Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Centralna Biblioteka Wojskowa Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaCentralna Biblioteka Wojskowa

Wyszukujesz frazę "bismuth" wg kryterium: Temat

  Lista filtrów
Wyrównaj
    Wyświetlanie 1-11 z 11
    Tytuł:
    Effects of Milling Duration on the Thermoelectric Properties of n-Type Bi2Te2.7Se0.3
    Autorzy:
    Park, Min-Soo
    Koo, Hye-Young
    Park, Yonh-Ho
    Ha, Gook-Hyun
    Powiązania:
    https://bibliotekanauki.pl/articles/354698.pdf
    Data publikacji:
    2019
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    thermoelectric
    bismuth telluride
    powder
    milling
    Opis:
    In this study, an oxide reduction process and a reduction-sintering process were employed to synthesize a thermoelectric alloy from three thermoelectric composite oxide powders, and the thermoelectric properties were investigated as a function of the milling duration. Fine grain sizes were analyzed by via X-ray diffraction and scanning electron microscopy, to investigate the influence of the milling duration on the synthesized samples. It was found that microstructural changes, the Seebeck coefficient, and the electrical resistivity of the compounds were highly dependent on the sample milling duration. Additionally, the carrier concentration considerably increased in the samples milled for 6 h; this was attributed to the formation of antisite defects introduced by the accumulated thermal energy. Moreover, the highest value of ZT (=1.05) was achieved at 373K by the 6-h milled samples. The temperature at which the ZT value maximized varied according to the milling duration, which implies that the milling duration of the three thermoelectric composite oxide powders should be carefully optimized for their effective application.
    Źródło:
    Archives of Metallurgy and Materials; 2019, 64, 2; 591-595
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigmen
    Autorzy:
    Kwolek, P.
    Czubajewski, K.
    Wojnicki, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/351844.pdf
    Data publikacji:
    2020
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    recovery
    inorganic pigments
    solubility
    vanadium
    bismuth
    immobilisation
    Opis:
    It has been shown that the precipitation of bismuth orthovanadate from a fly ash leachate is a promising method of vanadium recovery. BiVO4 obtained after appropriate heat treatment can be sold as a pigment. The yield of recovery of solubilised vanadium is equal to 68% and the precipitate is free from nickel impurity. The precipitate is insoluble in the solutions with pH ≥ 3. In more acidic media the solubility of precipitate increases with the decreasing pH. The solubility of the precipitate increases also with the increasing concentration of chloride ions.
    Źródło:
    Archives of Metallurgy and Materials; 2020, 65, 2; 901-909
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Morphology and Structure of the Erbium Stabilized Bismuth Oxide Thin Films Deposited by PLD Technique
    Autorzy:
    Kąc, S.
    Szwachta, G.
    Cieniek, Ł.
    Moskalewicz, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/356362.pdf
    Data publikacji:
    2019
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    Pulsed Laser Deposition
    thin films
    bismuth oxide
    surface topography
    Opis:
    The aim of the work was to obtain thin bismuth oxide films containing, at room temperature, the Bi1,5Er0,5O3 phase. This phase corresponds to the structure of the high-temperature δ-Bi2O3 phase, in pure bismuth oxide, characterized by the highest ionic conductivity of all known solid state ionic conductors. The high-temperature δ-Bi2O3 phase with the face centered cubic structure, in pure bismuth oxide, occurs only at temperature above 730°C. Stabilization of the δ-Bi2O3 phase at room temperature was achieved by an addition of the erbium together with the employ-ment of the Pulsed Laser Deposition (PLD) technique. The influence of an amount of Er alloying and the film thickness on surface morphology, microstructure, phase composition of thin films were investigated. The velocity of deposition of thin layers of bismuth stabilized with erbium in the PLD process using the Nd: YAG laser was about 0.5 nm/s.The investigation results of erbium doped bismuth oxide thin films deposited onto (0001) oriented Al2O3 monocrystalline substrate are presented. Thin films of uniform thickness, without cracks, and porosity were obtained. All deposited thin films (regardless of the film thickness or erbia (Er2O3) content) exhibited a columnar structure. In films stabilized with erbium, up to approx. 250 nm thickness, the columns have a diameter at the base from 25 to 75 nm. The columns densely and tightly fill the entire volume of the films. With increasing of the film thickness increases, porosity also significantly increases. In thin layers containing from 20 to 30 mole % Er2O3 the main identified phase at room temperature is Bi1,5Er0,5O3. It is similar to the defective fluorite-type structure, and belongs to the Fm-3m space group. This phase corresponds to the structure of the high-temperature δ-Bi2O3 phase in pure bismuth oxide.
    Źródło:
    Archives of Metallurgy and Materials; 2019, 64, 3; 969-974
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of Pd-P Layer on the Bonding Strength of Bi-Te Thermoelectric Elements
    Autorzy:
    Bae, Sung Hwa
    Han, Se Hun
    Son, Injoon
    Kim, Kyung Tae
    Powiązania:
    https://bibliotekanauki.pl/articles/353621.pdf
    Data publikacji:
    2019
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    bismuth telluride
    thermoelectric module
    electroless Pd-P plating
    bonding strength
    Opis:
    In this study, the effect of electroless Pd-P plating on the bonding strength of the Bi-Te thermoelectric elements was investigated. The bonding strength was approximately doubled by electroless Pd-P plating. Brittle Sn-Te intermetallic compounds were formed on the bonding interface of the thermoelectric elements without electroless Pd-P plating, and the fracture of the bond originated from these intermetallic compounds. A Pd-Sn solder reaction layer with a thickness of approximately 20 μm was formed under the Pd-P plating layer in the case of the electroless Pd-P plating, and prevented the diffusion of Bi and Te. In addition, the fracture did not occur on the bonding interface but in the thermoelectric elements for the electroless Pd-P plating because the bonding strength of the Pd-Sn reaction layer was higher than the shear strength of the thermoelectric elements.
    Źródło:
    Archives of Metallurgy and Materials; 2019, 64, 3; 963-968
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Reduction of Thermal Conductivity Through Complex Microstructure by Dispersion of Carbon Nanofiber in p-Type Bi0.5Sb1.5Te3 Alloys
    Autorzy:
    Sharief, P.
    Madavali, B.
    Sohn, Y.
    Han, J. H.
    Song, G.
    Hong, S. J.
    Powiązania:
    https://bibliotekanauki.pl/articles/2049341.pdf
    Data publikacji:
    2021
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    bismuth telluride
    carbon nano fiber
    grain size
    Thermal conductivity
    ZT
    Opis:
    The influence of nano dispersion on the thermoelectric properties of Bi2Te3 was actively investigating to wide-spread thermoelectric applications. Herein this report, we have systematically controlled the microstructure of Bi0.5Sb1.5Te3 (BST) alloys through the incorporation of carbon nanofiber (CNF), and studied their effect on thermoelectric properties, and mechanical properties. The BST/x-CNF (x-0, 0.05, 0.1, 0.2 wt.%) composites powder was fabricated using high energy ball milling, and subsequently consolidated the powder using spark plasma sintering. The identification of CNF in bulk composites was analyzed in Raman spectroscopy and corresponding CNF peaks were recognized. The BST matrix grain size was greatly reduced with CNF dispersion and consistently decreased along CNF percentage. The electrical conductivity was reduced and Seebeck coefficient varied in small-scale by embedding CNF. The thermal conductivity was progressively diminished, obtained lattice thermal conductivity was lowest compared to bare sample due to induced phonon scattering at interfaces of secondary phases as well as highly dense fine grain boundaries. The peak ZT of 0.95 achieved for 0.1 wt.% dispersed BST/CNF composites. The Vickers hardness value of 101.8 Hv was obtained for the BST/CNF composites.
    Źródło:
    Archives of Metallurgy and Materials; 2021, 66, 3; 803-808
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Fabrication, structural and AC impedance studies of layer-structured Bi4Ti3O12 ceramics
    Wytwarzanie, struktura oraz badania impedancyjne warstwowej ceramiki Bi4Ti3O12
    Autorzy:
    Bernard, H.
    Lisińska-Czekaj, A.
    Dzik, J.
    Osińska, K.
    Czekaj, D.
    Powiązania:
    https://bibliotekanauki.pl/articles/352884.pdf
    Data publikacji:
    2011
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    tytanian bizmutu
    spektroskopia impedancyjna
    bismuth titanate
    Aurivillius phase
    impedance spectroscopy
    Opis:
    In the present research bismuth titanate Bi4Ti3O12 (BiT) ceramics was synthesized by the standard solid-state reaction method from the mixture of oxides, followed by free sintering at temperature T=1000°C. BiT ceramics was studied in terms of its chemical composition (EDS), crystalline structure (X-ray), microstructure (SEM) and dielectric properties (ac technique of complex impedance spectroscopy) over a range of frequency (f=100Hz to f=1MHz) and temperature (T=200-500°C). Experimental results confirmed the phase formation. It was found that BiT ceramics crystallized in orthorhombic symmetry, best described with Fmmm space group and the following elementary cell parameters: a=5.409(6)°A, b=5.449(2)°A and c=32.816(2)°A. It was also found that BiT ceramics exhibited the plate-like microstructure and stoichiometric chemical composition. Impedance spectroscopy measurements showed contribution of three overlapping relaxation processes (three semicircles in the complex impedance diagrams were observed) ascribed to bulk, grain boundary and electrode/interface polarization phenomena. Impedance data were fitted to the corresponding equivalent circuit using the complex nonlinear least squares (CNLS) method. The ac conductivity for grains, grain boundaries and electrode processes was calculated from CNLS fit of the impedance data and thus the activation energy of ac conductivity (δAC) and relaxation (τ) was calculated for the three revealed components of the impedance spectra from the slopes of δAC and τ versus 1000/T plots (semi log scale) in the range of ΔT=200-500°C.
    W prezentowanej pracy ceramikę tytanianu bizmutu Bi4Ti3O12 (BiT) syntezowano metodą reakcji w fazie stałej z mieszaniny prostych tlenków w T=1000 °C. Zbadano skład chemiczny (EDS), strukturę krystaliczna (X-ray), mikrostrukturę (SEM) oraz właściwosci dielektryczne metodą spektroskopii impedancyjnej w zakresie częstotliwości od f =100Hz do f =1MHz w temperaturze T=200-500°C. Analizując obraz SEM można zauważyc, że płytkopodobne ziarna tworza liczne, rozgałęzione prety. Wyniki eksperymentalne potwierdziły wytworzenie się fazy krystalicznej BiT. Ceramika BiT krystalizuje w symetrii rombowej, opisywana jest grupa przestrzenna Fmmm, charakteryzuje się parametrami komórki: a=5.409(6)°A, b=5.449(2)°A, c=32.816(2)°A. Pomiary spektroskopii impendancyjnej wykazały udział trzech nakładających się procesów relaksacyjnych (zaobserwowano trzy półkola przedstawione w diagramach impedancji) przypisanych wnętrzu ziaren, granicy ziaren oraz zjawisk polaryzacji na granicy powierzchni elektroda/próbka. Dane impedancyjne przybliżono odpowiednimi schematami zastępczymi przy użyciu metody złożonych, nieliniowych, najmniejszych kwadratów (CNLS). Wyznaczono przewodnictwo zmiennoprądowe dla ziaren, granic ziaren i procesów elektrodowych oraz energię aktywacji przewodnictwa Eca i relaksacji Eta w zakresie temperatur ΔT=200–500°C.
    Źródło:
    Archives of Metallurgy and Materials; 2011, 56, 4; 1137-1148
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influence of Spark Plasma Sintering Temperature on Microstructure and Tthermoelectric Properties of Cu-Doped Bi0.5Sb1.495Te3 Compound
    Autorzy:
    Lee, Chul-Hee
    Dharmaiah, Peyala
    Song, Jun-Woo
    Jeong, Kwang-Yong
    Hong, Soon-Jik
    Powiązania:
    https://bibliotekanauki.pl/articles/353226.pdf
    Data publikacji:
    2020
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    bismuth antimony telluride
    gas atomization
    spark plasma sintering
    microstructure
    thermoelectric materials
    Opis:
    Due to air pollution, global warming and energy shortage demands new clean energy conversion technologies. The conversion of industrial waste heat into useful electricity using thermoelectric (TE) technology is a promising method in recent decades. Still, its applications are limited by the low efficiency of TE materials in the operating range between 400-600 K. In this work, we have fabricated Cu0.005 Bi0.5Sb1.495Te3 powder using a single step gas atomization process followed by spark plasma sintering at different temperatures (623, 673, 723, and 773 K), and their thermoelectric properties were investigated. The variation of sintering temperature showed a significant impact on the grain size. The Seebeck coefficient values at room temperature increased significantly from 127 μVK to 151 μV/K with increasing sintering temperature from 623 K to 723 K due to decreased carrier concentration. The maximum ZT values for the four samples were similar in the range between 1.15 to 1.18 at 450 K, which suggest these materials could be used for power generation in the mid-temperature range (400-600 K).
    Źródło:
    Archives of Metallurgy and Materials; 2020, 65, 3; 1105-1110
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of Surfactant Addition on Bi2Te3 Nanostructures Synthesized by Hydrothermal Method
    Autorzy:
    Dharmaiah, P.
    Lee, C. H.
    Madavali, B.
    Hong, S.-J.
    Powiązania:
    https://bibliotekanauki.pl/articles/351609.pdf
    Data publikacji:
    2017
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    bismuth telluride
    hydrothermal synthesis
    spark plasma sintering
    thermoelectric materials
    X-ray diffraction
    Opis:
    In the present work, we have prepared Bi2Te3 nanostructures with different morphologies such as nano-spherical, nanoplates and nanoflakes obtained using various surfactant additions (EG, PVP, and EDTA) by a hydrothermal method. The shape of the nanoparticles can be controlled by addition of surfactants. The samples were characterized by x-ray diffraction (XRD) and scanning electron microscopy (SEM). It is found that the minority BiOCl phase disappears after maintained pH at 10 with EG as surfactant. SEM bulk microstructure reveals that the sample consists of fine and coarse grains. Temperature dependence of thermoelectric properties of the nanostructured bulk sample was investigated in the range of 300-450K. The presence of nanograins in the bulk sample exhibits a reduction of thermal conductivity and less effect on electrical conductivity. As a result, a figure of merit of the sintered bulk sample reached 0.2 at 400 K. A maximum micro Vickers hardness of 102 Hv was obtained for the nanostructured sample, which was higher than the other reported results.
    Źródło:
    Archives of Metallurgy and Materials; 2017, 62, 2B; 1005-1010
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of Bismuth and Rare Earth Elements on Graphite Structure in Different Section Thicknesses of Spheroidal Graphite Cast Iron Castings
    Autorzy:
    Glavas, Z.
    Strkalj, A.
    Maldini, K.
    Kozina, F.
    Powiązania:
    https://bibliotekanauki.pl/articles/353810.pdf
    Data publikacji:
    2018
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    spheroidal graphite cast iron casting
    graphite structure
    bismuth
    rare earth elements
    microstructure
    Opis:
    Effects of additions of 0.00064, 0.001 and 0.0042 wt.% Bi on the graphite structure in the section thicknesses of 3, 12, 25, 38, 50, 75 and 100 mm of spheroidal graphite cast iron castings containing 2.11 wt.% Si and rare earth (RE) elements (Ce + La + Nd + Pr + Sm + Gd) in the range from 0.00297 to 0.00337 wt.% were analyzed in this paper. Addition of Bi was not necessary for obtaining high nodule count and nodularity higher than 80% in section thicknesses of 3, 12 and 25 mm. RE elements showed a beneficial effect on the nodule count and nodularity in these sections. Nodularity was below 80% in section thicknesses of 38, 50, 75 and 100 mm when Bi was not added. Detrimental effect of RE elements on graphite morphology in these sections was neutralized by adequate addition of Bi. Addition of 0.001 wt.% Bi (ratio of RE/Bi = 3.27) was enough to achieve nodularity above 80% in the section thickness of 38 mm. Nodularity was increased above 80% in section thicknesses of 50, 75 and 100 mm by addition of 0.0042 wt.% Bi (ratio of RE/Bi = 0.78). At the same time, Bi significantly increased the nodule count. Nodularity above 80% and the high nodule count in the section thicknesses of 75 and 100 mm were also achieved by using an external metallic chill in the mold. In this case, addition of Bi was not required.
    Źródło:
    Archives of Metallurgy and Materials; 2018, 63, 3; 1547-1553
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Studies of temperature and fabrication methods influence on structure and microstructure of BiNbO4 microwave electroceramics
    Badania wpływu temperatury i procesu wytwarzania na strukturę oraz mikrostrukturę mikrofalowej ceramiki BiNbO4
    Autorzy:
    Płońska, M.
    Czekaj, D.
    Powiązania:
    https://bibliotekanauki.pl/articles/352991.pdf
    Data publikacji:
    2011
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    niobian bizmutu
    struktura szelito-podobna
    ceramika
    bismuth niobate
    scheelite-like structure
    microwave ceramics
    Opis:
    The bismuth-based ceramics are well known as potential materials for microwave or microelectronics applications. One of them is a bismuth niobate (BiNbO4), which belongs to the family of the scheelite-like stibiotantalite structure A3+B5+O4. This low temperature co-fired dielectric ceramics is also reported as a good microwave dielectric material, using i.e. in multilayer microwaves systems. In the present studies depends of fabrication methods and temperature conditions on basic properties of bulk BiNbO4 are reported. Technological process included two stages. First, the ceramic powder was obtained from the high purity oxides (99.99%), by MOM method. The second stage involved consolidation of such prepared powders by free sintering and the hot uniaxial pressing methods. Goal of this study was to investigate how the fabrication processes i.e. temperature and sintering conditions influence on prepared powders and samples of bismuth niobate, like its structure and microstructure.
    Ceramika na bazie bizmutu znana jest jako potencjalny materiał do zastosowan w technice mikrofalowej oraz mikroelektronice. Jednym z jej przedstawicieli jest niobian bizmutu (BiNbO4), który należy do rodziny związków o strukturze szelito podobnej, tantalanu antymonu A3+B5+O4. Ceramika dielektryczna tego typu, wypalana niskotemperaturowo, przedstawiana jest również jako materiał o dobrych właściwościach mikrofalowych, wykorzystywany np.: w wielowarstwowych układach mikrofalowych. W przedstawionej pracy omówiono wpływ stosowanych metod wytwarzania oraz ich warunków temperaturowych, na podstawowe właściwości ceramiki BiNbO4. Proces technologiczny składał sie z dwóch etapów. W pierwszym z nich, technika MOM otrzymano proszki ceramiczne z wysokiej czystości tlenków (99.99%). Drugi etap obejmował zagęszczanie przygotowanych proszków za pomocą metod spiekania swobodnego i jednoosiowego prasowania na gorąco. Celem pracy było zbadanie wpływu procesu wytwarzania, tzn. temperatury i metod spiekania na otrzymane proszki oraz próbki ceramiczne BiNbO4, na ich strukturę oraz mikrostrukturę.
    Źródło:
    Archives of Metallurgy and Materials; 2011, 56, 4; 1169-1175
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Activity of zinc in the liquid Bi-In-Sn-Zn alloys determined by Knudsen method
    Pomiary aktywności cynku w ciekłych stopach Bi-In-Sn-Zn metoda efuzyjna Knudsena
    Autorzy:
    Zajączkowski, A.
    Gąsior, W.
    Onderka, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/356445.pdf
    Data publikacji:
    2012
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    metoda Knudsena
    aktywność cynku
    cynk
    quaternary system
    activity of zinc
    indium
    tin
    bismuth
    zinc
    vapour pressure
    effusion method
    Opis:
    The Knudsen effusion method was used for measurements of mass loss rate of liquid Bi-In-Sn-Zn alloys, in the temperature range from 572 to 768 K. The studies were carried out for the alloys with the ratio of Bi:In:Sn equal 2:6:2, 2:2:6 and 8:1:1. The obtained results were used for the calculation of zinc vapour pressure over liquid Bi-In-Sn-Zn alloys and next the activity of zinc in the Bi-In-Sn-Zn liquid phase. It was found that for the investigated alloys the activity of zinc shows the considerable positive deviation from the Raoult's law.
    Stosując efuzyjna metodę Knudsena pomierzono szybkość ubytku masy cynku z ciekłych stopów Bi-In-Sn-Zn, w zakresie temperatur od 572 do 768 K. Badania zostały przeprowadzone dla stopów o stosunku zawartości molowych Bi:In:Sn równym 2:6:2, 2:2:6 oraz 8:1:1. Wyniki badań zostały wykorzystane do obliczenia równowagowej prężności par cynku nad ciekłymi stopami Bi-In-Sn-Zn, a następnie aktywności cynku. Stwierdzono, że dla zbadanych stopów aktywność cynku wykazuje znaczne dodatnie odstępstwa od prawa Raulta.
    Źródło:
    Archives of Metallurgy and Materials; 2012, 57, 3; 838-843
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-11 z 11

      Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies