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Tytuł:
Dynamic expression profile of DNA methyltransferases in rat testis development
Autorzy:
Xu, H.X.
Qin, J.Z.
Zhang, K.Y.
Zeng, W.X.
Powiązania:
https://bibliotekanauki.pl/articles/31635.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Opis:
DNA methyltransferases (Dnmts) are unique and perform specific functions during male germ cell development. To further characterize the significance of Dnmts in the events leading to production of spermatozoa, we investigated whether the expression patterns in Dnmt1, Dnmt3a, Dnmt3b and Dnmt3l were apparent in rat testes at different time points during development. The qRT-PCR results showed that expression levels of Dnmt3a and Dnmt3l were abundant before birth and were present at the highest levels in testes tissue at 18.5 days postcoitus (dpc), and gradually decreased from day 0 postpartum (dpp) to 90 dpp. Expression of Dnmt1 and Dnmt3b reached a peak after birth (P <0.01), and then gradually reduced until adulthood. Western blotting and immunolocalization analysis of Dnmt3a and Dnmt3b further confirmed the differential expression and localization of the two proteins during rat testis development. The dynamic expression profile of Dnmts implies specific and potentially nonredundant roles for each of these enzymes in the developing rat testis.
Źródło:
Polish Journal of Veterinary Sciences; 2015, 18, 3
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Combustion Characteristics and Mechanism of Boron-based, Fuel-rich Propellants with Agglomerated Boron Powder
Autorzy:
Xu, H. -X.
Pang, W.-Q.
Guo, H.-W.
Zhao, F.-Q.
Wang, Y.
Sun, Z.-H.
Powiązania:
https://bibliotekanauki.pl/articles/358733.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
analytical chemistry
boron-based fuel-rich solid propellants
agglomerated boron powder
combustion performance
combustion mechanism
Opis:
In order to extend the burning rate of boron-based, fuel-rich solid propellants with agglomerated boron powder, the effects of the boron content, the AP content, and of the magnesium powder content, on the burning rate and pressure exponent have been studied systematically. It has been shown that when the AP content is constant, the burning rate of the propellants increases with an increase in the agglomerated boron content. Furthermore, the burning rate and pressure exponent increase with increasing the contents of AP and magnesium powder. By means of single colour frame amplification photography and combustion wave tests, the combustion mechanism of these propellants has been investigated. It has been shown that the flame of the propellants becomes brighter by increasing the AP content, the dT/dxcp and dT/dxgp of the propellant FR-5 being around 6815 and 5789 °C/mm respectively, higher than those of FR-4, resulting in greater burning rates. The Ts of these propellants is above 683 °C, which is higher than the decomposition peak temperatures of agglomerated boron powder and of propellants (about 649 °C), which indicates that agglomerated boron powder is partially oxidized on the combustion surface, and the heat released from it may be beneficial to the combustion of the propellants.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 4; 575-587
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of a High Energy Combustion Agent (BHN) and Its Effects on the Combustion Properties of Fuel Rich Solid Rocket Propellants
Autorzy:
Pang, W.-Q.
Zhao, F.-Q.
Xue, Y.-N.
Xu, H.-X.
Fan, X.-Z.
Xie, W.-X.
Zhang, W.
Lv, J.
Deluca, L. T.
Powiązania:
https://bibliotekanauki.pl/articles/358474.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
fuel rich solid propellant
BHN
DSC
TG-DTG
burning rate
combustion properties
Opis:
A high energy combustion agent (tetraethylammonium decahydrodecaborate, BHN) was prepared by means of an ion exchange reaction (IER), and the prepared samples were characterized by the advanced diagnostic techniques of Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), Thermogravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC) etc. The effects of BHN particles on the hazard and combustion properties of fuel rich solid propellants were investigated. The results showed that the BHN samples and fuel rich propellants containing BHN particles can be prepared successfully and solidified safely. The peak temperature of thermal decomposition and the heat of decomposition of the BHN samples prepared were 305.8 °C and 210.9 J•g-1 at a heating rate of 10 K•min-1, respectively. The burning rate and pressure exponent of fuel rich solid propellants decreases with increases in the fraction of BHN particles in the propellant formulation. Compared with the reference formulation (sample BP-1), the burning rate of the propellant with 10% mass fraction of BHN particles (sample BP-4) had decreased 30% at 3.0 MPa, and the pressure exponent had dropped from 0.44 to 0.41.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 3; 537-552
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Intervalley Transfer of Electrons in ZnS-Type Thin Film Electroluminescent Devices
Autorzy:
Zhao, H.
Wang, Y.
Xu, Z.
Xu, X.
Powiązania:
https://bibliotekanauki.pl/articles/2011094.pdf
Data publikacji:
1999-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
72.20.-i
78.60.-b
Opis:
Based on the calculation about intervalley scattering rates in ZnS, the intervalley transfer process in ZnS-type thin film electroluminescent devices is investigated through the Monte Carlo simulation. The transient time of intervalley transfer is about 0.2-0.3 ps, it coincides with that of electron average energy. Intervalley distribution shifts to high valleys as the electric field increased. The electron kinetic energy distributions in different valleys are also gained. We propose that high valleys could store energies, which could prolong the decay of the electron average energy as the field was removed. These results could be used as the basic data on the study of electroluminescent process and the citation of valley parameters in analytic models should be carefully considered.
Źródło:
Acta Physica Polonica A; 1999, 96, 3-4; 475-482
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analytical Band Model in Monte Carlo Simulation of Electric Transport in ZnS Thin Film Electroluminescent Devices
Autorzy:
Zhao, H.
Wang, Y.
Xu, X.
Powiązania:
https://bibliotekanauki.pl/articles/2014087.pdf
Data publikacji:
2000-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.60.-b
72.20.-i
Opis:
In this paper, an analytical band model is introduced in Monte Carlo simulation of electric transport process in thin film electroluminescent devices. The band structure of ZnS calculated from the empirical pseudopotential method is fitted by using polynomials. The density of states and scattering rates are also calculated from these polynomials. Based on these results, the electric transport process in ZnS-type thin film electroluminescent devices is simulated through the Monte Carlo method. By comparison with others, this model is as fast as the nonparabolic model and as accurate as the full band model. Furthermore, the influence of the band model on the simulation results is also investigated. We show that the dispersion relation and density of states are all important in the simulation.
Źródło:
Acta Physica Polonica A; 2000, 98, 1-2; 123-130
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A reliability analysis method of cloud theory – Monte Carlo based on performance degradation data
Oparta na teorii chmury i modelu Monte Carlo metoda analizy niezawodnościowej danych o obniżeniu charakterystyk
Autorzy:
Yang, H.
Xu, G.
Fan, X.
Powiązania:
https://bibliotekanauki.pl/articles/301128.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Polskie Naukowo-Techniczne Towarzystwo Eksploatacyjne PAN
Tematy:
performance degradation
Cloud theory
Monte Carlo method
randomness
fuzziness
obniżenie charakterystyk
teoria chmury
metoda Monte Carlo
losowość
rozmycie
Opis:
Owing to inadequate degradation data, the randomness and the fuzziness of degradation processes, it is difficult to calculate the reliability of product. By investigating performance reliability using degradation data of performance, the authors proposed a method of analyzing reliability of performance degradation data using Monte Carlo principle and cloud theory. First of all, the performance degradation cloud with the degradation amount and the entropy which denotes the possible discrete degree of the degradation data, is generated by using performance degradation data and a cloud theory forward cloud generator. Then, the minimum membership threshold of cloud droplets and the threshold of product failure were set. Meanwhile, the number of cloud droplets that comply with the minimum membership degree and the failure threshold were counted. Finally, the reliability method of performance degradation data was proposed by using the principle of Monte Carlo and the cloud theory. In this work, the cloud theory was introduced to verify the reliability of the performance degradation of the product. The randomness and the fuzziness in the degradation tests are resolved. In addition, due to the limits of degradation test data, the difficulties in calculation of the reliability is resolved using the principle of Monte Carlo, the minimum membership of cloud droplets and its minimum degree are therefore guaranteed. This work provides a new method of simulating the reliability of degradation. The feasibility of the method was validated by an example ensuring a high durability of conveyor belt joints is tantamount to guaranteeing their reliable operation and that the results of research conducted so far fail to provide unambiguous solutions to a number of problems that emerge in this case, it is advisable that advanced studies using computer techniques should be conducted within this area.
Ze względu na niewystarczające dane o degradacji oraz losowość i rozmycie procesów degradacji, obliczanie niezawodności produktu jest zadaniem trudnym. Chcąc badać niezawodność przy użyciu danych dotyczących obniżenia charakterystyk, autorzy zaproponowali metodę analizy danych o obniżeniu charakterystyk wykorzystującą zasady metody Monte Carlo oraz teorii chmury. Po pierwsze, wykorzystując dane o obniżeniu charakterystyk oraz progresywny generator chmur, wygenerowano chmurę obniżenia charakterystyk zawierającą dane na temat stopnia degradacji oraz stopnia entropii, która określa możliwy dyskretny stopień degradacji danych. Następnie, ustalono minimalny próg przynależności punktów chmury oraz próg uszkodzenia produktu. Policzono liczbę punktów chmury które spełniały warunek minimalnego stopnia przynależności oraz progu uszkodzenia. Wreszcie, zaproponowano metodę analizy niezawodnościowej danych o obniżeniu charakterystyk wykorzystującą zasady modelu Monte Carlo oraz teorii chmury. W pracy przedstawiono teorię chmury, która pozwala na weryfikację niezawodności danych of obniżeniu charakterystyk produktu. Rozwiązano w ten sposób problem losowości i rozmycia występujące w badaniach degradacji. Ponadto, przy użyciu metody Monte Carlo, rozwiązano trudności w obliczaniu niezawodności związane z ograniczeniami danych z badań degradacji, co zagwarantowało minimalną przynależność punktów chmury oraz minimalny stopień uszkodzenia. W prezentowanej pracy przedstawiono nową metodę symulacji niezawodności danych o degradacji. Poprawność przedstawionej metody zweryfikowano na podstawie przykładu. Zapewnienie wysokiej trwałości złączy taśmy przenośnikowej jest równoznaczne z zapewnieniem ich niezawodnej pracy, a ponieważ wyniki prowadzonych dotąd badań nie dostarczają jednoznacznych rozwiązań wielu wyłaniających się w tym przypadku problemów, wskazane jest prowadzenie w tym zakresie zaawansowanych badań z użyciem technik komputerowych.
Źródło:
Eksploatacja i Niezawodność; 2015, 17, 3; 435-442
1507-2711
Pojawia się w:
Eksploatacja i Niezawodność
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of PolyNIMMO-HTPB-polyNIMMO Triblock Copolymer as a Potential Energetic Binder
Autorzy:
Wang, X.
Shu, Y.
Lu, X.
Mo, H.
Xu, M.
Powiązania:
https://bibliotekanauki.pl/articles/358529.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
triblock copolymer
cationic ring opening polymerization
polymer
DSC
Opis:
Triblock copolymer polyNIMMO-HTPB-polyNIMMO was synthesized by cationic ring opening polymerization of NIMMO (3-nitratomethyl-3-methyloxetane) in the presence of hydroxyl-terminated polybutadiene catalyzed by BF3·OEt2. The polymer was characterized by FT-IR, 1H NMR, 13C NMR spectroscopy, and GPC. DSC was used to investigate the thermal behaviour of the triblock copolymer and its exothermic decomposition peak was found to be at 215 °C. All of the results indicated that the triblock copolymer polyNIMMO-HTPB-polyNIMMO might serve as a potential energetic propellant binder.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 3; 456-467
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis on electromechanical coupling vibration characteristics of in-wheel motor in electric vehicles considering air gap eccentricity
Autorzy:
Li, Y.
Wu, H.
Xu, X.
Cai, Y.
Sun, X.
Powiązania:
https://bibliotekanauki.pl/articles/200165.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
BLDC in-wheel motor
rotor eccentricity
unbalanced magnetic force
electric vehicle
electromechanical coupling vibrat
Opis:
The distortion of air gap magnetic field caused by the rotor eccentricity contributes to the electromechanical coupling vibration of the brushless DC (BLDC) permanent magnet in-wheel motor (PMIWM) in electric vehicles (EV). The comfort of the BLDC in-wheel motor drive (IWMD) EV is seriously affected. To deeply investigate the electromechanical coupling vibration of the PMIWM under air gap eccentricity, the PMIWM, tyre and road excitation are analyzed first. The influence of air gap eccentricity on air gap magnetic density is investigated. The coupling law of the air gap and the unbalanced magnetic force (UMF) is studied. The coupling characteristics of eccentricity rate, air gap magnetic density, UMF, phase current and vibration acceleration are verified on the test bench in the laboratory. The mechanism of the electro-mechanical coupling vibration of the BLDC PMIWM under air gap static eccentricity (SE), dynamic eccentricity (DE) and hybrid eccentricity (HE) is revealed. DE and HE deteriorate the vibration acceleration amplitude, which contributes the electromechanical coupling vibration of the PMIWM. The research results provide a solid foundation for the vibration and noise suppression of the PMIWM in distributed drive EV.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2019, 67, 5; 851-862
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Antibiofilm activity against Staphylococcus aureus and content analysis of Taraxacum Officinale phenolic extract
Autorzy:
Xu, P.
Xu, X.B.
Khan, A.
Fotina, T.
Wang, S.H.
Powiązania:
https://bibliotekanauki.pl/articles/2087162.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Taraxacum Officinale
phenolic
antibacterial mechanism
HPLC
Staphylococcus aureus
Źródło:
Polish Journal of Veterinary Sciences; 2021, 24, 2; 243-251
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extended Lie algebraic stability analysis for switched systems with continuous-time and discrete–time subsystems
Autorzy:
Zhai, G.
Xu, X.
Lin, H.
Liu, D.
Powiązania:
https://bibliotekanauki.pl/articles/929816.pdf
Data publikacji:
2007
Wydawca:
Uniwersytet Zielonogórski. Oficyna Wydawnicza
Tematy:
układ komutowany
funkcja Lapunowa
algebra Lie'go
stateczność wykładnicza
switched systems
common quadratic Lyapunov functions
Lie algebra
exponential stability
arbitrary switching
dwell time scheme
Opis:
We analyze stability for switched systems which are composed of both continuous-time and discrete-time subsystems. By considering a Lie algebra generated by all subsystem matrices, we show that if all subsystems are Hurwitz/Schur stable and this Lie algebra is solvable, then there is a common quadratic Lyapunov function for all subsystems and thus the switched system is exponentially stable under arbitrary switching. When not all subsystems are stable and the same Lie algebra is solvable, we show that there is a common quadratic Lyapunov-like function for all subsystems and the switched system is exponentially stable under a dwell time scheme. Two numerical examples are provided to demonstrate the result.
Źródło:
International Journal of Applied Mathematics and Computer Science; 2007, 17, 4; 447-454
1641-876X
2083-8492
Pojawia się w:
International Journal of Applied Mathematics and Computer Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of organohalogens in foodstuffs and environmental samples by neutron activation analysis and related techniques
Autorzy:
Xu, D.
Chai, Z.
Zhang, H.
Mao, X.
Ouyang, H.
Sun, H.
Powiązania:
https://bibliotekanauki.pl/articles/147259.pdf
Data publikacji:
2004
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
instrumental neutron activation analysis (INAA)
pine needle
foodstuff
extractable organohalogen
Opis:
Pine needles and foodstuffs collected from Beijing, China, were analyzed by instrumental neutron activation analysis (INAA) combined with organic solvent extraction for total halogens, extractable organohalogens (EOX) and extractable persistent organohalogens (EPOX). The INAA detection limits are 50 ng, 8 ng and 3.5 ng for Cl, Br and I, respectively. The contents and distribution patterns of organohalogens in these samples are reported. EOCl accounted for 0.013 0.016% and 1.6 2.7% of the total chlorine in yogurt and apples, respectively, which suggested that chlorine in foodstuffs mainly existed as inorganic species and non-extractable organochlorines. EOCl contents in pine needles and foodstuffs were noticeably higher than those of EOBr and EOI. For pine needles, yogurt and apples, 1.6 34%, 23 58% and 29 35% of EOCl remained as extractable persistent organochlorine (EPOCl), respectively. Pine needle containing higher EOCl contents in chemical industrial and traffic hub areas indicated that chemical industries and exhaust emission from vehicle were the main sources of organochlorines in the Beijing's air. The relative proportions of the known organochlorines (such as HCHs, DDTs, chlordanes, heptachlor, HCB and PCBs) to the total EOCl and EPOCl were 0.04 1.6% and 0.7 21.5%, respectively, which implied that the identity of species of a major portion of the EOCl and EPOCl measured in pine needles was unknown.
Źródło:
Nukleonika; 2004, 49, 3; 101-106
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
3D Simulation of Warp Knitted Structures with a New Algorithm Based on NURBS
Symulacja 3D struktur dzianych z zastosowaniem algorytmu opartego na algorytmie NURBS
Autorzy:
Xu, H Y
Chen, N L
Jiang, J H
Jin, L X
Wang, Z X
Powiązania:
https://bibliotekanauki.pl/articles/232913.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
warp knitted stitch
three-dimensional simulation
NURBS
joint of stitches
MATLAB
ścieg osnowy tkaniny
struktura dzianin
symulacja trójwymiarowy
algorytm NURBS
wspólne szwów
oprogramowanie Matlab
Opis:
In order to obtain a three-dimensional computer simulation of warp knitted structures with more flexibility and realism, a new algorithm using Matlab was developed by NURBS based on empirical geometrical loop models. With the principles of NURBS curves, once the values of data points are known, the control points with two coincidence points at the start and end points can be uncomplicatedly calculated by Matlab. Then the NURBS curve of a single typical stitch can be simulated flexibly by Matlab. A new typical stitch selected from two stitches simulated directly by the new method is redefined to improve the joint of neighboring stitches, and it is found that there are two types of redefined typical warp knitted stitches judged by whether the two under lap on the same side or not. Based on the redefined typical warp knitted stitch, two warp knitted structures are simulated regardless of the loop offset, and all the joints of stitches are smooth.
Przeprowadzono symulację komputerową struktur dzianin w wymiarze 3D, opracowując w tym celu nową procedurę opartą na algorytmie NURBS. Do tego celu wykorzystano oprogramowanie MATLAB. Symulację 3D przeprowadzono w oparciu o procedury numeryczne umożliwiające wykreślenie przestrzennych figur geometrycznych opisujących strukturę dzianin. Symulowano kształt oczek zamkniętych i otwartych podstawowych splotów kolumienkowych trykotu, sukna i aksamitu. W oparciu o 8 punktów referencyjnych zorientowano konfigurację pętli oczka i łącznika w postaci przestrzennej linii eliptycznej. Do zapisu struktury splotu kształtu oczek wykorzystywano aparat matematyczny w postaci macierzy.
Źródło:
Fibres & Textiles in Eastern Europe; 2015, 1 (109); 57-60
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Jiyuan tetrapod fauna of the Upper Permian of China: new pareiasaur material and the reestablishment of Honania complicidentata
Autorzy:
Xu, L.
Li, X.-W.
Jia, S.-H.
Liu, J.
Powiązania:
https://bibliotekanauki.pl/articles/22012.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Instytut Paleobiologii PAN
Opis:
Honania complicidentata and Tsiyuania simplicidentata are pareiasaur taxa based on material from the Shangshihezi Formation of Jiyuan, Henan Province, China that were earlier designated as nomina vana. Based on the study of new material, and the reexamination of old specimens, we determine that the pareiasaur material from Jiyuan represents a single species that differs from all known species from other localities. Thus, we resurrect the name H. complicidentata for the material from Jiyuan. H. complicidentata is characterized by maxillary teeth with high crowns, dentary teeth slightly posteriorly inclined compared to the dentary dorsal margin, nearly all preserved marginal teeth have a cusped cingulum on the lingual surface, and humerus without an ectepicondylar foramen. Phylogenetic analysis shows Honania is more basal than Shansisaurus and Shihtienfenia from the Sunjiagou Formation of China.
Źródło:
Acta Palaeontologica Polonica; 2015, 60, 3
0567-7920
Pojawia się w:
Acta Palaeontologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of quinoline from aqueous solutions by lignite, coking coal and anthracite. Adsorption isotherms and thermodynamics
Autorzy:
Xu, H.
Huagn, G.
Li, X.
Gao, L.
Wang, Y.
Powiązania:
https://bibliotekanauki.pl/articles/110016.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
quinoline adsorption
coking coal
adsorption isotherms
thermodynamics
Opis:
Based on the concept of circular economy, a novel method of industrial organic wastewater treatment by using adsorption on coal is introduced. Coal is used to adsorb organic pollutants from coking wastewaters. After adsorption, the coal would be used for its original purpose, its value is not reduced and the pollutant is thus recycled. Through systemic circulation of coking wastewater zero emissions can be achieved. Lignite, coking coal and anthracite were used as adsorbents in batch experiments. The quinoline removal efficiency of coal adsorption was investigated. The coking coal and anthracite exhibited properties well-suited for adsorption onto both adsorbents. The experimental data were fitted to Langmuir and Freundlich isotherms as well as Temkin, Redlich–Peterson (R-P) and Dubinin-Radushkevich (D-R) models. Both Freundlich Isotherm and D-R model provided reasonable models of the adsorption process. The thermodynamic parameters of quinoline adsorption on coking coal were calculated. The thermodynamic parameters indicated that the adsorption process is exothermic and is a physical adsorption. The △S° value indicated that the adsorption entropy decreased because the adsorbate molecule was under restrictions after it adsorption on the coal surface. The coal adsorption method for removing refractory organic pollutants is a great hope for achieving zero emission waste water for a coking plant.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 214-227
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pretreatment of coking wastewater by an adsorption process using fine coking coal
Autorzy:
Gao, L.
Li, S.
Wang, Y.
Gui, X.
Xu, H.
Powiązania:
https://bibliotekanauki.pl/articles/110417.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
coking coal
coking wastewater
adsorption
COD
phenol
Opis:
A new technique for pretreatment of coking wastewater is introduced based on the concept of circular economy. Coal is fed into a coking system after adsorption. This study validates the feasibility of using coking coal to adsorb organic pollutants in coking wastewater. The sorption kinetics and equilibrium sorption isotherms of coking coal for removal of chemical oxygen demand (COD) and phenol from coking wastewater was also discussed in this paper. Gas chromatograph/mass spectroscopy (GC/MS) was used to detect changes in the quality of coking wastewater. The results showed that when coking coal dosage was 120 g/dm3, 65% of COD and 34% of phenol in waste water can be removed after 40 min of agitation. The surface functional groups of coking coal before and after adsorption were observed with a Fourier transform infrared spectrometer. The kinetics of COD and phenol adsorption from coking wastewater by coking coal fitted the pseudo second-order model. The adsorption process of coking coal can be classified into two categories, namely, rapid and slow. The Freundlich isotherm provided a better fit with all adsorption isotherms than the Langmuir isotherm. Coking coal could be a suitable low-cost adsorbent for recalcitrant organic pollutants.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 422-436
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł

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