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    Wyświetlanie 1-5 z 5
    Tytuł:
    An Analytic Investigation of "Hot-Spot" Formation in Compressible Energetic Materials
    Autorzy:
    Li, X.
    Zhao, F.
    Liu, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/358425.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    analytic model
    bulk compressibility
    pore collapse
    "hot-spot" formation
    Opis:
    In this paper, the formation of the shock-induced “hot-spot” in compressible energetic materials has been analyzed. By applying the compressible elastic-viscoplastic material model to a hollow sphere, and solving the governing equations with the initial and boundary conditions, this paper proposes an analytic pore collapse model that is able to simulate the viscoplastic deformation which determines the formation of a “hot-spot”. In this new model there are three mechanisms, of which instantaneous deformation and the subsequent quasi-static incompressible deformation dominate “hot-spot” formation, while quasi-static compressible deformation is of little effect. In comparison with the incompressible solution, this model demonstrates that the bulk compressibility has a great influence on “hot-spot” formation, as the degree of the “hot-spot” reaction is a positive quasi-linear function of Poisson’s ratio ν. An error in Kim’s original pore collapse model has also been discussed.
    Źródło:
    Central European Journal of Energetic Materials; 2017, 14, 4; 806-820
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Molecular Dynamics Simulation Studies of the CL-20/DNB Co-crystal
    Autorzy:
    Sun, T.
    Xiao, J. J.
    Ji, G. F.
    Zhao, F.
    Xiao, H. M.
    Powiązania:
    https://bibliotekanauki.pl/articles/358075.pdf
    Data publikacji:
    2016
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    CL-20/DNB co-crystal
    composite
    interactions
    mechanical properties
    molecular dynamics simulation
    Opis:
    Molecular dynamics (MD) simulation was conducted for a DNB (1,3-dinitrobenzene) crystal, a ε-CL-20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane) crystal, a CL-20/DNB co-crystal and a CL-20/DNB composite. From the calculated maximum bond length (Lmax) of the N−NO2 trigger bond, the cohesive energy density (CED) and the binding energy (Ebind), it was found that the CL-20/DNB co-crystal is more insensitive than its composite. Its thermal stability is also better than that of its composite. The pair correlation function (PCF) analysis method was applied to investigate the interfaces between different molecular layers in the CL-20/DNB co-crystal, and in the composite. Additionally, the calculated mechanical data showed that the moduli of the CL-20/DNB co-crystal and its composite are smaller and their elastic elongation and ductility are better than those of the ε-CL-20 and DNB crystals.
    Źródło:
    Central European Journal of Energetic Materials; 2016, 13, 3; 677-693
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Unravelling the Effect of Anthraquinone Metal Salts as Wide-range Plateau Catalysts to Enhance the Combustion Properties of Solid Propellants
    Autorzy:
    Wang, Y.
    Yan, Q.-L.
    An, T.
    Chen, B.
    Ji, Y.-P.
    Wang, W.
    Zhao, F.
    Powiązania:
    https://bibliotekanauki.pl/articles/358042.pdf
    Data publikacji:
    2018
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    solid propellants
    burning rate catalysts
    anthraquinone metal salts
    wide-range plateau combustion
    Opis:
    Novel lead and copper salts based on anthraquinone, including 1,8-dihydroxyanthraquinone,1,4,5,8-tetrahydroxyanthraquinone and 1,8-dihydroxy-4,5-dinitroanthraquinone, were prepared and characterized by Fourier transform infrared spectroscopy (FTIR), elemental analysis (EA), and X-ray fluorescence (XRF). The catalytic effects of these compounds on the decomposition of nitrocellulose (NC) and on the combustion properties of double-base (DB) and composite modified double-base (CMDB) propellants were comprehensively investigated. The results demonstrated that the burning rate is significantly increased (by 200%) in the lower pressure range (2-6 MPa) as compared to the control systems without added anthraquinone-based salts. Concurrently, the pressure exponents (n) were obviously lower, exhibiting a “wide-range plateau” combustion phenomenon in the middle-pressure region. Specifically, for the DB propellants such a plateau region extended from 10 MPa to 16 MPa for n equal to 0.10, from 10 MPa to 18 MPa for n equal to 0.11 and from 8 MPa to 18 MPa when n is 0.05. In the case of RDX-CMDB propellants, the plateau was found to be in the range 6-18 MPa, with n in the range 0.16-0.27, depending on the type of catalyst, in contrast to the reference CMDB sample, which was characterized by n equal to 0.7 for the same pressure range.
    Źródło:
    Central European Journal of Energetic Materials; 2018, 15, 2; 376-390
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Combustion Characteristics and Mechanism of Boron-based, Fuel-rich Propellants with Agglomerated Boron Powder
    Autorzy:
    Xu, H. -X.
    Pang, W.-Q.
    Guo, H.-W.
    Zhao, F.-Q.
    Wang, Y.
    Sun, Z.-H.
    Powiązania:
    https://bibliotekanauki.pl/articles/358733.pdf
    Data publikacji:
    2014
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    analytical chemistry
    boron-based fuel-rich solid propellants
    agglomerated boron powder
    combustion performance
    combustion mechanism
    Opis:
    In order to extend the burning rate of boron-based, fuel-rich solid propellants with agglomerated boron powder, the effects of the boron content, the AP content, and of the magnesium powder content, on the burning rate and pressure exponent have been studied systematically. It has been shown that when the AP content is constant, the burning rate of the propellants increases with an increase in the agglomerated boron content. Furthermore, the burning rate and pressure exponent increase with increasing the contents of AP and magnesium powder. By means of single colour frame amplification photography and combustion wave tests, the combustion mechanism of these propellants has been investigated. It has been shown that the flame of the propellants becomes brighter by increasing the AP content, the dT/dxcp and dT/dxgp of the propellant FR-5 being around 6815 and 5789 °C/mm respectively, higher than those of FR-4, resulting in greater burning rates. The Ts of these propellants is above 683 °C, which is higher than the decomposition peak temperatures of agglomerated boron powder and of propellants (about 649 °C), which indicates that agglomerated boron powder is partially oxidized on the combustion surface, and the heat released from it may be beneficial to the combustion of the propellants.
    Źródło:
    Central European Journal of Energetic Materials; 2014, 11, 4; 575-587
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and Characterization of a High Energy Combustion Agent (BHN) and Its Effects on the Combustion Properties of Fuel Rich Solid Rocket Propellants
    Autorzy:
    Pang, W.-Q.
    Zhao, F.-Q.
    Xue, Y.-N.
    Xu, H.-X.
    Fan, X.-Z.
    Xie, W.-X.
    Zhang, W.
    Lv, J.
    Deluca, L. T.
    Powiązania:
    https://bibliotekanauki.pl/articles/358474.pdf
    Data publikacji:
    2015
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    fuel rich solid propellant
    BHN
    DSC
    TG-DTG
    burning rate
    combustion properties
    Opis:
    A high energy combustion agent (tetraethylammonium decahydrodecaborate, BHN) was prepared by means of an ion exchange reaction (IER), and the prepared samples were characterized by the advanced diagnostic techniques of Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), Thermogravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC) etc. The effects of BHN particles on the hazard and combustion properties of fuel rich solid propellants were investigated. The results showed that the BHN samples and fuel rich propellants containing BHN particles can be prepared successfully and solidified safely. The peak temperature of thermal decomposition and the heat of decomposition of the BHN samples prepared were 305.8 °C and 210.9 J•g-1 at a heating rate of 10 K•min-1, respectively. The burning rate and pressure exponent of fuel rich solid propellants decreases with increases in the fraction of BHN particles in the propellant formulation. Compared with the reference formulation (sample BP-1), the burning rate of the propellant with 10% mass fraction of BHN particles (sample BP-4) had decreased 30% at 3.0 MPa, and the pressure exponent had dropped from 0.44 to 0.41.
    Źródło:
    Central European Journal of Energetic Materials; 2015, 12, 3; 537-552
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-5 z 5

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