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Wyświetlanie 1-7 z 7
Tytuł:
Langmuir Monolayer Characteristics of Erucylphosphocholine - A Novel Anti-Tumor Drug
Autorzy:
Wnętrzak, A.
Łątka, K.
Marzec, M.
Dynarowicz-Łątka, P.
Powiązania:
https://bibliotekanauki.pl/articles/1490116.pdf
Data publikacji:
2012-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.18.-g
Opis:
Erucylphosphocholine, an alkylphosphocholine anticancer drug, was employed for Langmuir monolayer characterization and liquid crystalline studies. Differential scanning calorimetry measurements together with texture observation with polarizing microscope revealed the presence of nematic phase. Film forming properties of erucylphosphocholine at the air/water interface were thoroughly investigated by means of surface pressure-area (π-A) and electric surface potential-area (Δ V-A) isotherms. The influence of such factors as subphase temperature, ionic strength, speed of compression, number of molecules spread at the surface on the characteristics of the π-A isotherms was investigated. Erucylphosphocholine was found to form very stable Langmuir monolayers, which are almost not influenced by experimental conditions. The liquid character of its monolayers was confirmed with both compressibility modulus values and homogeneous Brewster angle microscopy images.
Źródło:
Acta Physica Polonica A; 2012, 121, 2; 468-473
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ferroelectric Liquid Crystal for Use in a New Generation of LCDs
Autorzy:
Fitas, J.
Marzec, M.
Tykarska, M.
Wróbel, S.
Dąbrowski, R.
Powiązania:
https://bibliotekanauki.pl/articles/1399018.pdf
Data publikacji:
2013-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
77.84.Nh
64.70.M-
Opis:
The key to improvements in liquid crystalline displays lies in the continuous synthesis and studies of new kinds of liquid crystalline substances. Among them, ferroelectric compounds are the subject of much attention, due to the potential progresses in switching time, colour depth, and other qualities of liquid crystal displays. In this paper we describe the research of the physical properties of 4-(2-methylbutoxy)phenyl 4-(octyloxy)-benzoate for purposes of its potential application in liquid crystal displays.
Źródło:
Acta Physica Polonica A; 2013, 124, 6; 954-958
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dielectric and Conductivity Anisotropy in Liquid Crystalline Phases of Strongly Polar Thioesters
Autorzy:
Mikułko, A.
Fraś, M.
Marzec, M.
Wróbel, S.
Ossowska-Chruściel, M.
Chruściel, J.
Powiązania:
https://bibliotekanauki.pl/articles/1813171.pdf
Data publikacji:
2008-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.30.-v
61.30.Eb
77.22.-d
66.10.Ed
Opis:
The main objective of this paper is to study dielectric properties of two compounds of acronyms 5OSCl and 6OSCl having strongly polar bond (C-Cl) at para position. Dielectric measurements were done in the frequency range from 40 Hz to 15 MHz. The dielectric spectra were measured for two principal alignments. For homeotropic alignment, the reorientation of molecule around the short molecular axis was observed. Both substances studied exhibit large positive dielectric anisotropy and the anisotropy of conductivity was obtained in smectic A as well as nematic phase.
Źródło:
Acta Physica Polonica A; 2008, 113, 4; 1155-1160
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies of New Antiferroelectric Liquid Crystal Based on Quantum-Chemical Model
Autorzy:
Tomczyk, W.
Marzec, M.
Juszyńska, E.
Dąbrowski, R.
Ziobro, D.
Wróbel, S.
Massalska-Arodź, M.
Powiązania:
https://bibliotekanauki.pl/articles/1399016.pdf
Data publikacji:
2013-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
77.84.Nh
64.70.M-
Opis:
Physical properties of new thermotropic antiferroelectric liquid crystal have been studied. Experiments were done by use of complementary methods such as differential scanning calorimetry, polarizing optical microscopy and X-ray powder diffractometry. Acquired data from X-ray powder diffractometry was examined under application of quantum chemical approach. It has been found that compound studied exhibits stable enantiotropic antiferroelectric SmC_{A}* phase in the wide temperature range while ferroelectric phase SmC* is very narrow.
Źródło:
Acta Physica Polonica A; 2013, 124, 6; 949-953
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rehydration of CTMA Modified DNA Powders Observed by NMR
Autorzy:
Harańczyk, H.
Kobierski, J.
Zalitacz, D.
Nowak, P.
Romanowicz, A.
Marzec, M.
Nizioł, J.
Hebda, E.
Pielichowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/1490149.pdf
Data publikacji:
2012-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.56.Na
Opis:
The rehydration of salmon sperm deoxyribonucleic acid (DNA) and cetyltrimethylammonium chloride $(C_{19}H_{42}ClN)$ complexes was observed using hydration kinetics, sorption isotherm, and high power proton relaxometry (at 30 MHz). The hydration kinetics shows (i) a very tightly bound water not removed by incubation over silica gel ($A_0^{h}$ = 0.061 ± 0.004), (ii) a tightly bound water saturating at $A_1^{h}$ = 0.039 ± 0.011, with the hydration time $t_1^{h}$ = (1.04 ± 0.21) h, a loosely bound water fraction (iii) with the hydration time $t_2^{h}$ = (19.1 ± 3.2) h and the contribution progressively increasing with the air humidity. For the hydration at $p//p_0$ = 100%, after $t_0$ = (152.6 ± 2.5) h of incubation the swelling process begins. The swelling time was $t_3^{h}$ = (12.5 ± 5.4) h, and the swelling amplitude $A_3^{h}$ = 0.140 ± 0.016. The sorption isotherm is sigmoidal in form and is fitted by the Dent model with the mass of water saturating primary binding sites Δ M/$m_0$ = 0.102 ± 0.021. Proton free induction decay is a superposition of the immobilized proton signal (Gaussian, with $T_{2S}$* ≈ 30 μs) and two liquid signal components coming from tightly bound ($T_{2 L_1}$* ≈ 100 μs) and loosely bound water fraction with the amplitude proportional to the mass of water added ($T_{2 L_2}$* ≈ 1000 μs).
Źródło:
Acta Physica Polonica A; 2012, 121, 2; 485-490
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dielectric and Electrooptic Investigations of B Phases οf Banana-Shaped Thioesters
Autorzy:
Wierzejska-Adamowicz, M.
Ossowska-Chruściel, D.
Chruściel, J.
Douali, R.
Legrand, Ch.
Marzec, M.
Mikułko, A.
Sikorska, A.
Wróbel, S.
Powiązania:
https://bibliotekanauki.pl/articles/1538244.pdf
Data publikacji:
2010-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
77.84.Nh
77.84.-s
78.20.Jq
Opis:
Electrooptic and dielectric measurements were done for B phases of two banana-shaped homologues 1,3-phenylene bis{4-[(4-nonylo-xy-benzoyl)sulfanyl]benzoate (9OSOR) and 1,3-phenylene bis{4-[(4-dodecylo-xy-benzoyl)sulfanyl]benzoate (12OSOR). Polarizing microscopy allowed to identify $B_{1}$ phase for 9OSOR and $B_{2}$ phase for 12OSOR on the basis of texture observation. Spontaneous polarization measurements were performed using reversal current method. The current response to applied triangular voltage shows that $B_{1}$ phase is a ferroelectric and $B_{2}$ phase - antiferroelectric one for which two well separated peaks were observed. Polarization for phase $B_{1}$ of 9OSOR is rather small and its temperature dependence is unusual for ferroelectric liquid crystals - it increases with temperature. Spontaneous polarization for $B_{2}$ phase of 12OSOR compound is of about 600 nC/$cm^{2}$. Dielectric spectra measured with bias field for $B_{2}$ phase of 12OSOR show two well separated relaxation processes. In the low frequency range the relaxation process is connected with fluctuations of ferroelectric domains. The relaxation process in the high frequency range appearing also without bias field is connected with molecular reorientation. The dielectric spectra measured for $B_{1}$ phase of 9OSOR with and without bias voltage showed only one dielectric relaxation process connected with molecular reorientation around the short axis.
Źródło:
Acta Physica Polonica A; 2010, 117, 4; 557-561
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Polymorphism of Chiral Thioester Studied by Dielectric Spectroscopy
Autorzy:
Wawrzyniak, A.
Chruściel, J.
Douali, R.
Dubois, F.
Leblond, J.
Legrand, Ch.
Ossowska-Chruściel, D.
Marzec, M.
Ropa, P.
Czerwiec, J.
Wróbel, S.
Powiązania:
https://bibliotekanauki.pl/articles/1399012.pdf
Data publikacji:
2013-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
77.84.Nh
64.70.M-
77.22.Gm
77.22.Ej
Opis:
(S)-(+)-4'-[(4-(1-methylheptyloxycarbonylphenyl) thiocarbonylphenyl]-decyloxybenzoate (in short 10.OPOSMH) was studied by complementary methods. The substance shows rich polymorphism. In addition to ferroelectric and antiferroelectric smectic C* phases it possesses three ferrielectric sub-phases. Phase transitions between the phases were revealed by differential scanning calorimetry and static dielectric permittivity measurements. The aim of this paper was to study phase transitions and differences in dielectric spectra shown by different phases. Collective and molecular dynamics of all phases shown by 10.OPOSMH will be discussed in terms of theoretical models. Dielectric spectra of antiferroelectric phase show two characteristic dielectric relaxation modes: one connected with the molecular process (reorientation around the short axis) and the other originating from fluctuations of antiferroelectric order parameters.
Źródło:
Acta Physica Polonica A; 2013, 124, 6; 933-936
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-7 z 7

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