Therefore, the effectiveness of fly ash stabilized/solidified Zn-contaminated soils has been investigated by unconfined compressive strength (UCS) and toxicity characteristics leaching procedure (TCLP) tests. Quantitative analysis of the soil microstructure was conducted by processing the X-ray diffraction (XRD) and scanning electron microscope (SEM) images. Mercury intrusion porosimetry (MIP) was carried out to illustrate the size and proportion of pore size for specimens under different ratios. The results of the tests showed an improvement in the UCS, which further increased as the content of binders was raised. Binder content would have little influence on the development of strength if the binder content exceeds a threshold value. The leached Zn2+ concentration of stabilized specimens was significantly decreased compared to that of untreated. Quantitative analysis confirmed that the addition of the binders resulted in the amount of hydration product, reduction of porosity, and a really random pores orientation, which was responsible for the improvement of the strength and leaching properties of the Zn2+ contaminated soils.
Źródło:
Environment Protection Engineering; 2023, 49, 3; 15--29
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Elemental composition and rough source apportionment of fine particulate matter in air in Cracow, Poland
Autorzy:
Samek, L.
Gdowik, A.
Ogarek, J.
Furman, L.
Powiązania:
https://bibliotekanauki.pl/articles/208112.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
elemental compositions
X-ray fluorescence method
source apportionment
source contributions
Cracow
metoda fluorescencji rentgenowskiej
Kraków
koncentracja pyłów zawieszonych
źródła emisji zanieczyszczeń
Opis:
Samples of PM2.5 fraction (particles with aerodynamic diameter ≤2.5 mu m) of air particulates were collected in winter 2011 and summer 2012 in Cracow, Poland. The concentrations of PM2.5 were 50 ±23 mu g/m3 (wintertime) and 16 ± 6 mu g/mV (summertime). The energy dispersive X-Ray fluorescence method was used for the determination of the concentrations of PM2.5-related elements. Principal component analysis and multilinear regression analysis were used to determine source contributions to ambient concentrations of PM2.5. In wintertime, the sources of air pollution were identified as municipal emission, steel and ferrous industry (49.2%), traffic (37.8%) and other, not identified sources (13%), whereas during summer, they were traffic (53%), steel and ferrous industry (18%), and not identified sources (29%).
Źródło:
Environment Protection Engineering; 2016, 42, 1; 71-83
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Catalytic decomposition of toluene over La1-xSr xMnO3/palygorskite synthesized catalysts
Autorzy:
Song, L.
Chen, T.
Chen, D.
Chen, Y.
Xie, J.
Liu, H.
Powiązania:
https://bibliotekanauki.pl/articles/207996.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
catalysts
manganese
manganese oxide
toluene
transmission electron microscopy
X ray diffraction
Palygorskite
katalizatory
mangan
tlenek manganu
toluen
transmisyjna mikroskopia elektronowa
dyfrakcja promieniowania rentgenowskiego
Opis:
Palygorskite (PG) supported La1-xSrxMnO3 catalysts were fabricated by copreripitation. The catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), specific surface area (SSA) and H2 temperature programmed reduction (H 2-TPR). Catalytic activity for VOCs was examined by using toluene as a model compound. The results show that the surface area as well as mechanical strength of catalysts increase substantially after catalysts loaded in PG. XRD patterns show that after calcination at 700 0C, PG as a support in 9% LaMn03/PG and 9% La0.7Sr0.3MnO3/PG was transformed into amorphous phase and the morphology was not destroyed. It was well established that the main reductive components are factually Mn(III) or Mn(IV) oxides in catalysts based on the results of TPR. It was also found that Mn(IV) increases while Mn(III) reduces responding with the increasing amount of Sr. Toluene conversion rate of as-preparedμ% La1-xSr xMnO3/PG increases with the increasing values of x and μ when x=0-0.3 and μ = 3-9%. Toluene can be converted completely at 285 0C by 9% La0.7Sr0.3MnO3/PG catalyst while no significant change was observed after addition on the doping and loading amount of Sr. During a 100 h stability experiment of 9% La 0.7Sr0.3MnO3/PG catalyst, toluene removal was found to be above 95%.
Źródło:
Environment Protection Engineering; 2013, 39, 3; 31-42
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ultrasonic-assisted synthesis of reactive carboxymethyl cellulose stabilized nano zero-valent iron and its application for removal of Cr6+ and Cu2+ ions
Autorzy:
Ayob, A.
Santiagoo, R.
Amneera, W. A.
Ismail, N.
Abdullah, A. Z.
Powiązania:
https://bibliotekanauki.pl/articles/207403.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
high resolution transmission
electron microscopy
light scattering
transmission electron microscopy X ray diffraction
zero-valent iron
wysoka rozdzielczość transmisyjna
mikroskopia elektronowa
dyfrakcja rentgenowska
żelazo
Opis:
Carboxymethyl cellulose (CMC) was used in the chemical reduction using sodium borohydride to yield dispersive nano zero-valent iron (nZVI) particles as reactive and stable adsorbents. CMC- -stabilized nZVI particles were characterized via UV-visible light spectroscopy, X-ray diffraction, dynamic light scattering, transmission electron microscopy, and specific surface area assisted using a probe ultrasonication dispersing tool at 50% amplitude power. High catalytic reactivity obtained in pseudo-first order reaction for Cr6+ (rate constant K1 = 0.0311 min–1) and pseudo-second order for Cu2+ (rate constant K2 = 0.0946 g·mg–1·min–1) indicated that colloidal stability of nZVI particles can be achieved with a stabilizer for the removal of toxic contaminants.
Źródło:
Environment Protection Engineering; 2016, 42, 2; 55-79
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation of titanium dioxide/attapulgite composites and their application in treating Reactive Black KN-B wastewater
Autorzy:
Xie, A.
Luo, S.
Chaoyao, Y.
Powiązania:
https://bibliotekanauki.pl/articles/207828.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
wastewater treatment
titanium dioxide
X ray diffraction
adsorption capacities
adsorption kinetics
Langmuir models
photocatalytic effect
oczyszczanie ścieków
dwutlenek tytanu
dyfrakcja promieniowania X
zdolności adsorpcyjne
kinetyka adsorpcji
modele Langmuira
efekt fotokatalityczny
Opis:
Removal of water soluble Reactive Black KN-B from aqueous media by means of titanium dioxide/attapulgite (TiO2/ATP) composites was studied in a batch system. The composites were investigated using X-ray diffraction and surface area analysis. Under UV irradiation, the photocatalytic effect of TiO2/ATP composites, pH and reaction temperature on the decolorization rate of Reactive Black KN-B were investigated in detail. The adsorption experiments of TiO2/ATP composites showed that the isotherms and adsorption kinetics were well followed by the Langmuir model and the zero order equation, respectively. The maximum adsorption capacity of TiO2/ATP composites for Reactive Black KN-B calculated by the Langmuir model was 20.08 mg g-1. It can be concluded that the TiO2/ATP composites could be good photocatalysts/adsorbents for treating Reactive Black KN-B wastewater.
Źródło:
Environment Protection Engineering; 2014, 40, 1; 45-56
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of the effect of heat treatment process on characteristics and photocatalytic activity of TiO2-UV100 nanoparticles
Autorzy:
Behnajady, M. A.
Alamdari, M. E.
Modirshahla, N.
Powiązania:
https://bibliotekanauki.pl/articles/208146.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
titanium dioxide
photocatalysis
X ray diffraction
Brunauer Emmett Tellers
heat treatment
photocatalytic activity
dwutlenek tytanu
ditlenek tytanu
fotokataliza
dyfrakcja promieniowania rentgenowskiego
izotermy Brunauer Tellers Emmett
obróbka cieplna
aktywność fotokatalityczna
Opis:
The effect of heat treatment process on crystallite size, phase content, surface area, band gap energy and photocatalytic activity of TiO 2-UV100 nanoparticles were investigated. Heat treated TiO2 nanoparticles were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) isotherm and diffuse reflectance spectroscopy (DRS) techniques, and its photocatalytic activity was investigated in the removal of C.I. Acid Red 88 (AR88), an anionic monoazo dye of acid class, as a model contaminant. Heat treatment process at 600 °C causes an increase in crystallite size and band gap energy of TiO2-UV100 nanoparticles. The results indicate that the nanoparticles treated for 1 h at 600 °C show the highest photocatalytic activity which can effectively degrade AR88 under UV-irradiation. Increasing heat treatment temperature above 600 °C led to reduction in TiO2 photoactivity which may be related to the anatase-rutile phase transformation, increasing particle size and decreasing specific surface area. Removal efficiency of AR88 with heat treated TiO 2-UV100 nanoparticles was sensitive to the operational parameters such as catalyst dosage, pollutant concentration and light intensity.
Źródło:
Environment Protection Engineering; 2013, 39, 1; 33-46
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Monitoring of bacterial biodiversity in anaerobic membrane bioreactors (AnMBRs) dealing with wastewater containing X-ray contrast media compounds
Autorzy:
Węgrzyn, A.
Żabczyński, S.
Powiązania:
https://bibliotekanauki.pl/articles/207395.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
bacteria
biodiversity
bioreactors
contrast media
electrophoresis
anaerobic membrane bioreactor
bacterial biodiversity
hospital wastewater
iodinated contrast media
X ray contrast media
bakterie
bioróżnorodność
bioreaktory
środki kontrastowe
elektroforeza
membranowy bioreaktor beztlenowy
bioróżnorodność bakterii
ścieki szpitalne
środki kontrastowe zawierające jod
rentgenowskie środki kontrastowe
Opis:
Iodinated contrast media compounds (ICM) have been identified in wastewater within the last 20 years. In this study, the biodiversity of activated sludge in anaerobic membrane bioreactors dealing with synthetic hospital wastewater with addition of ICM was investigated, using fluorescent in situ hybridization (FISH) and denaturing gradient gel electrophoresis (DGGE). During the adaptation of microorganisms to anaerobic growth conditions and to ICM presence, differences in the content of Alpha- and Betaproteobacteria were noted and bioreactors showed higher biological diversity (H = 2.9), suggesting that ICM were not toxic to the bacteria. The long sludge age had the strongest influence on the composition of activated sludge biocenosis.
Źródło:
Environment Protection Engineering; 2014, 40, 1; 151-164
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-13 z 13

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