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    Wyświetlanie 1-5 z 5
    Tytuł:
    Effect of Magnet Scrap Size on the Extraction Behavior of Heavy Rare Earth Elements by Liquid Metal Extraction
    Autorzy:
    Nam, Sun-Woo
    Rasheed, Mohammad Zarar
    Park, Sang-Min
    Lee, Sang-Hoon
    Kim, Do-Hyang
    Kim, Taek-Soo
    Powiązania:
    https://bibliotekanauki.pl/articles/355705.pdf
    Data publikacji:
    2020
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    liquid metal extraction
    rare earth elements
    recycling
    oxidation
    magnet scrap
    Opis:
    Liquid metal extraction (LME) process results in 100% neodymium (Nd) extraction but the highest extraction efficiency reportedfor Dysprosium (Dy) so far is 74%. Oxidation of Dy is the major limiting factor for incomplete Dy extraction. In order to enhance the extraction efficiency and to further investigate the limiting factors for incomplete extraction, experiments were carried out on six different particle sizes of under 200 μm, 200-300 μm, 300-700 μm, 700-1000 μm, 1000-2000 μm and over 2000 μm at 900°C with magnesium-to-magnet scrap ratio of 15:1 for 6, 24 and 48 hours, respectively. This research identified Dy2 Fe17 in addition toDy2 O3 phase to be responsible for incomplete extraction. The relationship between Dy2 Fe17 and Dy2O3 phase was investigated, and the overall extraction efficiency of Dy was enhanced to 97%.
    Źródło:
    Archives of Metallurgy and Materials; 2020, 65, 4; 1273-1276
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of Bismuth and Rare Earth Elements on Graphite Structure in Different Section Thicknesses of Spheroidal Graphite Cast Iron Castings
    Autorzy:
    Glavas, Z.
    Strkalj, A.
    Maldini, K.
    Kozina, F.
    Powiązania:
    https://bibliotekanauki.pl/articles/353810.pdf
    Data publikacji:
    2018
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    spheroidal graphite cast iron casting
    graphite structure
    bismuth
    rare earth elements
    microstructure
    Opis:
    Effects of additions of 0.00064, 0.001 and 0.0042 wt.% Bi on the graphite structure in the section thicknesses of 3, 12, 25, 38, 50, 75 and 100 mm of spheroidal graphite cast iron castings containing 2.11 wt.% Si and rare earth (RE) elements (Ce + La + Nd + Pr + Sm + Gd) in the range from 0.00297 to 0.00337 wt.% were analyzed in this paper. Addition of Bi was not necessary for obtaining high nodule count and nodularity higher than 80% in section thicknesses of 3, 12 and 25 mm. RE elements showed a beneficial effect on the nodule count and nodularity in these sections. Nodularity was below 80% in section thicknesses of 38, 50, 75 and 100 mm when Bi was not added. Detrimental effect of RE elements on graphite morphology in these sections was neutralized by adequate addition of Bi. Addition of 0.001 wt.% Bi (ratio of RE/Bi = 3.27) was enough to achieve nodularity above 80% in the section thickness of 38 mm. Nodularity was increased above 80% in section thicknesses of 50, 75 and 100 mm by addition of 0.0042 wt.% Bi (ratio of RE/Bi = 0.78). At the same time, Bi significantly increased the nodule count. Nodularity above 80% and the high nodule count in the section thicknesses of 75 and 100 mm were also achieved by using an external metallic chill in the mold. In this case, addition of Bi was not required.
    Źródło:
    Archives of Metallurgy and Materials; 2018, 63, 3; 1547-1553
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of Rare Earth Cerium Addition on Oxidation Behavior of Co-Al-W Alloys at 800°C
    Autorzy:
    Migas, Damian
    Liptáková, Tatiana
    Moskal, Grzegorz
    Powiązania:
    https://bibliotekanauki.pl/articles/2048827.pdf
    Data publikacji:
    2022
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    rare earth elements
    REE
    cyclic oxidation
    γ-γ′ cobalt-based superalloys
    Co-Ce
    Opis:
    The γ/γ′ Co-based alloys are a new class of cobalt superalloys, which are characterized by remarkable high temperature strength owing to strengthening by γ′-Co3(Al, X) phases. In this investigation, the effect of cerium addition on oxidation behavior of model Co-Al-W alloys was studied. The introduction of Ce aimed at improvement of the oxidation resistance of γ′-forming Co-based superalloys. The minor additions of cerium (0.1, 0.5 at.%) were added to the base alloy Co-9Al-9W. The alloys were prepared via induction vacuum melting (VIM). Further, a primary microstructure of the alloys was analyzed with particular regard to a segregation of Ce. The thermogravimetric analysis (TG) under non-isothermal conditions was used to preliminary estimate the oxidation behavior of alloys at different temperatures. During experiment, differential thermal analysis (DTA) was performed simultaneously. After this test, cyclic oxidation expermients was carried out at 800°C for 500 h. In as-cast state, Ce segregates to interdendritic areas and forms intermetallic phases. The effect connected with melting of interdendritic precipitates was observed at 1160°C. Ce-containing alloys were less prone of oxide spallation. Moreover, oxidation rate of these alloys substantially decreased after 100h of oxidation, whereas mass of the sample corresponding to base alloy continued to increase.
    Źródło:
    Archives of Metallurgy and Materials; 2022, 67, 1; 203-208
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Purification And Separation Of Rare Earth Elements From CCFL With Extraction Chromatography
    Oczyszczanie i separacja metali ziem rzadkich z lamp fluorescencyjnych z zimną katodą (CCFL) przy użyciu chromatografii ekstrakcji
    Autorzy:
    Kim, J. G.
    Powiązania:
    https://bibliotekanauki.pl/articles/352470.pdf
    Data publikacji:
    2015
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    extraction chromatography
    CCFL
    rare earth elements (REE)
    amberite
    recycling
    chromatografia ekstrakcyjna
    pierwiastki ziem rzadkich
    recykling
    Opis:
    In this study, Amberite XAD-7HP was used as the solvent-impregnated resin to separate each REE from the standard solution, which was mixed with the REEs (e.g., La Eu, Tb, Y and Ba). About 100 ppm of each of the REEs was separated from DI water using extraction chromatography. REEs were separated by extraction chromatography using Amberite XAD-7HP resin, the changes in the pH values of the HCl and HClO4 were between 0.2 N and 5 N, and the extraction rate of the solution was between 0.5 and 3 ml/min. The La solution with the separated REEs was leached. The solid-state REEs were annealed between 1083K. The extraction result was analyzed with ICP-AES and an X-ray diffractometer. Each REE was successfully separated with HCl and HClO4 with pH values between 0.1 N and 3 N and with extraction rate between 1.0 m/min and 3.0 m/min.
    Źródło:
    Archives of Metallurgy and Materials; 2015, 60, 2B; 1529-1533
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Recovery Of Electrodic Powder From Spent Nickel-Metal Hydride Batteries (NiMH)
    Odzyskiwanie proszku elektrodowego ze zużytych akumulatorów niklowo-wodorkowych (NiMH)
    Autorzy:
    Shin, S. M.
    Shin, D. J.
    Jung, G. J.
    Kim, Y. H.
    Wang, J. P.
    Powiązania:
    https://bibliotekanauki.pl/articles/356110.pdf
    Data publikacji:
    2015
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    nickel-metal hybride (NiMH)
    electrodic powder
    nickel
    rare earth elements (REE)
    thermal treatment
    akumulator niklowo-wodorkowy
    proszek elektrodowy
    nikiel
    pierwiastki ziem rzadkich
    obróbka termiczna
    Opis:
    This study was focused on recycling process newly proposed to recover electrodic powder enriched in nickel (Ni) and rare earth elements (La and Ce) from spent nickel-metal hydride batteries (NiMH). In addition, this new process was designed to prevent explosion of batteries during thermal treatment under inert atmosphere. Spent nickel metal hydride batteries were heated over range of 300°C to 600°C for 2 hours and each component was completely separated inside reactor after experiment. Electrodic powder was successfully recovered from bulk components containing several pieces of metals through sieving operation. The electrodic powder obtained was examined by X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX) and image of the powder was taken by scanning electron microscopy (SEM). It was finally found that nickel and rare earth elements were mainly recovered to about 45 wt.% and 12 wt.% in electrodic powder, respectively.
    Źródło:
    Archives of Metallurgy and Materials; 2015, 60, 2B; 1139-1143
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-5 z 5

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