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Tytuł:
Deformation Mechanisms and Fracture of Ni-Based Metallic Glasses
Autorzy:
Lesz, S.
Griner, S.
Nowosielski, R.
Powiązania:
https://bibliotekanauki.pl/articles/353790.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
metals
transmission electron microscopy
scanning electron microscopy
fracture
shear bands
Opis:
The cracking of materials and fracture surface is of great practical and academic importance. Over the last few years the development of the fractography of crystalline alloys resulted in a useful tool for the prediction or failure analysis. Many attempts have been made to observe cracks using optical microscopy, X-ray topography and transmission electron microscopy (TEM). Of these techniques, the resolution of optical microscopy and X-ray topography is too poor. By contrast, the resolution of TEM is high enough for detailed information to be obtained. However, in order to apply TEM observations, a thin foil specimen must be prepared, and it is usually extremely difficult to prepare such a specimen from a pre-selected region containing a crack. In the present work, deformation mechanisms fracture surfaces of Ni-based metallic glass samples have been studied by specially designed experiments. In order to study the deformation mechanisms and fracture the Ni-based metallic glasses have been investigated in the tensile test. The structure and fracture surfaces after the decohesion process in tensile tests were observed using transmission electron microscope (TEM) and scanning electron microscope (SEM), respectively. The studies of structure were performed on thin foils. Moreover the investigated tape was subjected to a banding test. Then, the tape was straightened and the thin foil from the area of maximum strain was prepared. This thin foil sample was deformed before the TEM investigation to obtain local tears.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2A; 791-796
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Milling Time on Amorphization of Mg-Zn-Ca Powders Synthesized by Mechanical Alloying Technique
Autorzy:
Lesz, S.
Kremzer, M.
Gołombek, K.
Nowosielski, R.
Powiązania:
https://bibliotekanauki.pl/articles/354717.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Mg-based powders
transmission electron microscopy
scanning electron microscopy
mechanical alloying
Opis:
Mg60 Zn35 Ca5 amorphous powder alloys were synthesized by mechanical alloying (MA) technique. The results of the influence of high-energy ball-milling time on amorphization of the Mg60 Zn35 Ca5 elemental blend (intended for biomedical application) were presented in the study. The amorphization process was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM). Initial elemental powders were mechanically alloyed in a Spex 8000 high-energy ball mill at different milling times (from 3 to 24 h). Observation of the powder morphology after various stages of milling leads to the conclusion that with the increase of the milling time the size of the powder particles as well as the degree of aggregation change. The partially amorphous powders were obtained in the Mg60 Zn35 Ca5 alloy after milling for 13-18h. The results indicate that this technique is a powerful process for preparing Mg60 Zn35 Ca5 alloys with amorphous and nanocrystalline structure.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 2; 845-851
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of the Quenching Rate on the Structure and Magnetic Properties of the Fe-Based Amorphous Alloy
Autorzy:
Nabiałek, M.
Powiązania:
https://bibliotekanauki.pl/articles/350944.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
transmissions electron microscopy
scanning electron microscopy
amorphous matrials
free volumes
quasidislocation
Opis:
This paper presents the results of investigations into the structure, microstructure and magnetic properties of Fe61Co10Y8W1B20 amorphous alloy. The alloy samples were in two physical forms: (1) plates of approximate thickness 0.5 mm (so-called bulk amorphous alloys) and (2) a ribbon of approximate thickness 35 μm (so-called classic amorphous alloy). The investigations comprised: X-ray diffractometry, Mössbauer spectrometry, transmission electron microscopy, and selected magnetic measurements; all of the investigations were carried out on samples in the as-quenched state. Analysis of the obtained SEM and TEM images, X-ray diffraction patterns, Mössbauer spectrometry results and measurements of the magnetisation in a high magnetic field facilitated collectively the detailed description of the structure of the investigated alloy, which was found to depend on the quenching speed.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 1; 439-444
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural Aging and Degradation of Human Fingernail Plates Upon Cosmetic Agents
Autorzy:
Kulesza, S.
Bramowicz, M.
Gwoździk, M.
Wilczyński, S.
Goździejewska, A. M.
Powiązania:
https://bibliotekanauki.pl/articles/354662.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Atomic Force Microscopy
Scanning Electron Microscopy
fractal characterization
nanoscale property mapping
Opis:
The knowledge whether and how chemical species react with tissues is important because of protection against harmful factors, diagnose of dermatological diseases, validation of dermatological procedures as well as effectiveness of topical therapies. In presented work the effects of chemical agents on plates of human fingernails were studied using Atomic Force Microscopy and Scanning Electron Microscopy. Apart from that, mapping of the elastic properties of the nails was also carried out. To obtain reliable measures of spatial evolution of the surface variations, recorded images were analyzed in terms of scaling invariance brought by fractal geometry, instead of common though not unique statistical measures.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 1; 181-184
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization of Microwave Sintered Aluminium Composite Reinforced with Hydroxyapatite Extracted from Rihu Fish Scales
Autorzy:
Venkatesh, V.S.S.
Prasad, Kalapala
Deoghare, Ashish B.
Powiązania:
https://bibliotekanauki.pl/articles/27765073.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
hydroxyapatite
aluminium matrix
microwave sintering
mechanical properties
Scanning Electron Microscopy
Opis:
In this study, Hydroxyapatite (HAp) is extracted from the Rihu fish scales which are generally dumped as garbage. The aluminium composite was fabricated through the powder metallurgy technique by reinforcing HAp (0, 5, 10 and 15 wt%) as a reinforcement. The fabricated samples were sintered through microwave sintering at 530℃ for 15 min under an argon gas environment. The fabricated composites were subjected to X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS) analysis to confirm the constituting elements and to describe the reinforcement dispersion in the matrix. Uniform reinforcement dispersion was observed for the composite reinforces with 5% HAp, 10% HAp particles. The mechanical characterization results reveal that the Al-10% HAp composite exhibits a microhardness value of 123 ± 3 Hv and maximum ultimate tensile strength of 263 ± 10 MPa and 299 ± 9 MPa compression strength was obtained due to the presence of a strong bond among the aluminium and HAp particles.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 2; 617--624
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural Deformation of Tungsten Diselenide Nanostructures Induced by Ozone Oxidation and Investigation of Electronic Properties Change
Autorzy:
Kim, Eunjeong
Lee, Sangyoeb
Je, Yeonjin
Lee, Dong Park
Park, Sang Jun
Jeong, Sanghyun
Park, Joon Sik
Ahn, Byungmin
Park, Jun Hong
Powiązania:
https://bibliotekanauki.pl/articles/2176647.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
tungsten diselenide
domain boundary
ozone oxidation
structural deformation
scanning tunneling microscopy
Opis:
Tungsten diselenide (WSe2) is one of the promising transition metal dichalcogenides (TMDs) for nanoelectronics and opto-electronics. To enhance and tune the electronic performance of TMDs, chemical functionalization via covalent and van der Waals approaches has been suggested. In the present report, the electric and structural transition of WSe2 oxidized by exposure to O3 is investigated using scanning tunneling microscopy. It is demonstrated that the exposure of WSe2/high-ordered pyrolytic graphite sample to O3 induces the formation of molecular adsorbates on the surface, which enables to increase in the density of states near the valence band edge, resulting from electric structural modification of domain boundaries via exposure of atomic O. According to the work function extracted by Kelvin probe force microscopy, monolayer WSe2 with the O3 exposure results in a gradual increase in work function as the exposure to O3. Therefore, the present report demonstrates the potential pathway for the chemical functionalization of TMDs to enhance the electric performance of TMDs devices.
Źródło:
Archives of Metallurgy and Materials; 2022, 67, 4; 1469--1473
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of the Powder Consolidation Method Type on the Microstructure and Selected Properties of Al2O3-Cu-Ni Composite
Autorzy:
Zygmuntowicz, J.
Wachowski, M.
Piotrkiewicz, P.
Kaszuwara, W.
Powiązania:
https://bibliotekanauki.pl/articles/351724.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
composites
Pulse Plasma Sintering
Uniaxial Powder Pressing
Scanning Electron Microscopy
Opis:
The present research is focused on the characterization of the composites from Al2O3-Cu-Ni system. Two methods of ceramic-metal composite forming were applied: uniaxial powder pressing and Pulse Plasma Sintering (PPS). To obtain the samples the powder mixtures containing 85 vol.% of Al2O3 and 15 vol.% of metal powders were used. Influence of the sintering process on microstructure and mechanical properties of the two series of the composites was analyzed in detail. The selected physical properties of samples were characterized by Archimedes immersion method. Vickers hardness and the fracture toughness of the composites was determined as well. The microstructure of the composites was characterized by XRD, SEM, EDX. Fractography investigation was carried out as well. Independently on composite production method Al2O3, Cu, Ni, and CuNi phases were revealed. Fractography investigation results revealed different character of fracture in dependence of fabrication method. Pulse Plasma Sintered samples were characterized by higher crack resistance and higher Vickers hardness in comparison to the specimens manufactured by uniaxial pressing.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 967-974
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanical properties of Ni-Fe-Cu-P-B alloy produced by two component melt spinning (TCMS)
Autorzy:
Wojciechowska, M.
Ziewiec, K.
Kąc, S.
Prusik, K.
Powiązania:
https://bibliotekanauki.pl/articles/351728.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
metallic glasses
scanning electron microscopy (SEM)
nanoindentation
transmission electron microscopy TEM
mechanical properties
Opis:
The aim of this work was to investigate the microstructure and mechanical properties of the two-component melt-spun (TCMS) alloy produced from Ni40Fe40B20 and Ni70Cu10P20 melts. The Ni40Fe40B20, Ni70Cu10P20, Ni55 Fe20 Cu5 P10 B10 alloys were arc-melted. Then the alloys were melt-spun in the two different ways i.e.: by casting from a single-chamber crucible and from the two-chamber crucible. All of the above mentioned alloys were processed in the first way and the Ni40Fe40B20 and Ni70Cu10P20 were simultaneously cast on the copper roller from the two-chamber crucible. The microstructure of the alloy was studied using transmission electron microscopy (TEM), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS) and light microscopy. The mechanical properties were investigated using tensile testing and nanoindentation. The two-component melt-spun (TCMS) amorphous Ni55 Fe20 Cu5 P10 B10 alloy present hardness, tensile strength and Young modulus on the significantly higher level than for a single phase amorphous Ni55 Fe20 Cu5 P10 B10 alloy and slightly below the corresponding values for the Ni40Fe40B20.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 1; 137-140
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
In-Situ Observation of Acicular Ferrite Transformation in High-Strength Low-Alloy Steel Using Confocal Laser Scanning Microscopy
Autorzy:
Lee, Sang-In
Shin, Seung-Hyeok
Park, Hyeonwoo
Kim, Hansoo
Lee, Joonho
Hwang, Byoungchul
Powiązania:
https://bibliotekanauki.pl/articles/2174577.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
acicular ferrite
high-strength low-alloy steel
confocal laser scanning microscopy
CLSM
phase transformation
in-situ observation
Opis:
In-situ observation of the transformation behavior of acicular ferrite in high-strength low-alloy steel using confocal laser scanning microscopy was discussed in terms of nucleation and growth. It is found that acicular ferrite nucleated at dislocations and slip bands in deformed austenite grains introduced by hot deformation in the non-recrystallization austenite region, and then proceeded to grow into an austenite grain boundary. According to an ex-situ EBSD analysis, acicular ferrite had an irregular shape morphology, finer grains with sub-grain boundaries, and higher strain values than those of polygonal ferrite. The fraction of acicular ferrite was affected by the deformation condition and increased with increasing the amount of hot deformation in the non-recrystallization austenite region.
Źródło:
Archives of Metallurgy and Materials; 2022, 67, 4; 1497--1501
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cooling Characteristic and Microstructure of Ni-Si-B-Ag Alloy
Autorzy:
Wojciechowska, M.
Ziewiec, K.
Mucha, D.
Powiązania:
https://bibliotekanauki.pl/articles/356071.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
amorphous/crystalline composite
scanning electron microscopy
X-ray diffraction
thermography
melt spinning
Opis:
The aim of this work was to investigate the possibility of obtaining an amorphous/crystalline composite starting from Ni-SiB-based powder grade 1559-40 and silver powder. The alloy was produced using arc melting of 95% wt. Ni-Si-B-based powder (1559-40) and 5% wt. Ag powder. Ingot was re-melted on a copper plate and observed while cooling using a mid-wave infra-red camera. The alloy was then melt-spun in a helium atmosphere. The microstructure of the ingot as well as the melt-spun ribbon was studied using light microscopy and scanning electron microscopy with energy dispersive spectrometry. Phase identification was performed by means of X-ray diffraction. The observations confirmed an amorphous/crystalline microstructure of the ribbon where the predominant constituent of the microstructure was an amorphous phase enriched with Ni, Si, and B, while the minor constituent was an Ag-rich crystalline phase distributed in a film along the melt-spinning direction.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 3; 1357-1360
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural Transition in SrZnO Laser Pulse Deposited Alloy
Autorzy:
Albrithen, H. A.
Elnaggar, M.
Ozga, K.
Szota, M.
Alahmed, Z. A.
Alanazi, A. Q.
Alshahrani, H.
Alfaifi, E.
Djouadi, M. A.
Labis, J. P.
Powiązania:
https://bibliotekanauki.pl/articles/355190.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
oxide materials
solid state alloys
structural phase transition
X-ray diffraction
scanning electron microscopy
Opis:
We have discovered a structural transition for the SrZnO alloy films from a wurtzite to a rock-salt structure, leading to a reduction in the (112̲0)/(0001) surface energy ratio. The films were grown by pulsed laser deposition using different SrO ratios, x. We have revealed that growth at a higher temperature, 750°C, resulted in a sharp 0002 peak at a low SrO content (5%), whereas growth at a higher SrO content (10%) resulted in a non-crystalline film with minute crystallites with a (112̲0) orientation. Generally the crystallinity decreased as the SrO content increased. No results obtained for the crystalline films showed any orientation of significant peaks besides the peak attributed to the (0001) plane, suggesting epitaxial growth. Optical measurements showed difference in transmission widows of alloys with different SrO percentage, and this was correlated to SrO influence on growth mode as indicated by scanning electron imaging. The studied SrZnO films, with SrO/(SrO + ZnO) ≤ 0.25, were grown by pulsed laser deposition using different SrO ratios, x. The effects of temperature and oxygen pressure during growth on the films’ structural properties were investigated. XRD results indicate that the film crystallinity was improved as the temperature and O2 pressure increased up to 650°C and 0.5 Torr, respectively.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 1; 211-216
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of structural relaxations within the amorphous structure on the magnetic properties of amorphous tapes from FeCoB family
Autorzy:
Szota, M.
Powiązania:
https://bibliotekanauki.pl/articles/354999.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
amorphous materials
free volumes
quasidislocation dipoles
scanning electron microscopy
approach to ferromagnetic saturation
magnetic moments
Opis:
The paper presents the research results for the Fe78Co2Si9B11 amorphous alloy, and after the process of annealing resulting only in the relaxation of the material. The structure relaxations occurring in the volume of test samples lead to the changes in their magnetic and mechanic properties. Therefore the studies on the effect of the structure defects on the properties of these type of materials are important. Understanding the processes occurring during the magnetizing of amorphous alloys can be helpful in the design of modern functional materials for special purposes. The main purpose of this elaboration was to determine the effect of the amorphous structure defects in the state after solidification and after heat treatment on the changes in the magnetizing process and in such parameters as the saturation magnetization and the coercivity field.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 1; 217-222
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Whisker Formation On Galvanic Tin Surface Layer
Tworzenie whiskerów na powierzchniowej warstwie cyny wytworzonej galwanicznie
Autorzy:
Radanyi, A. L.
Sycheva, A.
Gacsi, Z.
Powiązania:
https://bibliotekanauki.pl/articles/356255.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
tin whiskers
galvanic tin layer
mechanical stress
X-ray fluorescence spectrometry
scanning electron microscopy
wiskery cynowe
galwaniczne powłoki cynkowe
naprężenia mechaniczne
rentgenowska spektroskopia fluorescencyjna
mikroskop skaningowy (SEM)
Opis:
The present work reports the effect of substrate composition, thickness of the tin electroplate and its morphology on pressure-induced tin whisker formation. Pure tin deposits of different thickness were obtained on a copper and brass substrates using methane sulfonic industrial bath. The deposits were compressed by a steel bearing ball forming imprint on the surface. The microstructure of tin whiskers obtained at the boundary of each imprint, their length and number were studied using both light and scanning electron microscopy. It was shown that the most intensive formation and growth of whiskers was observed in the first two hours. In general, brass substrate was shown to be more prone to whisker formation than copper independently of the tin coating thickness. The results have been compared with industrial bright tin finish on control unit socket leads and proposals have been made as to modification of the production process in order to minimize the risk of whiskering.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1341-1345
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Failure Strain and Strain-Stress Analysis in Titanium Nitride Coatings Deposited on Religa Heart Ext Ventricular Assist Device
Odkształcenie uszkodzenia i analiza odkształceniowo-naprężeniowa w powłokach azotku tytanu nanoszonych na komorę wspomagania pracy serca Religa Heart Ext
Autorzy:
Kopernik, M.
Powiązania:
https://bibliotekanauki.pl/articles/356873.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
titanium nitride (TiN)
left ventricular assist device
finite element method (FEM)
scanning electron microscopy (SEM)
micro-tensile test
azotek tytanu (TiN)
urządzenie wspomagania lewej komory (VAD)
metoda elementów skończonych
skaningowy mikroskop elektronowy
Opis:
The Polish ventricular assist device is made of Bionate II with deposited TiN biocompatible nano-coating. The two scale finite element model is composed of a macro-model of blood chamber and a micro-model of the TiN/Bionate II. The numerical analysis of stress and strain states confirmed the possibility of fracture. Therefore, the identification of a fracture parameter considered as a failure strain is the purpose of the present work. The tensile test in a micro chamber of the SEM was performed to calibrate the fracture parameter of the material system TiN/Bionate II. The failure strain is a function of a temperature, a thickness of coating and parameters of surface's profile. The failure strain was calculated at the stage of the test, in which the initiation of fracture occurred. The finite element micro-model includes the surface roughness and the failure strain under tension condition for two thicknesses of coatings which will be deposited on the medical device.
Polska komora wspomagania pracy serca jest wykonana z Bionate II z naniesioną biokompatybilną powłoką TiN. Dwu-skalowy model elementów skończonych składa się z modelu makro czaszy krwistej i z modelu mikro dla TiN/Bionate II. Numeryczna analiza stanów naprężeń i odkształceń potwierdza prawdopodobieństwo pękania. Zatem, identyfikacja parametru pękania rozpatrywanego jako odkształcenie uszkodzenia jest celem niniejszej pracy. Próba rozciągania w komorze SEM została przeprowadzona, aby skalibrować parametr pękania dla układu materiałowego TiN/Bionate II. Odkształcenie uszkodzenia jest funkcją temperatury, grubości powłoki i parametrów profilu powierzchni. Odkształcenie uszkodzenia zostało obliczone w tym etapie testu, w którym pojawiła się inicjacja pęknięcia. Mikro model elementów skończonych zawiera chropowatość powierzchni i odkształcenie uszkodzenia w warunkach rozciągania dla dwóch grubości powłok, które będą nanoszone w tym urządzeniu medycznym.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 1; 121-129
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Physicochemical and electrochemical properties of AISI 316L stainless steel used for implants in human urinary system
Ocena własności fizykochemicznych i elektrochemicznych stali AISI 316L stosowanej na implanty w urologii
Autorzy:
Walke, W.
Przondziono, J.
Powiązania:
https://bibliotekanauki.pl/articles/351228.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
AISI 316L stainless steel
electrochemical impedance spectroscopy (EIS)
X-ray photoelectron spectroscopy (XPS)
scanning electron microscopy (SEM)
austenityczna stal nierdzewna AISI 316L
elektrochemiczna spektroskopia impedancyjna EIS
rentgenowska spektroskopia fotoelektronów XPS
skaningowa mikroskopia elektronowa (SEM)
Opis:
The main purpose of this study was to evaluate physicochemical and electrochemical properties of AISI 316L stainless steel with modified surface, used for implants in human urinary system. In order to simulate conditions, which occur in the tissue environment of the urinary system, the test pieces were exposed in a urinary solution at temperature of T=37 ±1ºC, for a period of 30 days. Evaluation of physicochemical properties of biomaterial was made on the basis of surface chemical analysis (XPS). To evaluate the effects which occur on the surface of the examined steel, Electrochemical Impedance Spectroscopy (EIS) method was also employed. Analysis of test results shows favourable influence of the suggested surface treatment of AISI 316L stainless steel. Samples having electrolytically polished and chemically passivated surface featured the best physicochemical and electrochemical characteristics.
Podstawowym kryterium przydatności biomateriału metalowego na implanty urologiczne (stenty urologiczne) jest biokompatybilność. Jest ona w głównej mierze związana z własnościami fizykochemicznymi powierzchni implantu, które powinny być dostosowane do cech środowiska tkanek układu moczowego człowieka. W celu poprawy biokompatybilności stali Cr-Ni-Mo ustalono warunki wytwarzania warstw pasywnych na jej powierzchni. Wytworzenie warstwy pasywnej obejmowało etap polerowania elektrolitycznego i pasywowania. Taki sposób obróbki powierzchniowej zapewnił chropowatość Ra < 0,16 μm wymaganą dla tego rodzaju implantów. W pracy tej szczególną uwagę skoncentrowano na analizie długotrwałego oddziaływania środowiska sztucznego moczu na własności fizykochemiczne wytypowanej stali. Zasadniczym celem pracy była ocena własnosci fizykochemicznych i elektrochemicznych stali AISI 316L o modyfikowanej powierzchni stosowanej na implanty w układzie moczowym człowieka. W celu zasymulowania warunków występujących w środowisku tkankowym układu moczowego próbki poddawano ekspozycji w roztworze sztucznego moczu o temperaturze T=37±1ºC przez okres 30 dni. O przydatności zaproponowanej warstwy pasywnej do uszlachetniania powierzchni stali w znacznym stopniu decyduje jej skład chemiczny. Dlatego w pracy wykonano badania składu chemicznego metodą spektroskopii fotoelektronów (XPS), z użyciem wielofunkcyjnego spektrometru elektronów PHI 5700/660 firmy Physical Electronics, podczas których zidentyfikowano i wyznaczono stężenia atomowe pierwiastków w badanych warstwach pasywnych. Dla próbek przeprowadzono pomiar widma fotoelektronów w szerokim zakresie energii wiązania od 0÷1400 eV oraz dokładne pomiary linii widmowych poszczególnych pierwiastków składowych z warstwy powierzchniowej. Dla oceny zjawisk zachodzacych na powierzchni badanej stali zastosowano również metodę elektrochemicznej spektroskopii impedancyjnej (EIS). Pomiary przeprowadzono z wykorzystaniem systemu pomiarowego AutoLab PGSTAT 302N wyposażonego w moduł FRA2 (Frequency Response Analyser). Badania przeprowadzono w alternatywnym roztworze symulującym środowisko moczu człowieka. Zastosowana w pracy mikroskopia skaningowa pozwoliła na ocene stanu powierzchni stali AISI 316L przed i po ekspozycji w sztucznym moczu. Analiza wyników badań wskazuje na korzystny wpływ zaproponowanej obróbki powierzchniowej stali AISI 316L. Najkorzystniejszą charakterystykę fizykochemiczną i elektrochemiczną miały próbki o powierzchni polerowanej elektrolitycznie i pasywowanej chemicznie. Przeprowadzone w pracy badania stanowią podstawę do dalszych analiz związanych z zagadnieniem biokompatybilności stali Cr-Ni-Mo stosowanej na implanty w urologii.
Źródło:
Archives of Metallurgy and Materials; 2013, 58, 2; 625-630
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł

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