Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Centralna Biblioteka Wojskowa Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaCentralna Biblioteka Wojskowa

Wyszukujesz frazę "Deng, L." wg kryterium: Wszystkie pola

  Lista filtrów
Wyrównaj
Wyświetlanie 1-15 z 21
Tytuł:
Flotation behavior of nickel sulfide ore in a cyclonic flotation column
Autorzy:
Deng, L.
Li, G.
Cao, Y.
Ma, Z.
Powiązania:
https://bibliotekanauki.pl/articles/109906.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cyclonic flotation column
floatability
flotation
nickel sulfide ore
Opis:
This study aimed to show the flotation behavior of a nickel sulfide ore in a cyclonic flotation column. The flotation experiments were carried out using a sample of nickel sulfide ore obtained from a mineral processing plant of China. Representative samples collected from the feed, concentrate, tailing, and circulation middling were sieved using a cyclonic particle analyzer to collect different size fractions for analysis. The function of the column cyclonic zone of was evaluated by comparing the quality of tailing and circulation middling. The flotation results showed that the concentrate with Ni grade of 1.78% and recovery of 65.56% was obtained under given test conditions. The content of main sulfide minerals and coarse particles in the circulation middling was higher than that in the tailing. The results indicated that, unlike conventional cyclone classification, separation achieved in the cyclonic zone of the column was not dependent on the particle size and density. Sulfide minerals with good floatability were easily captured by bubbles and moved toward the center of the column, even if these particles were coarser and heavier.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 770-780
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on mine ventilation resistance coefficient inversion based on genetic algorithm
Badanie inwersji współczynników oporu wentylacji kopalnianej na podstawie algorytmu genetycznego
Autorzy:
Gao, K.
Deng, L.
Liu, J.
Wen, L.
Wong, D.
Liu, Z.
Powiązania:
https://bibliotekanauki.pl/articles/219844.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
wentylacja kopalni węgla
współczynnik wentylacji
odwrócenie
algorytm genetyczny
coal mine ventilation
ventilation coefficient
inversion
genetic algorithm
Opis:
The frictional resistance coefficient of ventilation of a roadway in a coal mine is a very important technical parameter in the design and renovation of mine ventilation. Calculations based on empirical formulae and field tests to calculate the resistance coefficient have limitations. An inversion method to calculate the mine ventilation resistance coefficient by using a few representative data of air flows and node pressures is proposed in this study. The mathematical model of the inversion method is developed based on the principle of least squares. The measured pressure and the calculated pressure deviation along with the measured flow and the calculated flow deviation are considered while defining the objective function, which also includes the node pressure, the air flow, and the ventilation resistance coefficient range constraints. The ventilation resistance coefficient inversion problem was converted to a nonlinear optimisation problem through the development of the model. A genetic algorithm (GA) was adopted to solve the ventilation resistance coefficient inversion problem. The GA was improved to enhance the global and the local search abilities of the algorithm for the ventilation resistance coefficient inversion problem.
Współczynnik oporu oporu wentylacji jezdni w kopalni węgla jest bardzo ważnym parametrem technicznym w projektowaniu i renowacji wentylacji kopalnianej. Obliczenia oparte na wzorach empirycznych i badaniach terenowych w celu obliczenia współczynnika oporu mają ograniczenia. W niniejszym badaniu proponuje się inwertowaną metodę obliczania współczynnika oporu wentylacji kopalni za pomocą kilku reprezentatywnych danych dotyczących przepływu powietrza i ciśnienia w węzłach. Model matematyczny metody inwersji jest opracowywany na zasadzie najmniejszych kwadratów. Zmierzone ciśnienie i obliczone odchylenie ciśnienia wraz z zmierzonym przepływem i obliczonym odchyleniem przepływu są uwzględniane przy określaniu obiektywnej funkcji, która obejmuje również ciśnienie w węźle, przepływ powietrza i ograniczenia współczynników oporu wentylacji. Problem odwrotności współczynnika oporu wentylacji został przekształcony w nieliniowy problem optymalizacji poprzez opracowanie modelu. Zastosowano algorytm genetyczny (GA) w celu rozwiązania problemu inwersji współczynnika oporu wentylacji. GA został ulepszony w celu zwiększenia globalnych i lokalnych możliwości wyszukiwania algorytmu problemu odwrotności współczynnika oporu wentylacji.
Źródło:
Archives of Mining Sciences; 2018, 63, 4; 813-826
0860-7001
Pojawia się w:
Archives of Mining Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
17 beta-estradiol affects proliferation and apoptosis of canine bone marrow mesenchymal stem cells in vitro
Autorzy:
Zhou, Z.-H.
Gu, C.-W.
Li, J.
Huang, X.-Y.
Deng, J.-Q.
Shen, L.-H.
Cao, S.-Z.
Deng, J.-L.
Zuo, Z.-C.
Wang, Y.
Ma, X.-P.
Ren, Z.-H.
Yu, S.-M.
Powiązania:
https://bibliotekanauki.pl/articles/2087308.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
apoptosis
bone marrow mesenchymal stem cells (BMSCs)
canine
proliferation
17 beta-estradiol (E2)
Źródło:
Polish Journal of Veterinary Sciences; 2020, 23, 2; 235-245
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Design and Experiment on the Compact, Portable Pulse Forming Line
Autorzy:
Xia, L.
Shi, J.
Chen, D.
Zhang, H.
Zhang, L.
Deng, J.
Powiązania:
https://bibliotekanauki.pl/articles/1807991.pdf
Data publikacji:
2009-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
84.70.+p
77.90.+k
Opis:
Some research has been done on making the compact, portable pulse forming line. A kind of ceramic and a kind of newly developed composite polymer are both used as the dielectric of the planar pulse forming line. The ceramic's dielectric constant ranges from 200 to 600 and the composite polymer's dielectric constant ranges from 100 to 200. It is easier to manufacture the large composite polymer dielectric bulks than to manufacture the ceramic bulks. In the experiments, using the large composite polymer bulk as the dielectric, the planar Blumlein line generated the pulse up to 100 kV with duration 90 ns. Using the ceramic bulk as the dielectric, the planar line generated the voltage pulse up to 60 kV with duration 92 ns.
Źródło:
Acta Physica Polonica A; 2009, 115, 6; 1192-1193
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Germocyte lesions caused by porcine circovirus type 2b in Kunming mice
Autorzy:
Yuan, A.W.
Pang, P.
Gong, Q.L.
Deng, Z.B.
Powiązania:
https://bibliotekanauki.pl/articles/31710.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Opis:
Porcine circovirus type 2 (PCV2) has been known as a causative agent of reproductive failure in the sow. In the present study mouse model was used to investigate PCV2 infection. In order to investigate whether PCV2 can induce lesions of spermatocytes and oocytes, 6 male and 6 female mice were each inoculated intraperitoneally with PCV2b, and 3 male and 3 female mice mock-infected with cell culture supernatant served as controls. Samples of testes and ovaries from PCV2b-inoculated and mock-infected mice were investigated using PCR, histopathological, ultrastructural and immunofluorescent histochemical methods at 14 and 21 day post infection (dpi). The study revealed that in the virus-inoculated mice leydig cells in testes and granulosa cells in ovaries were degenerated, and a small number of spermatocytes and oocytes showed apoptosis. Positive PCV2b antigen signals were also observed in these apoptotic cells. It can be suggested that PCV2 can cause lesions of spermatocyte and oocyte prior to zygotes formation in its host.
Źródło:
Polish Journal of Veterinary Sciences; 2017, 20, 1
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
L-state analytical solution of the Klein-Gordon equation with position dependent mass using modified Deng-Fan plus exponential molecular potentials via Nikiforov-Uvarov method
Autorzy:
Itaa, B. I.
Louis, H.
Amos, P. I.
Joseph, I.
Nzeata-Ibe, N. A.
Magu, T. O.
Disho, H.
Powiązania:
https://bibliotekanauki.pl/articles/1178874.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Deng-Fan Potential
Exponential Molecular Potential
Klein-Gordon equation
Opis:
The solutions of the Klein-Gordon equation with Modified Deng-Fan plus Exponential molecular potentials (MDFEPP) has been presented using the Pekeris-like approximation and parametric Nikiforov-Uvarov (NU) method. The bound state energy eigenvalues and the corresponding un-unnormalized eigen functions are obtained in terms of Jacobi polynomials.
Źródło:
World Scientific News; 2017, 89; 64-70
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Design and the First Test Results of a Fast LTD Stage
Autorzy:
Chen, L.
Zhou, L.
Zou, W.
Ren, J.
Li, Y.
Wu, S.
Xie, W.
Feng, S.
Deng, J.
Powiązania:
https://bibliotekanauki.pl/articles/1807988.pdf
Data publikacji:
2009-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
84.70.+p
52.75.Kq
84.60.Ve
Opis:
Linear transformer driver stages are designed to be used as a primary energy storage in high power pulsed generators. In this report, the design and test results of the linear transformer driver stage prototype that delivers ≈100 kA fast pulse with 133 ns FWHM into a ≈0.87 Ω resistive load are described. This stage consists of 20 (100 kV, 20 nF) storage capacitors that are arranged in 10 identical bricks located evenly around the axis of the stage. Each brick contains two capacitors, a multi-gap switch, and the output connector that transfers the energy to the resistive load. The outer diameter of the stage is ≈1.5 m, at a length of ≈20 cm. The stage is developed to demonstrate the possibility of the fast linear transformer driver technology to create high power pulsed generators.
Źródło:
Acta Physica Polonica A; 2009, 115, 6; 1186-1188
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cloning, expression and genetic transformation of sucrose phosphate synthase (SPS) gene in Saccharum spontaneum L.
Autorzy:
Zhang, Yun-Wei
Zhou, Yun-Zhuan
Lu, Hai-Bo
Zheng, Deng-Yu
Huang, Yan-Hua
Powiązania:
https://bibliotekanauki.pl/articles/952058.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
saccharum spontaneum l.
sps gene
cloning
expression
tissue culture
genetic transformation
Opis:
Sucrose phosphate synthase (SPS) is a key enzyme catalyzing sucrose metabolism in plants. In this study, we isolated the SPS cDNA from Saccharum spontaneum and designated as SsSPS (GenBank accession no. MF398541). The full-length of SsSPS cDNA was 4153-bp with an opening reading frame (ORF) of 3132 nucleotides, which encoded a 1043-amino acid protein. The nucleotide sequences alignment showed that it had 98%, 97% and 87% homology with S. officinarum, Setaria italica and Lolium perenne, respectively. Moreover, the SsSPS was detected to express in leaf and stem tissues of S. spontaneum and exhibited a predominant expression in the stem tissue. However, there was no significant difference in the expression level of SsSPS between young leaves and mature ones. Additionally, we generated transgenic S. spontaneum using Agrobacterium-mediated transformation. Our data will provide a valuable foundation for further study of the potential role of SPS in plants.
Źródło:
Acta Biologica Cracoviensia. Series Botanica; 2017, 59, 2
0001-5296
Pojawia się w:
Acta Biologica Cracoviensia. Series Botanica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fast near-infrared palmprint recognition using nonnegative matrix factorization extreme learning machine
Autorzy:
Xu, X.
Zhang, X.
Lu, L.
Deng, W.
Zuo, K
Powiązania:
https://bibliotekanauki.pl/articles/173572.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
extreme learning machine
palmprint recognition
superior speed
support vector machine (SVM)
Opis:
Support vector machine and artificial neural network are widely used in classification applications. Extreme learning machine (ELM) is a novel and efficient learning algorithm based on the generalized single hidden layer feed forward networks, which performs well in classification applications. The research results have shown the superiority of ELM with the existing classical algorithms: support vector machine (SVM) and back propagation neural network. In this study, we firstly propose a novel nonnegative matrix factorization extreme learning machine (NMFELM) to improve the performance of standard ELM method. Then we propose a novel near-infrared palmprint recognition approach based on NMFELM classifier. As the test data, we use the near-infrared palmprint database provided by Hong Kong Polytechnic University. The experimental results demonstrate that the proposed NMFELM method outperforms the standard ELM- and SVM-based methods.
Źródło:
Optica Applicata; 2014, 44, 2; 285-298
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization Results for the L(2, 1, 1)-Labeling Problem on Trees
Autorzy:
Zhang, Xiaoling
Deng, Kecai
Powiązania:
https://bibliotekanauki.pl/articles/32031843.pdf
Data publikacji:
2017-08-01
Wydawca:
Uniwersytet Zielonogórski. Wydział Matematyki, Informatyki i Ekonometrii
Tematy:
tree
diameter
L(2, 1, 1)-labeling
Opis:
An L(2, 1, 1)-labeling of a graph G is an assignment of non-negative integers (labels) to the vertices of G such that adjacent vertices receive labels with difference at least 2, and vertices at distance 2 or 3 receive distinct labels. The span of such a labelling is the difference between the maximum and minimum labels used, and the minimum span over all L(2, 1, 1)-labelings of G is called the L(2, 1, 1)-labeling number of G, denoted by λ2,1,1(G). It was shown by King, Ras and Zhou in [The L(h, 1, 1)-labelling problem for trees, European J. Combin. 31 (2010) 1295–1306] that every tree T has Δ2(T) − 1 ≤ λ2,1,1(T) ≤ Δ2(T), where Δ2(T) = maxuv∈E(T)(d(u) + d(v)). And they conjectured that almost all trees have the L(2, 1, 1)-labeling number attain the lower bound. This paper provides some sufficient conditions for λ2,1,1(T) = Δ2(T). Furthermore, we show that the sufficient conditions we provide are also necessary for trees with diameter at most 6.
Źródło:
Discussiones Mathematicae Graph Theory; 2017, 37, 3; 611-622
2083-5892
Pojawia się w:
Discussiones Mathematicae Graph Theory
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Three-dimensional biomechanical modeling and simulation of trephine cutting cornea for keratoplasty
Autorzy:
Su, P.
Lu, D.
Deng, S.
Zhang, L.
Hao, Y.
Yang, Y.
Powiązania:
https://bibliotekanauki.pl/articles/307486.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
rogówka
biomechanika
kryterium wytężeniowe
FEM
cornea
biomechanics
failure criterion
finite element simulation
Opis:
Trephination is one of the basic operations of keratoplasty, and the biomechanical mechanism of the operation can be revealed based on three-dimensional modeling and simulation of trephine cutting cornea. Methods: Based on the analysis of the physical and biomechanical characteristics of corneal trephination, a three-dimensional numerical model of corneal trephination is built, where the cornea can be simplified to two layers structure including stroma and epithelium, and the trephine cuts the cornea under the vertical motion load and the rotational motion load. A three-dimensional failure criterion of corneal material is proposed based on the yield strength theory. On this basis, trephination simulation is carried out, and the units of corneal material are removed from the model when they meet the defined failure criterion. Results: Under the given parameters including the velocity, the angle and the angular velocity, the trephine force curves, include the linear cutting force and the rotary cutting force are obtained, and show the change of the forces with displacement during the process of trephination simulation. The maps of the equivalent stress show the destruction and deformation of the cornea. Then, the experiment of robotic trephination is carried out under the same parameters and the effectiveness of the simulation is evaluated. Conclusions: Based on mechanics theory and finite element method, the process of trephine cutting cornea has been reproduced, and the interaction mechanism is revealed, which lays the foundation for the development of real-time simulation and virtual system of the corneal surgery.
Źródło:
Acta of Bioengineering and Biomechanics; 2018, 20, 2; 23-33
1509-409X
2450-6303
Pojawia się w:
Acta of Bioengineering and Biomechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sexual dimorphism in perissodactyl rhinocerotid Chilotherium wimani from the Late Miocene of the Linxia Basin (Gansu, China)
Autorzy:
Chen, S.
Deng, T.
Hou, S.
Shi, Q.
Pang, L.
Powiązania:
https://bibliotekanauki.pl/articles/23414.pdf
Data publikacji:
2010
Wydawca:
Polska Akademia Nauk. Instytut Paleobiologii PAN
Tematy:
sexual dimorphism
perissodactyl rhinocerotid
Mammalia
Perissodactyla
Chilotherium wimani
Late Miocene
Miocene
Linxia basin
China
Opis:
Sexual dimorphism is reviewed and described in adult skulls of Chilotherium wimani from the Linxia Basin. Via the analysis and comparison, several very significant sexually dimorphic features are recognized. Tusks (i2), symphysis and occipital surface are larger in males. Sexual dimorphism in the mandible is significant. The anterior mandibular morphology is more sexually dimorphic than the posterior part. The most clearly dimorphic character is i2 length, and this is consistent with intrasexual competition where males invest large amounts of energy jousting with each other. The molar length, the height and the area of the occipital surface are correlated with body mass, and body mass sexual dimorphism is compared. Society behavior and paleoecology of C. wimani are different from most extinct or extant rhinos. M/F ratio indicates that the mortality of young males is higher than females. According to the suite of dimorphic features of the skull of C. wimani, the tentative sex discriminant functions are set up in order to identify the gender of the skulls.
Źródło:
Acta Palaeontologica Polonica; 2010, 55, 4
0567-7920
Pojawia się w:
Acta Palaeontologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assessing soil environmental capacity on different land uses in a suburban area of Chengdu, China
Autorzy:
Yang, W.-L.
Zhou, W.-Y.
Wan, W.-X.
Gou, S.-Z.
Zhang, J.
Deng, S.-H.
Shen, F.
Wang, Y.-J.
Yang, H.
Luo, L.
Powiązania:
https://bibliotekanauki.pl/articles/207670.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
China
soil pollution
heavy metals
soil
vegetables
Chiny
zanieczyszczenie gleby
metale ciężkie
gleba
warzywa
Opis:
Wenjiang (China) is the area which undertakes high-intensity planting activities. Additionally, the soil environmental capacity has been a hot area of research as it plays a key role in environmental protection planning, environmental impact assessment and sustainable development. In this paper, the static model of soil environmental capacity is employed to investigate the distribution of residual soil environmental capacity in Wenjiang. The results show that the soil environmental capacity of mercury is the largest for industrial land while it is the lowest in garlic-rice planting areas; the soil environmental capacity of arsenic is the largest in city construction land while it is the lowest in ecological conservation zone; the soil environmental capacity of lead is the largest in city construction land while it is the lowest in garlic-rice planting areas; and the soil environmental capacity of chromium is the largest in city construction land while it is the lowest in garlic-rice planting areas.
Źródło:
Environment Protection Engineering; 2019, 45, 2; 55-67
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Seroprevalence of antibodies to classical swine fever virus and porcine reproductive and respiratory syndrome virus in healthy pigs in Hunan Province, China
Autorzy:
Yu, H.
Zhang, L.
Cai, Y.
Hao, Z.
Luo, Z.
Peng, T.
Liu, L.
Wang, N.
Wang, G.
Deng, Z.
Zhan, Y.
Powiązania:
https://bibliotekanauki.pl/articles/16539345.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
classical swine fever virus (CSFV)
porcine reproductive and respiratory syndrome virus (PRRSV)
pig
seroprevalence
antibody
Opis:
Classical swine fever (CSF) and porcine reproductive and respiratory syndrome (PRRS) are responsible for major economic losses and represent a threat to the swine industry worldwide. Routine surveillance serology for CSF and PRRS viruses is critical to maintaining the health status of sow farms in Hunan Province, which is one of the top pig production provinces in China. The aim of our study was to investigate the serological statistics of CSF virus (CSFV) and PRRS virus (PRRSV) in Hunan Province. The cohort serum samples were collected from vaccinated and unvaccinated pigs. Our findings showed that the average rates of CSFV and PRRSV antibody seropositivity were 82.2% (95% CI: 80.1-84.3) and 84.8% (95% CI: 82.5-87.1), respectively, in the immunized group and that these rates were higher than those in the unvaccinated group (58.6% for CSFV and 47.8% for PRRSV). Additionally, the level of CSFV antibody in piglet serum declined gradually with age, whereas PRRSV-specific antibody level increased initially (1 to 2 weeks old) and then declined with age (2 to 4 weeks old). In summary, we investigated the difference in CSFV/PRRSV antibody levels among piglets at various weeks old (1 to 4 weeks) to further establish the duration of maternal immunity in piglets. In addition, routine monitoring of CSFV/PRRSV antibodies in immunized pigs was carried out to evaluate the efficacy of vaccination.
Źródło:
Polish Journal of Veterinary Sciences; 2022, 25, 3; 375-381
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ag+/S2O8 2– system for the degradation of aqueous flutriafol
Autorzy:
Yang, H.
Zhou, W.
Yang, L.
Deng, J.
Hu, Q.
Wei, H.
Au, C.
Yi, B.
Powiązania:
https://bibliotekanauki.pl/articles/207760.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chemical analysis
degradation
free radicals
metal ions
molecular orbital
transition metals
analiza chemiczna
degradacja
wolne rodniki
jony metali
orbital molekularny
metale przejściowe
Opis:
The degradation of flutriafol in aqueous persulfate (S2O82–) system in the presence of selected transition metal ions was investigated. In the presence of Ag+ or Fe2+, flutriafol degradation occurs, whereas in the presence of Mn2+, Co2+, Ni2+, Cu2+, Zn2+ and Bi3+ ions, the degradation is less than 15%. The Ag+/ S2O82– aqueous system being the most effective was adopted for experimental and theoretical investigations. It was confirmed that pH of 3.0 is the most suitable, and that both · SO4–and ·OH– radicals are the main active species to afford flutriafol degradation, with the former contributes more than the latter. To elucidate degradation mechanism, molecular orbital calculations were performed and reaction intermediates identified by GC/MS and HPLC/MS/MS analyses. Three degradation pathways are proposed that involve the cleavage of C–N and C–C bonds as a result of ·SO4– attack, as well as the formation of hydroxylated products due to · OH radicals.
Źródło:
Environment Protection Engineering; 2018, 44, 2; 57-72
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 21

Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies