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    Wyświetlanie 1-3 z 3
    Tytuł:
    Anodic oxide films on niobium and tantalum in different aqueous electrolytes and their impedance characteristics
    Autorzy:
    Verma, N.
    Singh, K.
    Marí, B.
    Mollar, M.
    Jindal, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/1075354.pdf
    Data publikacji:
    2016-03
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    68.37.Hk
    68.55.J-
    68.60.Bs
    Opis:
    The anodic oxide films were prepared on the niobium and tantalum in aqueous electrolyte mixtures containing 1 M CH₃COOH + 1 M H₃PO₄ or 1 M CH₃COOH + 1 vol.% HF or 1 M CH₃COOH + 1 M H₃PO₄ + 1 vol.% HF at 30 V for 30 min. The barrier films were obtained on both niobium and tantalum surfaces in all electrolyte mixtures except niobium oxide film formed in 1 M CH₃COOH + 1 vol.% HF which is porous in nature. The anodic oxide films were characterized by FESEM. Also, electrochemical impedance spectroscopy at open-circuit potential on Nb and Ta was applied and obtained data were analyzed by fitting with four different equivalent circuits.
    Źródło:
    Acta Physica Polonica A; 2016, 129, 3; 297-303
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Luminescence Properties of CaAl₂O₄:Eu³⁺, Gd³⁺ Phosphors Synthesized by Combustion Synthesis Method
    Autorzy:
    Verma, N.
    Singh, K.
    Marí, B.
    Mollar, M.
    Jindal, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/1030093.pdf
    Data publikacji:
    2017-10
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    phosphors
    luminescence
    combustion method
    calcium aluminate
    Opis:
    CaAl₂O₄:Eu³⁺ (1 mol.%) co-doped with varying concentration of Gd³⁺ (1, 2, 5, and 10 mol.%) were prepared by combustion synthesis method at 600°C and further annealed at 1000°C. All the compositions were investigated for their structural and photoluminescence properties. It was observed that both states of europium i.e. Eu³⁺ and Eu²⁺ were present and ratio of these states changes on heating at 1000°C. The materials synthesized at 600°C showed high intense peak around 440 nm due to presence of Eu²⁺ and less intense peaks in the red region which were due to presence of Eu³⁺. On annealing the compounds at 1000°C, intensity of peak around 440 nm decreases and intensity of peaks in the red region increases significantly. The ⁵D₀ → ⁷F₃ transition due to Eu³⁺ at 657 nm appears as the highest intensity peak. All co-doped samples annealed at 1000°C showed the higher intensity than the mono doped sample which is due to energy transfer from the Gd³⁺ to Eu³⁺. The second rare-earth ion (Gd³⁺) acts as sensitizer and enhances the photoluminescence intensity. The X-ray diffraction spectra reveal the monoclinic phase of CaAl₂O₄ in all the samples which showed that Eu³⁺ and Gd³⁺ do not change the crystalline structure of calcium aluminate.
    Źródło:
    Acta Physica Polonica A; 2017, 132, 4; 1261-1264
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of van Hove Singularity on T$\text{}_{c}$ in Rb doped C$\text{}_{60}$
    Autorzy:
    Agrawal, B. K.
    Agrawal, S.
    Yadav, P. S.
    Srivastava, P.
    Srivastava, R.
    Singh, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/2035748.pdf
    Data publikacji:
    2003-05
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    74.25.Jb
    74.62.Fj
    74.70.Wz
    Opis:
    In the present study we investigate the role of van Hove singularity on the optimization of T$\text{}_{c}$ in Rb doped fullerenes C$\text{}_{60}$ Rb$\text{}_{3}$. A first principles self-consistent full potential linear muffin-tin orbital method using density functional theory in local density approximation was employed. The doped Rb atoms are of two types occupying the tetrahedral and interstitial positions in the fcc lattice. The added Rb atoms fill the t$\text{}_{1u}$ band of the undoped fullerenes C$\text{}_{60}$ up to half which makes C$\text{}_{60}$Rb$\text{}_{3}$ conducting. Saddle points leading to van Hove singularities are observed in the neighbourhood of the symmetry point L. The shifting of the van Hove singularity with the volume of the lattice is investigated. We observe a saddle point just at the Fermi level for a lattice constant of 14.435Å. The highest value of T$\text{}_{c}$ should thus be observed at the above lattice constant. This result is in excellent agreement with the observed high value of T$\text{}_{c}$ measured in C$\text{}_{60}$Rb$\text{}_{3}$ for a lattice constant of 14.435Å.
    Źródło:
    Acta Physica Polonica A; 2003, 103, 5; 477-482
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-3 z 3

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