- Tytuł:
- Measurements of Hydrogen Solubility in Nitrobenzene/Aniline Mixtures
- Autorzy:
-
Srebniak, A.
Sobieszuk, P.
Kraut, M.
Görke, O. - Powiązania:
- https://bibliotekanauki.pl/articles/185556.pdf
- Data publikacji:
- 2017
- Wydawca:
- Polska Akademia Nauk. Czytelnia Czasopism PAN
- Tematy:
-
solubility
Henry’s constant
hydrogenation
rozpuszczalność
Stała Henry'ego
uwodornienie - Opis:
- Measurements of hydrogen solubility in various nitrobenzene-aniline mixtures were conducted in an autoclave reactor with a stirrer and control of temperature. The solubility of hydrogen was measured at 7 different values of temperature (30 °C, 40 °C, 50 °C, 90 °C, 130 °C, 170 °C, 210 °C, respectively), 3 values of stirrer rotation speed (1200 rpm, 1600 rpm, 2000 rpm, respectively) and a range of pressure of 20 ‒ 30 bar. Moreover, pure aniline, pure nitrobenzene and their mixtures with different concentrations were used. In the next step, values of Henry’s constant were calculated. Based on experimental data a dependence of Henry’s constant on temperature for pure aniline and pure nitrobenzene was proposed. Additionally, for each temperature correlations between Henry’s constant and aniline’s concentration in mixture of nitrobenzene-aniline were found.
- Źródło:
-
Chemical and Process Engineering; 2017, 38, 2; 241-248
0208-6425
2300-1925 - Pojawia się w:
- Chemical and Process Engineering
- Dostawca treści:
- Biblioteka Nauki
Artykuł