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Wyświetlanie 1-2 z 2
Tytuł:
Comparison of components and parameters of some sulfide minerals surface tension with regards to stability of mineral-air bubble system
Autorzy:
Jańczuk, Bronisław
Zdziennicka, Anna
Powiązania:
https://bibliotekanauki.pl/articles/1450639.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
contact angle
wettability
surface tension
detachment force
sulfide minerals
Opis:
The measurements of the advancing contact angle of water, glycerol, formamide, ethylene glycol, diiodomethane, α-bromonaphthalene, 1,2,3-tribromopropane on unoxidized and oxidized galena, pyrite, chalcopyrite, djurleite, bornite and covellite at the temperature equal 293 K were made. Additionally, the measurements of the force air bubble detachment from these sulfide minerals including also chalcocite in water were performed. Using the values of the obtained contact angle of water, glycerol, formamide, ethylene glycol, diiodomethane, α-bromonaphthalene, 1,2,3-tribromopropane the components and parameters of the unoxidized and oxidized sulfide minerals surface tension were calculated. For this calculation the van Oss et al. method was applied after analysis of the components and parameters of the surface tension of liquids used for contact angle measurements. Taking into account the contact angle of water on the sulfide minerals, the detachment force of air bubble from these minerals in water was determined using our equation and comparing to that of measured one. As follows from the measurements and calculations the wetting properties of sulfide minerals and the stability of mineral-air bubble depends to a larger extent on the degree of sulfide minerals oxidation than on the type of mineral.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 22-31
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison between surface and volumetric properties of short-chain alcohols and some classical surfactants
Autorzy:
Bielawska, Magdalena
Zdziennicka, Anna
Jańczuk, Bronisław
Powiązania:
https://bibliotekanauki.pl/articles/764079.pdf
Data publikacji:
2016
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
alcohols, surfactants, micelles, aggregates, CMC
Opis:
Measurements of the dynamic surface tension of the aqueous solutions of methanol, ethanol, propanol, CTAB and SDDS at their given concentrations were made. From the obtained results and the literature data it was concluded that the adsorption of short-chain alcohols at the water-air interface is somewhat similar to that of classical surfactants. For that reason the relationship between the Gibbs standard free energy of adsorption of short-chain alcohols and classical surfactants at that interface was established. The correlation between the chemical potential of mixing of alcohols and surfactants was also analysed. This analysis concerned the critical aggregation concentration (CAC) of alcohols and the critical micelle concentration (CMC) of surfactants. The chemical potential of surfactant mixing was calculated from the literature CMC data for the homologous series of alkyl sulfates, alkyl sulfonates, alkyl ammonium chlorides, alkyl trimethylammonium bromides, and alkyl pyridinium bromides. The influence of the hydrophobic chain length of alcohol and surfactant molecules on the Gibbs standard free energy of their adsorption at the water-air interface and their chemical potential of mixing were considered. It appeared that there is a linear dependence between these thermodynamic functions and the number of carbon atoms increased by 1 in the hydrocarbon chains of these compounds. This confirms clearly our conclusion that the behaviour of short-chain alcohols and classical surfactants at the water-air interface and in the bulk phase of aqueous solutions is similar. 
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2016, 71, 1
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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