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Wyświetlanie 1-15 z 86
Tytuł:
The Role of Product Composition in Determining Detonation Velocity and Detonation Pressure
Autorzy:
Politzer, P.
Murray, J. S.
Powiązania:
https://bibliotekanauki.pl/articles/358258.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
detonation velocity
detonation pressure
density
detonation product composition
detonation heat release
Opis:
Four sets of rules for predicting the detonation product compositions of explosives have been investigated: the Kamlet-Jacobs, the KistiakowskyWilson, the modified Kistiakowsky-Wilson and the Springall-Roberts. These can result, for a given compound, in significantly differing detonation products and amounts of heat release. However the resulting detonation velocities D and detonation pressures P obtained for the compound using the Kamlet-Jacobs equations are generally quite similar, with the Kamlet-Jacobs rules leading to the D and P that are, on average, closest to the experimental. The fact that the variations among the D and P values are relatively small can be attributed to a balancing of opposing effects relating to the quantities of gaseous products and the heat releases. Accordingly, obtaining reasonable accuracy for D and P does not necessarily imply corresponding accuracy for the product composition and heat release that were used. The analysis presented explains the observations that D and P can be correlated with loading density alone, even though product compositions are known to change with density.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 4; 459-474
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Detonation Performance of Four Groups of Aluminized Explosives
Autorzy:
Xiang, D.-L.
Rong, J.-L.
He, X.
Powiązania:
https://bibliotekanauki.pl/articles/358148.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
aluminized explosive
detonation pressure
detonation velocity
heat of detonation
KHT code
Opis:
The detonation performances of TNT-, RDX-, HMX-, and RDX/AP-based aluminized explosives were examined through detonation experiments. The detonation pressure, velocity, and heat of detonation of the four groups of aluminized explosives were measured. Reliability verification was conducted for the experimental results and for those calculated with an empirical formula and the KHT code. The test results on detonation pressures and velocities were in good agreement with the predicted values when aluminum (Al) particles were considered inert. The experimental heat of detonation values exhibited good consistency with the predicted values when a certain proportion of Al particles was active. Ammonium perchlorate (AP) can effectively reduce the detonation pressure and improve the heat of detonation for the RDX/AP-based aluminized explosive. A comparison of the current test results and literature data shows that errors may exist in early test data. The test data presented in this study allow for an improved understanding of the detonation performance of the four groups of aluminized explosives.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 903-915
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Calculation of Thermochemical and Explosive Characteristics of Furoxanes
Autorzy:
Zhukov, I.
Kozak, G. D.
Powiązania:
https://bibliotekanauki.pl/articles/358541.pdf
Data publikacji:
2008
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
furoxanes
benzofuroxanes
high-power energetic materials
heat of detonation
detonation velocity
detonation pressure
Opis:
Search of high-power energetic materials is one primary line of development of chemical physics of combustion and explosion. Yield of such materials is usually very small, and its cost is very high. Calculation of unknown characteristics and properties is the only way out from this situation. There are different methods today that allow calculating unknown detonation performance and some of physicochemical properties. Examination of calculated detonation performance of furoxanes and benzofuroxanes compounds that are not enough investigated is presented in this work. These compounds are new high-power energetic materials. Influence of error in enthalpy of formation of these compounds on their detonation performance is also examined in this work. Furoxanes plays particular part among energetic materials. They are convenient blocks of molecules of high-power energetic materials. Joining of explosiphorus clusters of atoms are lead to obtaining of number of high-performance compounds. It is caused by flatten structure of furoxane ring, that lead to high density of compounds and are characterized by high and positive value of enthalpy of formation. Detonation performance of furoxanes was not study practically. That is why 10 furoxanes have been chosen as object of study (see Nomenclature). 7 of 10 studied furoxanes have anomalous elemental composition, because they are hydrogenfree. In order to evaluate possible error in computational detonation performance, explosive characteristics of 6 hydrogen-free energetic materials with known experimental data have been calculated.
Źródło:
Central European Journal of Energetic Materials; 2008, 5, 3-4; 45-54
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Some Perspectives on Estimating Detonation Properties of C, H, N, O Compounds
Autorzy:
Politzer, P.
Murray, J. S.
Powiązania:
https://bibliotekanauki.pl/articles/358498.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
detonation velocity
detonation pressure
density
enthalpy of formation
detonation product composition
explosives
Opis:
We have explored various aspects of the Kamlet-Jacobs equations for estimating detonation velocities and pressures. While the loading density of the explosive compound is certainly an important determinant of these properties, its effect can sometimes be overridden by other factors, such as the detonation heat release and/or the number of moles of gaseous products. Using a gas phase rather than solid phase enthalpy of formation in obtaining a compound's heat release can produce a signifcant error in the calculated detonation velocity. However a negative enthalpy of formation is not necessarily incompatible with excellent detonation properties. Additional evidence is presented to support Kamlet and Jacobs' conclusion that, for C, H, N, O explosives, assuming the detonation product composition to be N2(g)/H2O(g)/CO2(g)/C(s) gives overall quite satisfactory results.
Źródło:
Central European Journal of Energetic Materials; 2011, 8, 3; 209-220
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prediction of Detonation Pressure and Velocity of Explosives with Micrometer Aluminum Powders
Autorzy:
Zhang, Q.
Chang, Y.
Powiązania:
https://bibliotekanauki.pl/articles/358334.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
aluminized explosives
detonation pressure
nonideal explosives
detonation velocity
Opis:
The data reported shows that the Chapman-Jouguet (CJ) detonation parameters of non-ideal explosives calculated from existing thermodynamic computer codes are significantly different from experimental results. We use CJ detonation theory to present a new approach predicting detonation pressure and velocity of aluminized explosives by thermodynamic detonation theory. There is no need to use the assumption of full and partial equilibrium of aluminum powder in reaction zones in the new approach. In this work the best agreement with experimental data was obtained by adjusting the parameter k in the Becker- Kistiakosky-Wilson equations of state (BKW-EOS). The detonation pressure and velocity values calculated by the present method agree well with the experimental results. All of the deviations for the calculated pressures of aluminized explosives are less than 9% and those for the detonation velocities are less than 7%.
Źródło:
Central European Journal of Energetic Materials; 2012, 9, 1; 77-86
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Detonator Shell Materials on Detonation Calorimetry Results
Autorzy:
Němec, Ondřej
Musil, Tomáš
Künzel, Martin
Powiązania:
https://bibliotekanauki.pl/articles/1062738.pdf
Data publikacji:
2020
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
detonation calorimetry
detonator
PETN
heat of detonation
bomb calorimetry
Opis:
Detonation calorimetry is a method for the determination of the heat released by the detonation of an explosive charge. Compared to classical combustion calorimetry, detonation calorimetry requires an inert atmosphere, a large sample mass and a detonator for its initiation. This detonator releases some energy for which the results must be corrected. Four types of detonator have been tested in the calorimeter alone and also in combination with explosive charges of PETN. It was found that the aluminium shell of the detonator considerably increases the apparent heat of detonation of the PETN samples in a vacuum, while the presence of combustible (polymeric) components has the opposite effect. Pressurization of the calorimetric vessel with nitrogen gas only partially suppresses these effects. The preferred technique is to use copper or glass confinement in a high pressure inert atmosphere.
Źródło:
Central European Journal of Energetic Materials; 2020, 17, 4; 552-565
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Detonation Parameters of PlSEM Plastic Explosive
Autorzy:
Cardoso, Aline Anastacio
Selesovsky, Jakub
Künzel, Martin
Kucera, Jindrich
Pachman, Jiri
Powiązania:
https://bibliotekanauki.pl/articles/358518.pdf
Data publikacji:
2019
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
Detonation velocity
PlSEM
plastic explosive
detonation pressure
cylinder test
Opis:
PlSEM is a plastic explosive based on RDX, PETN and a non-explosive binder, and is used in linear shaped charges for demolition purposes. Its experimentally obtained detonation parameters are presented in the present paper. The detonation velocity was measured for cylindrical charges of various diameters, with and without confinement. The detonation pressure and particle velocity were determined using an impedance window matching technique, and cylinder tests were used to obtain the parameters of the JWL equation of state of the detonation products. Detonation velocities from 7.75 to 8.05 km·s–1 were obtained for unconfined charges with diameters from 4 to 8 mm, and from 8.15 to 8.24 km·s–1 for charges with 25 mm diameter. The experimentally determined detonation pressure was found to be 24.6 GPa.
Źródło:
Central European Journal of Energetic Materials; 2019, 16, 4; 487-503
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on the Detonation Parameters of Aluminized Explosives Based on a Disequilibrium Multiphase Model
Autorzy:
Pei, H.
Nie, J.
Jiao, Q.
Powiązania:
https://bibliotekanauki.pl/articles/358535.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
nonideal explosives
velocity of detonation
detonation pressure
relaxation timescale
Opis:
Detonation models are usually based on the classical Euler equations of gas dynamics under the assumption of thermodynamic equilibrium. However reported data show the Chapman-Jouguet (CJ) detonation parameters of nonideal explosives based on thermodynamic equilibrium codes are significantly different from experimental results. Based on the conventional CJ model, a new multiphase flow model, not in thermal equilibrium, was considered in this study. This approach was applied to compute the velocity of detonation for several aluminized explosives. The predictions are better than the CJ equilibrium model and are in excellent agreement with experimental data. All of the deviations for the velocity of detonation (VOD) are less than 4%.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 4; 491-500
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Detonation Characteristics of Gaseous Isopropyl Nitrate at High Concentrations
Autorzy:
Zeng, Linghui
Liang, Huimin
Zhang, Qi
Powiązania:
https://bibliotekanauki.pl/articles/27788043.pdf
Data publikacji:
2021
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
isopropyl nitrate
detonation properties
detonation products
fuel-rich
numerical simulation
Opis:
Isopropyl nitrate (IPN) is a component of propellant fuel. High concentrations of IPN can still produce detonation. To date, very limited literature is available regarding high concentrations of IPN detonations. The detonation pressure is related to the equivalence ratio and density of IPN/air mixtures. These two factors have opposing effects on the detonation of an IPN/air mixture. The detonation characteristics of gaseous IPN/air mixtures at high concentrations (300-4000 g/m3) have been studied numerically. The results showed that when the IPN concentration is 300-600 g/m3, density played a dominant role on detonation. The maximum detonation pressure, 2.81 MPa, and the maximum detonation velocity, 1890 m/s, occurred at a concentration of 600 g/m3 (equivalence ratio Φ = 2.15). When the IPN concentration was increased from 300 to 600 g/m3, the peak overpressure and velocity increased by 19.6% and 6.2%, respectively. When the IPN concentration is higher than 600 g/m3, the equivalence ratio is extremely large and the detonation properties were seriously degraded. An analysis of the detonation products illustrated the burn-off rate of high concentrations of IPN and the influence of the detonation product CH3CHO. At a concentration of 600 g/m3, the IPN/air mixture can achieve optimal detonation properties and fuel economy.
Źródło:
Central European Journal of Energetic Materials; 2021, 18, 2; 245--270
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nitro Groups vs. N-Oxide Linkages: Effects Upon Some Key Determinants of Detonation Performance
Autorzy:
Politzer, P.
Murray, J. S.
Powiązania:
https://bibliotekanauki.pl/articles/358223.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
C,H,N,O explosives
detonation velocity
detonation pressure
N-oxides
polyazines
polyazoles
detonation heat release
crystal density
heats of formation
gaseous detonation products
Opis:
Increasing the nitrogen/carbon ratios in the molecular frameworks of C,H,N,O explosives has attracted considerable attention because it tends to result in more positive heats of formation and often greater densities. In conjunction with this, there has been a growing interest in N-oxide linkages, N+ → O−, as another source of oxygen in these compounds, in addition to or even possibly replacing NO2 groups. In this study, for a series of polyazines and polyazoles, we have compared the effects of introducing a single N-oxide linkage or NO2 group upon key properties that affect detonation velocity and detonation pressure. We found that: (1) The heats of formation per gram of compound, which is what is relevant for this purpose, are almost always higher for the N-oxides. (2) The nitro derivatives have greater densities and detonation heat releases. In relation to the latter, it must be kept in mind that increasing detonation heat release tends to be accompanied by increasing sensitivity. (3) The N-oxides produce more moles of gaseous detonation products per gram of compound.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 3-25
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Molecular Dynamics Study of Vibrational Nonequilibrium in Detonation of Polyatomic Liquids
Autorzy:
Smirnov, A. L.
Dremin, A. N.
Powiązania:
https://bibliotekanauki.pl/articles/358863.pdf
Data publikacji:
2008
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
molecular dynamics
detonation
Opis:
Energy transfer mechanisms to internal molecular degrees of freedom in shock and detonation waves in polyatomic liquids are investigated. The proposed approach uses a new version of the method of nonequilibrium molecular dynamics based on the simplest model potential energy surfaces of reacting polyatomic molecules. The main feature is adaptation of some results and approaches of gas theory to liquids. It is shown that vibrational nonequilibrium is produced by shock compression and influences on chemical reactions. So, the structure of shock and detonation waves depends strongly on the peculiarities of vibrational spectra and the structure of normal modes of compounds. Numerical simulations have been carried out for steady state detonation waves and processes of initiation of detonation by shock waves or by local heating. The results demonstrate different shock wave chemistry for substances of almost identical behaviour at static conditions.
Źródło:
Central European Journal of Energetic Materials; 2008, 5, 1; 63-74
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies on Empirical Approaches for Estimation of Detonation Velocity of High Explosives
Autorzy:
Shekhar, H.
Powiązania:
https://bibliotekanauki.pl/articles/358324.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
explosives
detonation
velocity of detonation (VOD)
empirical
density
heat of formation
Opis:
Despite many computer based codes like CHEETAH, TIGER, RUBY, BKW, etc. the velocity of detonation (VOD) for explosive molecules and explosive mixtures (formulations) is estimated by several empirical formulations. This article discusses various approaches for the estimation of the velocity of detonation by empirical mathematical equations. The formulation proposed by Kamlet in 1968 is the oldest one and it is confirmed to be more reliable by many subsequent researchers. The method proposed by Rothstein (1978), Xiong (1985), Stein (1990), Keshavarz (2006) are discussed and compared for conventional explosive molecules like RDX, HMX, TNT, PETN, and HNS. The values of the velocity of detonation for these molecules are found to be very close to each other. Further comparison of empirical mathematical formulations was carried out for four other explosive molecules of relatively recent origin (CL-20, FOX-7, TATB and NTO). These molecules were selected as they were unknown at the time of the proposed formulations except that by Keshavarz (2006). For CL-20, the velocity of detonation by different methods is 9345.1 m/s (Kamlet), 9378.8 m/s (Rothstein), 9116.0 m/s (Xiong), 9383.7 m/s (Stein) and 9887.9 m/s (Keshavarz) respectively. The method proposed by Keshavarz gives a higher value of the velocity of detonation than the others. For FOX-7, the values are 8636.6 m/s (Kamlet), 8733.3 m/s (Rothstein), 8766.1 m/s (Xiong), 8645.0 m/s (Stein) and 8245.3 m/s (Keshavarz) respectively. In this case the Keshavarz approach gives a lower value of the velocity of detonation. For these molecules, the results by the Xiong method is very close to that obtained by the Kamlet method. Deviation, as well as dispersion of the calculated values by other methods, is on the high side.
Źródło:
Central European Journal of Energetic Materials; 2012, 9, 1; 39-48
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Detonation Performance of Aluminium - Ammonium Nitrate Explosives
Autorzy:
Paszula, J.
Trzciński, W. A.
Sprzątczak, K.
Powiązania:
https://bibliotekanauki.pl/articles/358869.pdf
Data publikacji:
2008
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
nonideal explosives
detonation
performance
Opis:
The research on an effect of aluminium contents on detonation characteristics of ammonium nitrate explosives was carried out. Measurements of detonation velocity were performed. Parameters of blast waves produced by charges of the investigated explosives detonating in an open space were measured by the use of piezoelectric gauges. Quasi-static pressure measurements were conducted in a steel chamber of 0.15 m3 volume filled with air. Moreover, the heat of detonation was measured with a calorimetric set in a 5.6 dm3 bomb filled with argon. The results of measurements of QSP, detonation velocity and heat were compared with those obtained from thermochemical calculations.
Źródło:
Central European Journal of Energetic Materials; 2008, 5, 1; 3-11
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Detonation Performance of Oxygen-rich Trinitromethylsubstituted Pyrazoles: an in-silico Investigation
Autorzy:
Naithani, N.
George, B. K.
Powiązania:
https://bibliotekanauki.pl/articles/358132.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
nitropyrazole
aminonitropyrazoles
detonation velocity
detonation pressure
density functional theory
high energy molecules
Opis:
A new class of high energy molecules was designed and their detonation properties were evaluated using thermo-chemical parameters obtained from quantum chemical calculations at B3LYP/6-31G(d,p) level. The designed molecules exhibited high density, positive oxygen balance and excellent detonation properties. The impact sensitivity of these molecules, in terms of H50 values, was also evaluated from structural correlations. Among these, 3,4,5-tris(trinitromethyl)1H-pyrazol-1-amine (N13) showed the highest detonation pressure (40.67 GPa) and highest detonation velocity (9.17 km/s), though it exhibited high impact sensitive (H50 = 15 cm). Interestingly, 4,5-dinitro-3-(trinitromethyl)-1H-pyrazol-1-amine (N01) (detonation pressure 39.69 GPa; detonation velocity 9.23 km/s) was found to be an ideal high energy molecule with a near zero oxygen balance. The H50 value of N01 was predicted to be 64 cm, which is higher in magnitude, indicating a lower sensitivity than that of the conventionally used RDX (H50 = 26 cm).
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 4; 537-533
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
OPTIMEX: Measurement of Detonation Front Curvature with a Passive Fiber Optical System
Autorzy:
Pachman, J.
Künzel, M.
Kubát, K.
Selesovsky, J.
Maršálek, R.
Pospíšil, M.
Kubíček, M.
Prokeš, A.
Powiązania:
https://bibliotekanauki.pl/articles/358142.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
detonation front curvature
detonation shock curvature
A-IX-1
RDX
OPTIMEX
Opis:
The ability of a newly developed independent passive optical system OPTIMEX to measure the detonation front curvature is demonstrated on charges of pressed explosive A-IX-1 (RDX/ceresin-stearin mixture with 95/5 wt.%). The charges, with length to diameter ratios of from one to four, were prepared from cylinders with diameters of 21 mm, 30 mm, 40 mm and 50 mm pressed to a density of 1.66 g/cm3. Such charges detonate with a velocity of 8220 m/s. The detonation curvature was obtained using 8 optical fibers and the results were compared with photographs acquired by an ultra-high speed framing camera UHSi 12/24.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 807-820
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 86

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