- Tytuł:
- The Role of CeO₂-Doping of γ-Al₂O₃ on its Structural and Superficial Area
- Autorzy:
-
Aribi, K.
Ghelamallah, M.
Bellifa, A.
Bousehaba, F. - Powiązania:
- https://bibliotekanauki.pl/articles/1030118.pdf
- Data publikacji:
- 2017-09
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
γ-Al₂O₃
CeO₂
surface
structure
reducibility - Opis:
- A series of samples, noted Al_xCe_{1-x} has been prepared by hydrolysis, from γ-Al₂O₃ and CeO₂. These samples were calcined under air at 450, 900 and 1200°C, and then characterized by specific surface area, X-ray diffraction and thermoreduction programmed under H₂. Obtained results show that after calcination at 450 and 900°C, the cerium decreases the surface of alumina. Results of X-ray diffraction and thermoreduction programmed under H₂ experiments showed that the samples are constituted of: γ-Al₂O₃ and CeO₂. The global consumption of hydrogen increase with rate of CeO₂ added. At 1200°C, the sintering of the samples is very important and γ-Al₂O₃ is transformed into the α-phase. The decrease in specific surface area is more accentuated for Al₁Ce₀ sample, since sintering occurs due to the growth in crystallite size. Thermoreduction programmed under H₂ experiments show that reduction of CeO₂ much more accentuated for ceria samples or its decrease can reflect some alterations of the nature of interactions between Al₂O₃ and CeO₂.
- Źródło:
-
Acta Physica Polonica A; 2017, 132, 3; 445-447
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł