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Wyszukujesz frazę "Materials" wg kryterium: Temat


Tytuł:
Nanoscale Aluminum - Metal Oxide (Thermite) Reactions for Application in Energetic Materials
Autorzy:
Piercey, D. G.
Klapötke, T. M.
Powiązania:
https://bibliotekanauki.pl/articles/358693.pdf
Data publikacji:
2010
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
nano-aluminum
materials
thermites
energetic materials
Opis:
Energetic materials fnd use in both military and civilian applications, however many commonly used materials suffer from serious defciencies including toxicity and high sensitivity. Nanothermites exhibit vastly differing characteristics compared to their well known micron scale relatives and through the use of various preparatory chemical techniques can be tailored to have a wide spectra of chemical and energetic properties. This may allow use as superior replacements of conventional energetic materials in various applications.
Źródło:
Central European Journal of Energetic Materials; 2010, 7, 2; 115-129
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Compatibility Study of 2,6-Diamino-3,5-dinitropyridine-1-oxide with Some Energetic Materials
Autorzy:
Li, X.
Wang, B.-L,
Lin, Q.-H.
Powiązania:
https://bibliotekanauki.pl/articles/358871.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
compatibility
energetic materials
ANPyO
Opis:
For the application of 2,6-diamino-3,5-dinitropyridine-1-oxide (ANPyO) in composite explosives, the compatibility of ANPyO with some energetic materials was studied by the use of differential scanning calorimetry (DSC), where the energetic materials were cyclotrimethylenetrinitramine (RDX), cyclotetramethylenetetranitramine (HMX), 3,4-dinitrofurazanfuroxan (DNTF), hexanitrohexazaisowurtzitane (CL-20), 2,4,6-trinitrotoluene (TNT), 2,4,6-triamino-1,3,5-trinitrobenzene (TATB), 3-nitro-1,2,4-triazol-5-one (NTO), 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105), 5-amino-1H-tetrazole nitrate (5-ATEZN), ammonium perchlorate (AP), potassium perchlorate (KP), aluminum powder (Al), boron powder (B), magnesium hydride (MgH2) and magnesium borohydride (Mg(BH4)2). The results showed that the binary systems of ANPyO/CL-20, ANPyO/NTO, ANPyO/5-ATEZN, ANPyO/Al, ANPyO/B, ANPyO/MgH2 and ANPyO/Mg(BH4)2 are compatible, and that the systems of ANPyO with RDX, LLM-105, HMX, AP and KP are sensitive, and with DNTF, TNT and TATB are incompatible.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 978-988
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Review of the Photodecomposition of Some Important Energetic Materials
Autorzy:
Sun, Y.
Shu, Y.
Xu, T.
Shui, M.
Zhao, Z.
Gu, Y.
Wang, X.
Powiązania:
https://bibliotekanauki.pl/articles/358397.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
photodecomposition mechanisms
energetic materials
Opis:
The photodecomposition mechanisms of energetic materials vary with molecular structure, photodissociation wavelength, the phase of the material, experimental pressure and temperature etc. In this paper, the significant progress on photodecomposition studies of some important energetic materials achieved in recent years is introduced in detail, including nitromethane, DMNA (dimethylnitramine), TATB (1,3,5-triamino-2,4,6-trinitrobenzene), RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), HMX (1,3,5,7-tetranitro-1,3,5,7- tetrazacycloctane) and CL-20 (2,4,6,8,10,12-hexanitrohexaazaisowurtzitane). The difficulties and prospects of photodecomposition research of energetic materials are also indicated.
Źródło:
Central European Journal of Energetic Materials; 2012, 9, 4; 411-423
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pre-formulation Compatibility Studies of 5-Amino-1H-tetrazole Nitrate with Several Typical Materials by Thermal and Non-thermal Techniques
Autorzy:
Guo, W.
Han, Z.
Lin, Q.
Wang, B.
Powiązania:
https://bibliotekanauki.pl/articles/358375.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
5-ATN
compatibility
energetic materials
Opis:
The aim of the present study was to assess the physicochemical compatibility of a promising energetic salt, 5-amino-1H-tetrazole nitrate (5-ATN), with some typical materials. Thermal techniques (differential scanning calorimetry (DSC) and vacuum stability test (VST)) and non-thermal techniques (X-ray diffractometry (XRD) and Fourier Transform Infrared Spectroscopy (FTIR)) were applied. Five energetic materials (TNT, RDX, HMX, CL-20 and AP) and three common additives (Al, DOS and F2604-2) were tested to evaluate their compatibility with 5-ATN. Based on the DSC results, except for AP that was only partially compatible with 5-ATN, all of the selected materials exhibited good compatible with 5-ATN. The VST test further confirmed the compatibility of the 5-ATN/AP mixtures. Combined with the thermal methods, the FTIR results agreed with the DSC findings. The XRD results showed some differences.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 100-114
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Review of Nano-thermites: a Pathway to Enhanced Energetic Materials
Autorzy:
Zaky, Mohamed Gaber
Elbeih, Ahmed
Elshenawy, Tamer
Powiązania:
https://bibliotekanauki.pl/articles/27787860.pdf
Data publikacji:
2021
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic materials
nanothermite
synthesis
applications
Opis:
Nano-thermites or metastable intermolecular composites (MICs) have been implemented into modern research on energetic materials as they offer much higher energy densities, higher rates of energy release, stability, and safety (lower sensitivity). This paper reviews several synthetic methods for MICs that have been well thought-out for energetic applications, advantages and disadvantages, as well as the characteristics of each manufacturing technique. The techniques presented include powder mixing, sol-gel, synthesis of MICs based on nano-porous silicon (Psi), sputtering, multilayer nano-foils and electrolytically plated carbon nano-materials for nano-thermite applications. These techniques offer enormously different characteristics and, through the variation of various chemical techniques and conditions, a wide range of chemical and energetic properties may be attained. This may give the opportunity for the safe use of MICs as replacements for some conventional energetic materials in various applications, and may also enable us to study the effects when incorporating these MICs into energetic matrixes, as a promising and feasible research field.
Źródło:
Central European Journal of Energetic Materials; 2021, 18, 1; 63--85
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation and Characterization of 1-(5-Azido-1H-1,2,4-triazol-3-yl)tetrazole
Autorzy:
Izsák, D.
Klapötke, T. M.
Powiązania:
https://bibliotekanauki.pl/articles/358367.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic materials
heterocycles
triazoles
tetrazoles
azides
Opis:
This study presents the preparation of 1-(5-azido-1H-1,2,4-triazol-3yl)tetrazole (5) from commercially available chemicals in a five step synthesis. The energetic title compound was comprehensively characterized by various means, including vibrational (IR, Raman) and multinuclear (1H, 13C, 14N, 15N) NMR spectroscopy, mass spectrometry and differential scanning calorimetry. The sensitivities towards various outer stimuli (impact, friction) were determined according to BAM standards. The enthalpy of formation was calculated at the CBS-4M level of theory.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 3; 403-416
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
5,5'-Dinitrimino-3,3'-methylene-1H-1,2,4-bistriazole - a Metal Free Primary Explosive Combining Excellent Thermal Stability and High Performance
Autorzy:
Dippold, A. A.
Feller, M.
Klapötke, T. M.
Powiązania:
https://bibliotekanauki.pl/articles/358456.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic materials
triazoles
detonation parameter
sensitivities
Opis:
The synthesis of 5,5´-dinitrimino-3,3'-methylene-1H-1,2,4-triazole (1) and selected nitrogen rich salts are presented. All compounds were fully characterized in terms of sensitivity and energetic properties. Besides a chemical characterization including multinuclear magnetic resonance study (1H, 13C, 14N) and vibrational analysis (IR, Raman), X-Ray diffraction was performed. Thermal stability was determined using differential scanning calorimetry. Detonation parameters were calculated using the EXPLO5.4 code based on CBS-4M computed heats of formation. The presented compound 5,5´-dinitrimino-3,3´-methylene- 1H-1,2,4-bistriazole shows excellent thermal stabilities in combination with high sensitivities and therefore is of interest for possible applications as metal free primary.
Źródło:
Central European Journal of Energetic Materials; 2011, 8, 4; 261-278
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
4-Amino-3-hydrazino-1,2,4-triazole: a Precursor for the Preparation of Divalent Energetic Materials
Autorzy:
Lin, Q.
Wang, P.
Sun, Q.
Lu, M.
Powiązania:
https://bibliotekanauki.pl/articles/951501.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic materials
detonation performance
nitrogen heterocycle
Opis:
4-Amino-3-hydrazino-1,2,4-triazole (AHT) was developed as a divalent cation. The multivalent structure can be used to increase the number of nitrogen-rich heterocycles, thereby increasing the heat of formation and improving the detonation performance. Herein we report on a family of divalent energetic salts, which exhibit excellent properties, viz. acceptable density, good detonation performance, and desirable thermal and impact stabilities. The structural features of the salts were further determined by single-crystal X-ray diffraction. In addition, the detonation properties calculated for these energetic salts identified them as competitively energetic compounds.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 18-29
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hydrazinium 5-Aminotetrazolate: an Insensitive Energetic Material Containing 83.72% Nitrogen
Autorzy:
Fischer, N.
Klapötke, T. M.
Scheutzow, S.
Stierstorfer, J.
Powiązania:
https://bibliotekanauki.pl/articles/358539.pdf
Data publikacji:
2008
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
hydrazines
tetrazoles
crystal structure
energetic materials
sensitivities
Opis:
Hydrazinium 5-aminotetrazolate (2) was synthesized via two facile routes. Both the reaction of 5-amino-1H-tetrazole (1) with hydrazine hydrate in aqueous solution and the reaction of 1 with diluted hydrazine solution in THF yield 2 in excellent purities and yields. 2 was characterized comprehensively by X-ray diffraction, IR, Raman and multinuclear NMR spectroscopy, mass spectrometry, elemental analysis and differential scanning calorimetry. The heat of formation was calculated (CMS-4M) using the atomization method to be 373 kJ mol-1. With this value and the X-ray density several detonation parameter (heats of explosion, detonation pressure, detonation velocity, explosion temperature) were calculated with the EXPLO5 computer software. An incredible high value (9516 m s-1) was obtained for the detonation velocity. Therefore experimentally tests to determine the velocity of detonation were performed. In addition the use of 2 in solid propellant compositions was calculated and tested in combination with oxidizers, e.g. ammonium dinitramide. Lastly the sensitivities towards impact, friction and electrostatic discharge were determined with the BAM drophammer, friction tester and an ESD machine.
Źródło:
Central European Journal of Energetic Materials; 2008, 5, 3-4; 3-18
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of polar plasticizers on the characteristics of selected cyclic nitramines
Autorzy:
Elbeih, A.
Zeman, S.
Pachman, J.
Powiązania:
https://bibliotekanauki.pl/articles/358627.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic materials
polymers
sensitivity
combustion
thermal stability
Opis:
Dioctyl sebacate (DOS) is a plasticizer used with oily material for the softening of polyisobutylene binder (PIB) to form a polymeric matrix. This matrix was used for the preparation of various plastic explosives. The following energetic cyclic nitramines were used as explosive fillers: BCHMX (cis-1,3,4,6- tetranitrooctahydroimidazo [4,5 d]imidazole), ε-HNIW (ε-2,4,6,8,10,12- hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane), RDX (1,3,5-trinitro-1,3,5- triazacyclohexane), and HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazacyclooctane). For comparison, Fluorel binder was used for the preparation of several plastic bonded explosives (PBXs) based on the same selected explosives. Impact and friction sensitivities of the prepared samples and the pure explosive fillers were measured. The thermal stability was studied using differential thermal analysis (DTA). High performance liquid chromatography (HPLC) was used to detect the presence of BCHMX dissolved in dioctyl sebacate (DOS). The heat of combustion of the prepared samples and of the pure explosive fillers was measured using a bomb calorimetry. The results show that PIB softened by plasticizer (DOS) has a greater positive effect on decreasing the impact sensitivity of the studied pure explosives than Fluorel binder. On the other hand, the plasticizer acts as a solvent for the energetic materials and decreases the decomposition temperature of these plastic explosives.
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 3; 339-349
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on a New Synthesis of LLM-105 Using N-Nitroso-bis(cyanomethyl)amine
Autorzy:
Jing, S.
Liu, Y.
Liu, D.
Guo, J.
Powiązania:
https://bibliotekanauki.pl/articles/358371.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
LLM-105
energetic materials
synthesis
characterization
properties
Opis:
A new three-step synthetic method was designed to prepare 2,6-diamino- 3,5-dinitropyrazine 1-oxide (LLM-105) with an overall yield of 43.5%, using iminodiacetonitrile, triethylamine and hydroxylamine hydrochloride as the starting materials, and involved nitrosylation, cyclization and nitration. The structure of LLM-105 was characterized by FTIR, 1H NMR spectroscopy and elemental analysis. The crucial factors and mechanism of the cyclization were explored. Thermal decomposition, mechanical sensitivity and the purity of the LLM-105 were determined by TG-DTA, an impact sensitivity instrument and high performance liquid chromatography (HPLC) respectively. The results showed that LLM-105 synthesised via 2,6-diamino-3,5-dinitropyrazine (ANPZ) was less sensitive to impact, but the LLM-105 synthesized by the new method had some obvious advantages in terms of purity, security and production costs. Moreover, the LLM-105 synthesized by this new method can be initiated reliably without recrystallization.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 1; 21-32
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Combustion Synthesis of Titanium Carbonitrides
Autorzy:
Dyjak, S.
Wasilewska, M.
Cudziło, S.
Powiązania:
https://bibliotekanauki.pl/articles/358421.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
combustion synthesis
titanium carbonitride
ceramics
refractory materials
Opis:
Titanium carbonitride (TiC0.5N0.5) micron powders were synthesized in reactions of titanium with zinc dicyanide: Zn(CN)2 + 4Ti → 4TiC0.5N0.5 + Zn. The reactions are sufficiently exothermic to propagate in the reactant mixture to form a self-sustaining, high-temperature synthesis (SHS). The final product was separated and the only byproduct (zinc) was removed by dissolution in dilute hydrochloric acid. The use of zinc dicyanide as the source of carbon and nitrogen causes the titanium carbonitride to contain only these elements in an atomic ratio of one. The reaction temperature can be easily reduced by the addition of zinc powder to the green mixture. Synthesis in the presence of zinc yields TiC0.5N0.5 powders consisting of round-shaped and unagglomerated particles.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 2; 249-259
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Calculation of Combustion, Explosion and Detonation Characteristics of Energetic Materials
Autorzy:
Grys, S.
Trzciński, W. A.
Powiązania:
https://bibliotekanauki.pl/articles/358699.pdf
Data publikacji:
2010
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
thermochemical codes
energetic materials
combustion
explosion
detonation
Opis:
In this work, the thermodynamic code for the determination of the chemical equilibrium composition of a non-ideal heterogeneous system is presented. Computation of combustion, explosion and detonation parameters for some explosives is performed as well as isentropes of products expansion and detonation energy are estimated. Moreover, the non-equilibrium calculations are carried out, in which chemical inertness of one from the components of explosive composition as well as no heat exchange between the component and the detonation products are assumed. At the end, some calculated detonation characteristics are compared with the experimental ones.
Źródło:
Central European Journal of Energetic Materials; 2010, 7, 2; 97-113
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Environmental Long Term Impact on a Romanian Military Testing Range
Autorzy:
Petre, R.
Rotariu, T.
Zecheru, T.
Petrea, N.
Băjenaru, S.
Powiązania:
https://bibliotekanauki.pl/articles/358798.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
contamination
analytical methods
heavy metals
energetic materials
Opis:
Military range management has become extremely important in recent years, in order to comply with the limitations imposed by national and international environmental regulations. In this regard, soil, vegetation and ground water samples from a testing facility belonging to the Romanian Ministry of National Defense were analyzed for contamination with metals and energetic materials. The tests confirmed the presence of contaminants as energetic materials and heavy metals (Pb, Cu, Zn), with a heterogeneous distribution on the range and concentrated in the impact and firing line areas.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 1; 3-19
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Study of a Protective Container for Combined Blast, Fragmentation and Thermal Effects from Energetic Materials Detonation
Autorzy:
Ahmed, Khurshid
Malik, Abdul Qadeer
Powiązania:
https://bibliotekanauki.pl/articles/27788212.pdf
Data publikacji:
2022
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic materials
fireball
blast
fragmentation
container
mitigation
Opis:
A composite protective container is experimentally investigated to counter combined blast, fragmentation and thermal effects from either a 1.0 kg bare or 0.6 kg cased (pipe-bomb) TNT equivalent charge. Commercially available shaving foam was used as the internal filling material. The shaving foam quenched the initial fireball and afterburning reactions. The composite case contained the blast overpressure and prevented the escape of primary fragments. The novel combination of extended polystyrene (EPS) foam, bakelite and polyurethane (PU)-silica composite employed at the container base provided protection against in-contact explosive detonation. Maximum peak reflected overpressure of 86.87 kPa (12.6 psi) was measured at 1.0 m distance for 1.0 kg TNT equivalent charge detonation inside the container. The protective container provided 97% peak overpressure reduction compared to the equivalent surface burst detonation. The fragmentation and their impact on container were simulated using a coupled SPH-ALE approach. Steel casing fragments weighing up to 8.0 g with velocities in the range of 1260-1550 m/s were produced and impacted the container. This investigation provides a basis in the design of a device to combat terrorist devices in public places, high profile meeting venues and transportation systems.
Źródło:
Central European Journal of Energetic Materials; 2022, 19, 2; 135--157
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł

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