- Tytuł:
- Photoemission Electronic States of Thallium- and Bismuth-Based Superconductors
- Autorzy:
-
Zalecki, R.
Kołodziejczyk, A.
König, J. W.
Gritzner, G. - Powiązania:
- https://bibliotekanauki.pl/articles/2014372.pdf
- Data publikacji:
- 2000-11
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
74.72.-h
79.60.-i - Opis:
- X-ray photoemission spectra the core-levels as well as the X-ray photoemission spectra and ultraviolet photoemission spectra from the valence bands of the (Tl$\text{}_{0.6}$Pb$\text{}_{0.5}$)(Sr$\text{}_{0.9}$Ba$\text{}_{0.1}$) Ca$\text{}_{2}$Cu$\text{}_{3}$O$\text{}_{y}$ and (Bi$\text{}_{1.75}$Pb$\text{}_{0.35}$)Sr$\text{}_{1.9}$Ca$\text{}_{2.05}$Cu$\text{}_{3.05}$O$\text{}_{y}$ superconductors were measured and analyzed. Special attention was paid to the valence band X-ray photoemission spectra and ultraviolet photoemission spectra, the Cu 2p core-level X-ray photoemission spectra and the Cu L$\text{}_{2,3}$-M$\text{}_{4,5}$M$\text{}_{4,5}$ and O K-L$\text{}_{2,3}$L$\text{}_{2,3}$ Auger spectra. Both Cu 2p$\text{}_{3}\text{}_{/}\text{}_{2}$ and Cu 2p$\text{}_{1}\text{}_{/}\text{}_{2}$ core-level lines consisted of two spin-orbit split main lines accompanied with the two satellite lines. The charge transfer energy Δ from the oxygen ligand to the copper 3d$\text{}^{9}$ states and the hopping integral t were estimated from the energy separation between the main line and the satellite line taking advantage of the local cluster model calculations and their extension to high-temperature superconductors. The Coulomb correlation on-site energy U$\text{}_{dd}$ of two electrons in the same copper orbital and U$\text{}_{pp}$ of two electrons in the oxygen orbital as well as the correlation energy U$\text{}_{cd}$ of the 2p core hole - 3d electron interaction have been estimated from the Auger electron spectra and the valence band spectra. They are: U$\text{}_{dd}$=6.0±0.5eV, of U$\text{}_{pp}$≅ 10±1eV and of U$\text{}_{cd}$≅ 8.0±0.5eV nearly the same for both the Tl- and Bi-compounds. We conclude that these compounds are the charge transfer strongly-correlated metals.
- Źródło:
-
Acta Physica Polonica A; 2000, 98, 5; 513-524
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł