- Tytuł:
- Electronic States of Collosal Magnetoresistive Manganites $La_{0.67}Pb_{0.33}Mn_{1-x}Fe_{x}O_{3}$ from Photoemission Spectroscopy
- Autorzy:
-
Kowalik, M.
Zalecki, R.
Kołodziejczyk, A. - Powiązania:
- https://bibliotekanauki.pl/articles/1538821.pdf
- Data publikacji:
- 2010-02
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
71.20.Lp
79.60.Bm
71.15.Ap
74.20.Mn - Opis:
- The electron photoemission spectra of valence bands and core-level states of manganese perovskite $La_{0.67}Pb_{0.33}(Mn_{1-x}Fe_{x})O_{3}$ with x = 0, 0.01, 0.03, 0.06, 0.10 and 0.15 were measured by the X-ray and Ultraviolet Photoemission Spectroscopy (XPS and UPS) below and above the metal-insulator transition. From analysis of the Mn 2p core-level spectra the ratio $Mn^{3+}//Mn^{4+}$ was calculated as a function of the iron content. Comparison of the valence band spectrum with band structure calculations and with the high-resolution spectra measured at synchrotron radiation for Ca-, Ba- and Ce- substituted manganites revealed the strong hybridisation of Mn 3d and of O 2p states between -3 eV and -7 eV, and no estimated oxygen states between 0 eV and -2 eV where the Mn-3d states play a predominant role. The composition dependent insulating energy gaps were measured at room temperature. Reasons for the behaviour were discussed taking into account previous analysis of XPS/UPS spectra of other manganese perovskites.
- Źródło:
-
Acta Physica Polonica A; 2010, 117, 2; 277-280
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł