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Wyświetlanie 1-3 z 3
Tytuł:
Synthesis and Characterization of PolyNIMMO-HTPB-polyNIMMO Triblock Copolymer as a Potential Energetic Binder
Autorzy:
Wang, X.
Shu, Y.
Lu, X.
Mo, H.
Xu, M.
Powiązania:
https://bibliotekanauki.pl/articles/358529.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
triblock copolymer
cationic ring opening polymerization
polymer
DSC
Opis:
Triblock copolymer polyNIMMO-HTPB-polyNIMMO was synthesized by cationic ring opening polymerization of NIMMO (3-nitratomethyl-3-methyloxetane) in the presence of hydroxyl-terminated polybutadiene catalyzed by BF3·OEt2. The polymer was characterized by FT-IR, 1H NMR, 13C NMR spectroscopy, and GPC. DSC was used to investigate the thermal behaviour of the triblock copolymer and its exothermic decomposition peak was found to be at 215 °C. All of the results indicated that the triblock copolymer polyNIMMO-HTPB-polyNIMMO might serve as a potential energetic propellant binder.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 3; 456-467
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of the cook-off processes of HMX-based mixed explosives
Autorzy:
Chen, L.
Ma, X.
Lu, F.
Wu, J.
Powiązania:
https://bibliotekanauki.pl/articles/358000.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
explosives
chemical kinetics
thermal decomposition
cook-off
numerical simulation
Opis:
In order to investigate the characteristics of the thermal reaction for two kinds of mixed explosives, PBXC-10 (HMX/TATB/Binder, 38/57/5) and JO-8 (HMX/Binder, 95/5), multi-point measured temperature cook-off tests were carried out at different heating rates. The thermal transfer and finite chemical reactions that include the β→δ transition of HMX, and the endothermic and exothermic cook-off processes were analyzed. A 3D model of the explosive cook-off test was developed to simulate the thermal and chemical behaviour in a thermal ignition. The decomposition mechanisms for HMX and TATB are described by the multistep, chemical kinetic model. The thermal properties, decomposition pathways, and chemical kinetic reaction rate constants for each component are used to develop the reaction courses at various weight percentages. The thermal decomposition reaction of a multi-component, mixed explosive can be predicted as long as the chemical kinetics model of each single-base explosive and binder are known. The phase transition of HMX has an influence on the temperature of the explosive, especially for an explosive with a high HMX content. For mixed explosives containing HMX and TATB, most of the heat release is produced by the decomposition of HMX before ignition, but TATB can delay the ignition time and decrease the reaction violence in the cook-off process.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 2; 199-218
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Computational Investigation on the Structure and Performance of Novel 4,7-dinitro-furazano-[3,4-d]-pyridazine Derivatives
Autorzy:
Wang, K.
Shu, Y.
Liu, N.
Ding, X.
Wu, Z.
Lu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/358090.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
4,7-dinitro-furazano-[3,4-d]-pyridazine
heat of formation
density
detonation performance
bond dissociation energy
Opis:
Seven novel energetic 4,7-dinitro-furazano-[3,4-d]-pyridazine derivatives were designed, and their optimized structures and performances were studied by density functional theory (DFT) at B3LYP/6-311g(d,p) level. The detonation performances were estimated by the Kamlet-Jacobs equations. The results show that these compounds have high crystal densities (1.818-1.925 g·cm−3), detonation velocities (8.51-9.56 km·s−1) and detonation pressures (32.28-41.70 GPa). The bond dissociation energies (BDEs) of the weakest bond (N–O bond) vary from 70.889 kJ·mol−1 to 173.283 kJ·mol−1, and some of them exhibit higher BDEs than that of RDX (N–NO2 bond, 149.654 kJ·mol−1) and HMX (N–NO2 bond, 154.905 kJ·mol−1). M4 and M5 exhibit similar and higher detonation performance than RDX (8.81 km·s−1, 34.47 GPa). The detonation performance of M7 (9.56 km·s−1, 41.70 GPa) even surpasses that of HMX (9.10 km·s−1, 39.00 GPa). Otherwise, the specific impulse values of M1-M7 (266-279 s) outperform HMX (266 s) by 0-13 s, which indicates that M1-M7 may show better performance as monopropellants. It is concluded that density, heat of formation, stability, detonation performance and specific impulse of the designed compounds depend on the position and number of the N→O oxidation bonds.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 26-46
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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