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Wyświetlanie 1-15 z 95
Tytuł:
Magnetic resonance study of co-modified (Co,N)-TiO2 nanocomposites
Autorzy:
Guskos, N.
Zolnierkiewicz, G.
Guskos, A.
Typek, J.
Berczynski, P.
Dolat, D.
Mozia, S.
Aidinis, C.
Morawski, A. W.
Powiązania:
https://bibliotekanauki.pl/articles/146542.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
nanocomposites
titanium dioxide
ferromagnetic resonance
Opis:
Three nCo,N-TiO2 nanocomposites (where cobalt concentration index n = 1, 5 and 10 wt %) were prepared and investigated by magnetic resonance spectroscopy at room temperature. Ferromagnetic resonance (FMR) lines of magnetic cobalt agglomerated nanoparticle were dominant in all registered spectra. The relaxation processes and magnetic anisotropy of the investigated spin system essentially depended on the concentration of cobalt ions. It is suggested that the samples contained two magnetic types of sublattices forming a strongly correlated spin system. It is suggested that the existence of strongly correlated magnetic system has an essential infl uence of the photocatalytic properties of the studied nanocomposites.
Źródło:
Nukleonika; 2015, 60, No. 3, part 1; 411-416
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simultaneous photooxidation and photoreduction of phenol and Cr(VI) ions using titania modified with nanosilica
Autorzy:
Kądziołka, Daria
Grzechulska-Damszel, Joanna
Schmidt, Beata
Powiązania:
https://bibliotekanauki.pl/articles/2174823.pdf
Data publikacji:
2022
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
photocatalysis
titanium dioxide
nanosilica
water purification
Opis:
The photocatalytic process of phenol oxidation and Cr(VI) reduction in the presence of nano-silica modified titania was carried out. The activity of composites was tested using two different light sources. The photocatalysts with 10% of nanosilica showed the highest activity. The calcination temperature (200–800 °C) significantly determined the sensitivity of the obtained materials to the light source used. Photocatalysts alternately adsorbed and desorbed Cr(VI) ions from the reaction mixture during irradiation. In the one-component mixture, complete oxidation of phenol was observed using material calcined at 650 °C, after 3 h of UV-VIS irradiation. In the reaction mixture of Cr(VI) and phenol, the highest activity was demonstrated by photocatalyst calcined at 300 °C. The concentration of phenol decreased in proportion to the decrease of chromium ions. The obtained titania-silica composites showed oxidizing properties towards phenol and reductive properties toward Cr(VI) ions.
Źródło:
Polish Journal of Chemical Technology; 2022, 24, 4; 23--29
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechaniczne i fizykochemiczne właściwości warstw TiO2
Mechanical and physicochemical properties of titanium dioxide thin films
Autorzy:
Krzak-Roś, J.
Grygier, D.
Baszczuk, A.
Będziński, R.
Powiązania:
https://bibliotekanauki.pl/articles/284866.pdf
Data publikacji:
2007
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
ditlenek tytanu
implanty
implants
titanium dioxide
Źródło:
Engineering of Biomaterials; 2007, 10, no. 67-68; 35-37
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The optical parameters of TiO2 antireflection coating prepared by atomic layer deposition method for photovoltaic application
Autorzy:
Szindler, Marek
Szindler, Magdalena M.
Powiązania:
https://bibliotekanauki.pl/articles/1835965.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
thin film
atomic layer deposition
titanium dioxide
Opis:
Titanium dioxide thin films have been deposited on silicon wafers substrates by an atomic layer deposition (ALD) method. There optical parameters were investigated by spectroscopic ellipsometry and UV/VIS spectroscopy. A material with a refractive index of 2.41 was obtained. Additionally, in a wide spectral range it was possible to reduce the reflection from the silicon surface below 5%. The Raman spectroscopy method was used for structural characterization of anatase TiO2 thin films. Their uniformity and chemical composition are confirmed by a scanning electron microscope (SEM) energy dispersive spectrometer (EDS).
Źródło:
Optica Applicata; 2020, 50, 4; 663-670
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Artificial skin composites
Autorzy:
Ładniak, Agata
Powiązania:
https://bibliotekanauki.pl/articles/2079951.pdf
Data publikacji:
2018
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
titanium dioxide,
chitosan
hyaluronic acid
skin substitutes
Opis:
Skin injuries are a health problem and can lead to serious, significant deterioration in the quality of life and, consequently, even illness and disability. Therefore, after wounding, immediate regeneration of the tissue is necessary to avoid further complications and pathogenesis. Consequently, many wound healing strategies have been developed, leading to the progress in constructing of multifunctional tissue substitutes for the skin, biomembranes, scaffolds and intelligent dressings. The field of science focusing on the creation of the above-mentioned products is tissue engineering (TE). Its main goal is to find a system that is able to replace or be a model that perfectly mimics the form and function of the skin. Research carried out on such constructs is mainly based on the analysis of mechanical properties (porosity, elasticity), as well as the assessment of the impact of individual components on processes related to the formation of new tissue as cell proliferation and differentiation, proliferation, angiogenesis - through in vivo studies (using animal models: mice, New Zealand rabbits) and in vitro (most often using mouse fibroblasts - L929). Skin constructions may have potential applications as wound dressings or skin substitutes in cases of severe skin damage.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2018, 73, 1; 51-60
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Degradation of sertraline in water by suspended and supported TiO2
Autorzy:
Rejek, M.
Grzechulska-Damszel, J.
Powiązania:
https://bibliotekanauki.pl/articles/780043.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
photocatalysis
titanium dioxide
pharmaceuticals
sertraline
water treatment
Opis:
Pharmaceutical pollutants have been detected in many countries in surface and ground water after treatment in wastewater treatment plants. The presented studies concern the photocatalytic removal of one of SSRI antidepressants - sertraline from water using TiO2  photocatalyst. The process was conducted using two laboratory installations with periodic and flow reactors. Two forms of TiO2  was used in the photocatalytic reactions: suspended and supported onto a glass fabric. The studies shown that with increasing initial concentration of pharmaceutical, photoactivity decreases. For the initial concentration of 0.025 g/dm3 , the best results – 94% removal – was achieved for the process conducted in the periodic reactor with TiO2  supported onto a glass fabric.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 2; 107-112
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Behaviour of tio2/chitosan dispersion as a function of solution ph
Autorzy:
Gozdecka, Agata
Wiącek, Agnieszka E.
Powiązania:
https://bibliotekanauki.pl/articles/1034623.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
adsorption
chitosan
pH
targeted therapy
titanium dioxide
Opis:
This paper presents the physico-chemical characteristics of titanium dioxide/chitosan dispersion. The surface and electrostatic properties of TiO2 particles in the electrolyte solution (NaCl) and in the presence of a biopolymer were determined by static and dynamic light scattering. The stability measurements were made under different conditions, where the variable was the dispersion pH. This paper mainly includes discussion of dispersion behaviour in neutral and alkaline environments. At each pH value (6–9), the addition of chitosan caused significant improvement in stability compared to the systems of base titanium dioxide. Of the tested systems, the most stable values of diameter and zeta potential for dispersion were found at pH 7. The study allowed the conclusion that the addition of chitosan to TiO2 dispersion created the possibility of using such systems as a drug carrier for the controlled release of active substances sensitive to pH changes.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2017, 22; 27-41
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Polarization Processes on the Morphology and Photoluminescence Properties of PP/TiO₂ Polymer Nanocomposites
Autorzy:
Ramazanov, M.
Hajiyeva, F.
Maharramov, A.
Hasanova, U.
Ahmadova, A.
Rahimli, A.
Shirinova, H.
Powiązania:
https://bibliotekanauki.pl/articles/1032328.pdf
Data publikacji:
2017-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
photoluminescence
corona discharge
nanocomposites
polypropylene
titanium dioxide
Opis:
The paper reports of synthesis and investigation of polymeric nanocomposites based on isotactic polypropylene and titanium dioxide nanoparticles PP+TiO₂ (PPT). The structure of the PPT nanocomposites was studied by scanning electron and atomic force microscopy. There was also studied the influence of the polarization process by corona discharge on the structure and photoluminescence properties of PPT nanocomposites. It was found that intensity of the photoluminescence after the polarization increases, and this depends on the concentration of titan dioxide nanoparticles in the polymer matrix. It was shown that rms roughness for non-polarized sample compositions is 60-100 nm, whereas for polarized samples after the corona discharge polarization, makes 20-40 nm, i.e. there takes place grinding of the structural elements. It is supposed that, in the composite there forms sufficiently high internal local field, due to the boundary charges, so under the influence of this field there were excited additional luminescent centers, and as a result, after the polarization there was observed the increase of luminescence intensity.
Źródło:
Acta Physica Polonica A; 2017, 131, 6; 1540-1543
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Correlation between growth mechanisms and the influence of process control parameters on physical properties of titanium dioxide nanotubes in electrochemical anodisation
Autorzy:
Kioko, S.
Khanna, K. M.
Österlund, L.
Powiązania:
https://bibliotekanauki.pl/articles/1193444.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Anodization
High field
Nanotubes
Titanium dioxide
Tunneling
Opis:
The growth of thin oxide films has been covered by several theories and models. The high electrical field model, Fowler-Nordheim tunneling in Metal Oxide films and Schottyky barrier Mechanisms are models which explain metal oxide formation. The growth mechanisms and process control parameters during thin film growth in electrochemical anodization play a key role in the growth process. This work explores how the growth mechanisms correlate with process control parameters to influence the growth process in electrochemical anodization of titanium dioxide nanotubes (TNTs). The theories on growth mechanism have been explained in detail. On the experimental part, TiO2 nanotubes were synthesized for photocatalytic activity using electrochemical anodization in a third generation electrolyte. The electrolyte comprised of a mixture of ethylene glycol and ammonium fluoride in little amount of water. Anodizing time and electrode separation distance were explored as process control parameters. The TNTs were analysed using SEM, XRD, Profilometer and UV-Visible spectrophotometer. Short electrode separation distance recorded fast growth, non-uniformity in TNTS, disorganisation, distortion and etching of TNTs. The TNT length, inner and outer diameters reduced with increasing electrode separation distance due to reduction of electric field, increased bulk resistance. There was no significant increase in TNT dimensions at electrode separation distance of 4.5 cm which also recorded the smallest grain size for the TNTs highest degree of crystallinity for with absorption maxima at 550 nm. TNT length, inner and outer diameters and crystallinity increased with anodising time.
Źródło:
World Scientific News; 2021, 157; 80-104
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of chitosan, hyaluronic acid and/or titanium dioxide on the physicochemical characteristic of phospholipid film/glass surface
Autorzy:
Ładniak, Agata
Jurak, Małgorzata
Wiącek, Agnieszka Ewa
Powiązania:
https://bibliotekanauki.pl/articles/109601.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chitosan
titanium dioxide
hyaluronic acid
phospholipid
adhesion
topography
Opis:
The production of preparations, whose destination action takes place in close proximity to living cells, increases the necessity to carry out studies concerning the determination of the biomaterial surface effect on the cellular response. In achieving this goal, physicochemical characteristic of the surface can be helpful. This can be established based on topography, chemical composition, wettability, and surface energy analysis. In addition, determining the changes of these properties which can occur as a result of surface modification will allow prediction of cell behaviour when contacting with biomaterial. In the study, the Langmuir-Blodgett technique was used. It enabled the transfer of the Langmuir monolayer formed from 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) to a solid support. The DPPC film imitated a natural biological membrane capable of interacting with the components of the liquid subphase: chitosan (Ch), hyaluronic acid (HA) and/or titanium dioxide (TiO2). Depending on the type and strength of interactions of phospholipid molecules with the components of the subphase, the films obtained on the solid support were characterized by specific surface properties. Their characteristics based mainly on values of the work of adhesion in connection with films topography, allowed for statement that it is possible to form semi-interpenetrating Ch network in which HA is entrapped, contributing to the enhanced adhesion of the DPPC film, additionally intensified by TiO2 inclusion. This type of research permit for better understanding of the interactions at the interface, cell membrane-Ch/HA/TiO2 and can be important in the creation of a new generation of skin or tissue substitutes.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 6; 1535-1548
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetics of sulphuric acid leaching of titanium from refractory anatase under atmospheric pressure
Autorzy:
Gao, Likun
Rao, Bing
Dai, Huixin
Xie, Haiyun
Wang, Peng
Ma, Fangtong
Powiązania:
https://bibliotekanauki.pl/articles/109701.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
anatase ore
kinetics
sulphuric acid
leaching
titanium dioxide
Opis:
Anatase, as an important titanium resource, is attracting more and more attention in research and application. In this study, an efficient process of comprehensively extracting the titanium and other valuable elements from the anatase mineral was proposed. The effect of particle size, stirring speed, initial sulphuric acid concentration, solid-to-liquid ratio, and reaction temperature on the leaching rate of titanium from anatase was investigated. Under appropriate two-stage countercurrent leaching conditions, with the first stage of the liquid-to-solid ratio of 1/3 g/cm3, reaction temperature of 120 °C, initial acid concentration of 11 mol/dm3, residence time of 30 min, stirring speed of 200 rpm, and the second stage of the liquid-to-solid ratio of 1/3 g/cm3, reaction temperature of 200 °C, initial acid concentration of 13 mol/dm3, residence time of 30 min, and stirring speed of 200 rpm, over 99% TiO2, 99% Al2O3, and 97% Sc2O3 were extracted respectively with quartz still remained in the residue. X-ray diffraction, X-ray fluorescence spectrometer, and scanning electron microscopy/energy-dispersive spectroscopy were used to characterize the anatase samples before and after the leaching. Additionally, the leaching kinetics analysis indicated that both acid concentration and temperature were the most significant parameters for the leaching process. And, the titanium leaching reaction rate was controlled by the diffusion of reactants through the residual layer.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 467-478
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental Analysis of Titanium Dioxide Synthesis from Synthetic Rutile Waste using a Moderate Acid Concentration and Temperature
Autorzy:
Ahmad Mukifza, H.
Awang, H.
Yusof, S.
Farid, E.
Powiązania:
https://bibliotekanauki.pl/articles/1031724.pdf
Data publikacji:
2017-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
synthetic rutile
titanium dioxide
caustic hydrothermal
sodium titanate
Opis:
The present study is to clarify the present influences of acid concentration and temperature of caustic hydrothermal method on extracting the titanium dioxide (TiO₂) from synthetic rutile waste. In this experimental work, the caustic hydrothermal method comprises two processes: a decomposition and the sulphate process. The extracted titanium is characterized by using a electron dispersive X-ray spectroscopy to specify its chemical composition, field emission scanning electron microscope to determine the morphology and particle size, and lastly it is the X-ray diffraction to analyse the crystallinity of extracted titanium. In this study, we found that both acid concentration and temperature affected the TiO₂ growth while the calcination process could improve the crystallinity of extracted titanium.
Źródło:
Acta Physica Polonica A; 2017, 132, 3; 833-835
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of titanium dioxide addition on physical and biological properties of Na2O-B2O3-P2O5 and CaO-Na2O-P2O5 glasses
Autorzy:
Kalwasińska, O.
Gajc, M.
Kłos, A.
Orliński, K.
Pawlak, D. A.
Krok-Borkowicz, M.
Rumian, Ł.
Pietryga, K.
Reczyńska, K.
Pamuła, E.
Powiązania:
https://bibliotekanauki.pl/articles/285502.pdf
Data publikacji:
2016
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
phosphate glasses
bioactive glasses
titanium dioxide
tissue engineering
Opis:
Two types of phosphate glasses 50Na2O-20B2O3-30P2O5 (NBP) and 30CaO-20Na2O-50P2O5 (CNP) with different content of TiO2 (0, 3 and 5 mol%) have been prepared by melt-quenching process. TiO2 was added to increase glass network stability. Physical properties of glasses were investigated by density measurements, differential scanning calorimetry and degradation in phosphate buffered saline (PBS). Biological performance of glasses in a direct contact with osteoblast-like MG-63 cells was analysed with the use of resazurin test and live-dead staining. The results show that TiO2 addition increased density, glass transition temperature (Tg) and melting temperature (Tm) of both types of glasses. In the case of NBP glasses presence of TiO2 resulted in their fast degradation in PBS and acidification of cell culture medium. As a consequence such glasses did not support cell adhesion and growth, but they can be considered for e.g. drug delivery systems. On the other hand addition of TiO2 to CNP glasses resulted in enhanced cell adhesion and viability. Particularly positive results were found for CNP glass containing 5% TiO2, so it can be a good candidate as a scaffold material for bone tissue engineering.
Źródło:
Engineering of Biomaterials; 2016, 19, 134; 2-7
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of sulfur addition on the hazard-type reaction of ilmenite ores with sulfuric acid
Autorzy:
Jabłoński, Maciej
Lubkowski, Krzysztof
Tylutka, Sandra
Ściążko, Andrzej
Powiązania:
https://bibliotekanauki.pl/articles/1849314.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
hazard-type reaction
ilmenite
titanium dioxide pigment
sulfur
Opis:
The paper presents results of thermokinetic investigation of the hazard-type reaction of Norwegian and Australian ilmenite ores with sulfuric acid, modified by the addition of elemental sulfur, to increase the process safety in industrial conditions. In the reactions of both ilmenite ores the addition of sulfur caused a reduction of the thermal power generated in the reaction and a decrease in the value of the thermokinetic parameter ΔTmax/Δτ for almost the whole range of initial concentrations of sulfuric acid. It was also found that the addition of sulfur to the reaction did not negatively affect the degree of ilmenite leaching. The interpretation of the obtained thermokinetic curves allowed to determine safe process conditions for both types of titanium raw materials.
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 3; 17-23
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of sulfur addition on the hazard-type reaction of ilmenite ores with sulfuric acid
Autorzy:
Jabłoński, Maciej
Lubkowski, Krzysztof
Tylutka, Sandra
Ściążko, Andrzej
Powiązania:
https://bibliotekanauki.pl/articles/1849319.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
hazard-type reaction
ilmenite
titanium dioxide pigment
sulfur
Opis:
The paper presents results of thermokinetic investigation of the hazard-type reaction of Norwegian and Australian ilmenite ores with sulfuric acid, modified by the addition of elemental sulfur, to increase the process safety in industrial conditions. In the reactions of both ilmenite ores the addition of sulfur caused a reduction of the thermal power generated in the reaction and a decrease in the value of the thermokinetic parameter ΔTmax/Δτ for almost the whole range of initial concentrations of sulfuric acid. It was also found that the addition of sulfur to the reaction did not negatively affect the degree of ilmenite leaching. The interpretation of the obtained thermokinetic curves allowed to determine safe process conditions for both types of titanium raw materials.
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 3; 17-23
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
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