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Wyszukujesz frazę "kinetic equation" wg kryterium: Temat


Wyświetlanie 1-3 z 3
Tytuł:
Adsorption in Perfect Mixing Tank – Comparison of Exact and Approximate Kinetic Models
Autorzy:
Kupiec, K.
Gwadera, M.
Larwa, B.
Powiązania:
https://bibliotekanauki.pl/articles/185543.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
przybliżone równanie kinetyczne
adsorpcja w naczyniu
approximate kinetic equation
adsorption in vessel
Opis:
Periodic adsorption in a perfect mixing tank of a limited volume was considered. It was assumed that the adsorption rate is limited by diffusion resistance in a pellet. The approximate model of diffusion kinetics based on a continued fraction approximation was compared with the exact analytical solution. For the approximate model an algorithm was developed to determine a temporal variation of the adsorbate concentration in the pellet. The comparison was made for different values of the adsorbent load factor. In the numerical tests different shapes of pellets were considered. Both the numerical tests as well as our own experimental results showed that the approximate model provides results that are in good agreement with the exact solution. In the experimental part of this work adsorption of p-nitrophenol and acetic acid from aqueous solutions on cylindrical pellets of activated carbon was conducted.
Źródło:
Chemical and Process Engineering; 2014, 35, 3; 277-291
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetic investigations of heterogeneous reactor processes – Optimization of experiments
Autorzy:
Szałek, Adrian
Szukiewicz, Mirosław
Chmiel-Szukiewicz, Elżbieta
Powiązania:
https://bibliotekanauki.pl/articles/2034046.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
kinetic equation
hydrogenation of propene
designing of experiments
równanie kinetyczne
uwodornienie propenu
projektowanie eksperymentów
Opis:
A series of steps taken to determine a kinetic equation that describes hydrogenation of propene on nickel catalyst is presented in this study. Mixed factorial design approach, belongs to designing of experiments methods was used to plane experiments. The investigations showed that the method applied makes possible determination of the kinetic equation in a relatively fast and cheap manner since only a few measurement points is required. The equation obtained was verified experimentally and statistically. Both tests showed satisfactory precision of anticipated values of the process rate.
Źródło:
Chemical and Process Engineering; 2021, 42, 1; 35-41
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mathematical Kinetic Modelling and Representing Design Equation for a Packed Photoreactor with Immobilised TiO2-P25 Nanoparticles on Glass Beads in the Removal of C.I. Acid Orange 7
Autorzy:
Sheidaei, B.
Behnajady, M. A.
Powiązania:
https://bibliotekanauki.pl/articles/185458.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
heterogeneous photocatalysis
batch-recirculated photoreactor
design equation
mathematical kinetic modelling
TiO2-P25 nanoparticles
C.I. Acid Orange 7
fotoreaktor
modelowanie matematyczne
Nanocząstki TiO2-P25
CL kwas pomarańczowy 7
Opis:
In this work, a design equation was presented for a batch-recirculated photoreactor composed of a packed bed reactor (PBR) with immobilised TiO2-P25 nanoparticle thin films on glass beads, and a continuous-flow stirred tank (CFST). The photoreactor was studied in order to remove C.I. Acid Orange 7 (AO7), a monoazo anionic dye from textile industry, by means of UV/TiO2 process. The effect of different operational parameters such as the initial concentration of contaminant, the volume of solution in CFST, the volumetric flow rate of liquid, and the power of light source in the removal efficiency were examined. A rate equation for the removal of AO7 is obtained by mathematical kinetic modelling. The results of reaction kinetic analysis indicate the conformity of removal kinetics with Langmuir-Hinshelwood model (kL-H = 0.74 mg L-1 min-1, Kads = 0.081 mg-1 L). The represented design equation obtained from mathematical kinetic modelling can properly predict the removal rate constant of the contaminant under different operational conditions (R2 = 0.963). Thus the calculated and experimental results are in good agreement with each other.
Źródło:
Chemical and Process Engineering; 2015, 36, 2; 125-133
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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