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    Wyświetlanie 1-4 z 4
    Tytuł:
    Adsorption of arsenic on granular ferric hydroxide (GEH®). Impact of initial concentration of arsenic(V) on kinetics and equilibrium state
    Autorzy:
    Saldaña-Robles, A.
    Márquez-Herrera, A.
    Ruiz-Aguilar, G. M. L.
    Flores-Ortega, A.
    Saldaña-Robles, N.
    Powiązania:
    https://bibliotekanauki.pl/articles/207941.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    adsorption
    groundwater
    kinetics
    adsorpcja
    wody podziemne
    kinetyka
    Opis:
    The present study discusses the adsorption kinetics of arsenic(V) on granular ferric hydroxide (GEH) and the GEH adsorption capacity for arsenic(V) at equilibrium. The impact of temperature on GEH adsorption capacity was studied, as well as the effects of the initial concentration of arsenic(V) and GEH concentration on the adsorption rates of arsenic(V). The Freundlich isotherm describes the arsenic(V) adsorption behavior reasonably well (r2 > 0.965). The adsorption kinetics was studied by fitting the experimental data to both first-order and second-order models. The maximum adsorption capacity of arsenic(V) on GEH was 2.701 mg·g–1, which is higher than the adsorption capacities of other adsorbents reported. The kinetics of arsenic(V) adsorption was well defined by the second-order model, with the correlation coefficients in the range of 0.960–0.987. This study shows that due to its properties, GEH is a good candidate for removal of arsenic(V) from groundwater.
    Źródło:
    Environment Protection Engineering; 2018, 44, 3; 51-62
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Adsorption of Pb(II) using novel Pleurotus sajor-caju and sunflower hybrid biosorbent
    Autorzy:
    Majeed, A.
    Jilani, M. I.
    Nadeem, R.
    Hanif, M. A.
    Ansari, T. M.
    Powiązania:
    https://bibliotekanauki.pl/articles/206884.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    ołów
    adsorpcja
    biomasa
    zanieczyszczenie wody
    biosorbent
    Pleurotus sajor caju
    grzyby
    lead
    adsorption
    biomass
    water pollution
    biosorbents
    Opis:
    The present study was focused on the technical feasibility of using immobilized hybrid biomass of Pleurotos sajor-caju and sunflower for Pb(II) removal from the contaminated water. After preliminary evaluation, it was found that immobilized hybrid biomass of Pleurotos sajor-caju and sun-flower effectively removed Pb(II) from wastewater at pH 4.5. The effect of various experimental parameters on Pb(II) uptake by hybrid biosorbent was systematically evaluated in a batch biosorption system. The optimized biosorbent dose, contact time, initial metal concentration and temperature were 0.05 g/100 cm 3, 180 min, 800 mg/dm3 and 60 °C. Dynamics of the adsorption process were studied, and the values of rate constants of pseudo first order and pseudo second order kinetic models were calculated. Equilibrium isotherms for the adsorption of Pb(II) were analyzed by the Langmuir and Freundlich isotherm models. The sorption of Pb(II) followed the pseudo second order kinetic model. The Langmuir sorption isotherm fitted well to Pb(II) concentration data. The results revealed that this new hybrid biosorbent system was a promising candidate for eliminating Pb(II) from contaminated aquatic environment.
    Źródło:
    Environment Protection Engineering; 2014, 40, 2; 5-15
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Removal of hexavalent chromium from aqueous solution by adsorption on γ-alumina nanoparticles
    Autorzy:
    Golestanifar, H.
    Haibati, B.
    Amini, H.
    Dehghani, M. H.
    Asadi, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/207945.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    adsorption
    alumina
    aluminum
    chemicals removal
    water treatment
    chromium
    chromium compounds
    nanoparticles
    sorption
    alumina nanoparticles
    hexavalent chromium
    adsorpcja
    aluminium
    usuwanie chemikaliów
    uzdatnianie wody
    chrom
    związki chromu
    nanocząstki
    sorpcja
    nanocząstki tlenku glinu
    chrom sześciowartościowy
    Opis:
    The use of γ-alumina (γ-Al2O3) nanoparticles as adsorbent to remove Cr(VI) from aqueous solution was investigated using batch experiments. Adsorption experiments were carried out for various initial doses of Al2O3, initial concentrations of chromium(VI), contact times and pH. The structure and morphology of the sorbent was characterized by XRD, SEM, and TEM techniques. Results demonstrated that the removal efficiency of chromium(VI) was increased by increasing the contact time, initial concentration, and pH. The results of the study showed that adsorption of chromium by γ-alumina nanoparticles reached equilibrium after 60 min and after that a little change of chromium removal efficiency was observed. Furthermore, kinetics of chromium sorption was well fitted by pseudo-second order kinetic model, and well explained by the Freundlich isotherm (R2 > 0.992). Overall, alumina nanoparticles recognized as an effective sorbent to remove chromium(VI) from aqueous solutions.
    Źródło:
    Environment Protection Engineering; 2015, 41, 2; 133-145
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Equilibrium and kinetic studies on the removal of heavy metal ions with natural low-cost adsorbents
    Autorzy:
    Varank, G.
    Demir, A.
    Bilgili, M. S.
    Top, S.
    Sekman, E.
    Yazici, S.
    Erkan, H. S.
    Powiązania:
    https://bibliotekanauki.pl/articles/207257.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    adsorbents
    adsorption
    bentonite
    dyes
    heavy metals
    kinetics
    metal ions
    water treatment
    heavy metal removal
    heavy metal ions
    heavy metals ions removal
    adsorbenty
    adsorpcja
    bentonit
    barwniki
    metale ciężkie
    kinetyka
    jony metali
    usuwanie jonów metali ciężkich
    uzdatnianie wody
    Opis:
    Adsorption isotherms and kinetics of the removal of heavy metal ions (Ni, Pb, Zn) from aqueous solutions by natural adsorbents (zeolite, bentonite, clay) were investigated in a lab-scale batch study. The effect of various parameters such as adsorbent dosage, initial concentration of heavy metal ions, temperature, and agitation time were studied to optimise the conditions. Under those optimized conditions (180 rpm agitation rate, 120 min agitation time, pH 4.0, 298 K, 100 mg/dm3 initial adsorbate concentration), the removal percentages of heavy metal ions for natural adsorbents have been determined. The adsorption mechanisms and characteristic parameters of the process were analyzed by two and three parameter isotherm models (Langmuir, Freundlich, Temkin, Redlich-Peterson, Toth and Sips), and kinetic models (Lagergren's pseudo-first order, Ho and McKay's pseudo-second order). Adsorption thermodynamics of heavy metal ions (changes of standard enthalpy, entropy and free energy) on zeolite, bentonite and clay were also studied at 298,318 and 338 K.
    Źródło:
    Environment Protection Engineering; 2014, 40, 3; 43-61
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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