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Wyświetlanie 1-15 z 23
Tytuł:
Removal of quinoline from aqueous solutions by lignite, coking coal and anthracite. Adsorption kinetics
Autorzy:
Xu, H.
Wang, Y.
Huagn, G.
Fan, G.
Gao, L.
Li, X.
Powiązania:
https://bibliotekanauki.pl/articles/110664.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
quinoline adsorption
coking coal
kinetics
adsorption activation energy
coal adsorption
Opis:
Basing on the concept of circular economy, a novel method of industrial organic wastewater treatment by using adsorption on coal is introduced. Coal is used to adsorb organic pollutants from coking wastewaters. After adsorption, the coal would be used in its original purpose, as its value was not reduced and the pollutant was reused. Through the systemic circulation of coking wastewater zero emissions can be achieved. Lignite, coking coal and anthracite were used as adsorbents in batch experiments. The quinoline removal efficiency of coal adsorption was investigated. Both the coking coal and anthracite exhibited properties well-suited for quinoline adsorption removal. The experimental data were fitted to the pseudo-first- order and pseudo-second-order kinetic equations as well as intraparticle diffusion and Bangham models. An attempt was made to find the rate-limiting step involved in the adsorption processes. Both boundary-layer diffusion and intraparticle diffusion are likely involved in the rate-limiting mechanisms. Effect of pH on coal adsorptions by coking coal was investigated. The process of quinoline adsorption on coal was researched. The coal adsorption method for removing refractory organic pollutants is a great hope for achieving wastewater zero emission for coking plants.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 397-408
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of coal particle size on coal adsorption and desorption characteristics
Wpływ wielkości ziaren węgla na charakterystyki adsorpcji i desorpcji na węglu
Autorzy:
Zhang, L.
Aziz, N.
Ren, T.
Nemcik, J.
Tu, S.
Powiązania:
https://bibliotekanauki.pl/articles/219328.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
adsorpcja na węglu
desorpcja na węglu
wymiary ziaren węgla
izoterma
objętość Langmuira
coal adsorption
desorption
coal particle size
isotherm
Langmuir volume
Opis:
Accurate testing coal isotherm can play a significant role in the areas of coal seam gas drainage, outburst control, CO2 geo-sequestration, coalbed methane (CBM) and enhanced coalbed methane recovery (ECBM) etc. The effect of particle size on the CO2 and CH4 sorption capacity of bituminous coal from Illawarra, Australia was investigated at 35°C and at pressure up to 4 MPa. A unique indirect gravimetric apparatus was used to measure the gas adsorption and desorption isotherms of coal of different particle sizes ranging from around 150 urn to 16 mm. Langmuir model was used to analysis the experimental results of all gases. Coal particle size was found to have an apparent effect on the coal ash content and helium density results. Coal with larger particle size had higher ash content and higher helium density. The sorption isotherm was found to be highly sensitive with helium density of coal which was determined in the procedure of testing the void volume of sample cell. Hence, coal particle size had a significant influence on the coal sorption characteristics including sorption capacity and desorption hysteresis for CO2 and CH4, especially calculated with dry basis of coal. In this study, the 150-212 um (150 um) coal samples achieved higher sorption capacity and followed by 2.36-3.35 mm (2.4 mm), 8-9.5 mm (8 mm) and 16-19 mm (16 mm) particle size samples. However, the differences between different coal particles were getting smaller when the sorption isotherms are calculated with dry ash free basis. Test with 150 um coal samples were also found to have relatively smaller desorption hysteresis compared with the other larger particle size samples. The different results including adsorption/desorption isotherm, Langmuir parameters and coal hysteresis were all analysed with the CO2 and CH4 gases.
Dokładne zbadanie izoterm sorpcji na węglu odgrywa kluczową rolę w takich dziedzinach jak odgazowanie pokładów węgla, zapobieganie wybuchom, sekwestracja geologiczna CO2, odzysk metanu ze złoża. Wpływ wielkości ziaren na pojemność sorpcyjną bitumicznego węgla z Illawara (Australia) względem CO2 i CH4 zbadano w temperaturze 35°C przy ciśnieniu do 4 MPa. Wykorzystano oryginalną aparaturę do badań grawimetrycznych do zmierzenia izoterm adsorpcji i desorpcji na węglu w którym rozmiar ziaren wahał się od 150 μm do 16 mm. Analizę wyników doświadczalnych dla wszystkich gazów przeprowadzono w oparciu o model Langmuira. Stwierdzono, że rozmiary ziaren węglowych w znacznym stopniu warunkują zawartość popiołu i gęstość helową. Węgiel grubiej uziarniony charakteryzował się wyższą zawartością popiołu i większą gęstością helową. Wykazano, że izoterma sorpcji wykazuje wysoką wrażliwość na zmiany gęstości helowej, co stwierdzono na podstawie badania martwej przestrzeni ampułki w której umieszczono próbkę. Wnioskować stąd można, że rozmiar ziaren węgla w dużym stopniu wpływa na charakterystyki sorpcyjne węgla, w tym także na chłonność sorpcyjną i histerezy desorpcji dla CO2 i CH4, zwłaszcza w badaniach na węglu suchym. W trakcie badań próbki węgla z ziarnami o wymiarach 150-212 μm (150 μm) wykazywały wyższą chłonność sorpcyjną, w dalszej kolejności plasowały się próbki o wymiarach ziaren: 2.36-3.35 mm (2.4 mm), 8-9.5 mm (8 mm) i 16-19 (16 mm). Jednakże różnice pomiędzy różnymi ziarnami węgla stawały się mniej wyraźne gdy izotermy sorpcji obliczane były w odniesieniu do próbki suchej, pozbawionej popiołu. Badania próbek o wymiarach ziaren 150 μm wykazały, że w ich przypadku histereza desorpcji jest stosunkowo mniejsza w porównaniu z próbkami gruboziarnistymi. Wszystkie wyniki: izotermy adsorpcji i desorpcji, parametry Langmuira oraz histerezy węgla badano przy użyciu dwóch gazów: CO2 i CH4.
Źródło:
Archives of Mining Sciences; 2014, 59, 3; 807-820
0860-7001
Pojawia się w:
Archives of Mining Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of quinoline from aqueous solutions by lignite, coking coal and anthracite. Adsorption isotherms and thermodynamics
Autorzy:
Xu, H.
Huagn, G.
Li, X.
Gao, L.
Wang, Y.
Powiązania:
https://bibliotekanauki.pl/articles/110016.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
quinoline adsorption
coking coal
adsorption isotherms
thermodynamics
Opis:
Based on the concept of circular economy, a novel method of industrial organic wastewater treatment by using adsorption on coal is introduced. Coal is used to adsorb organic pollutants from coking wastewaters. After adsorption, the coal would be used for its original purpose, its value is not reduced and the pollutant is thus recycled. Through systemic circulation of coking wastewater zero emissions can be achieved. Lignite, coking coal and anthracite were used as adsorbents in batch experiments. The quinoline removal efficiency of coal adsorption was investigated. The coking coal and anthracite exhibited properties well-suited for adsorption onto both adsorbents. The experimental data were fitted to Langmuir and Freundlich isotherms as well as Temkin, Redlich–Peterson (R-P) and Dubinin-Radushkevich (D-R) models. Both Freundlich Isotherm and D-R model provided reasonable models of the adsorption process. The thermodynamic parameters of quinoline adsorption on coking coal were calculated. The thermodynamic parameters indicated that the adsorption process is exothermic and is a physical adsorption. The △S° value indicated that the adsorption entropy decreased because the adsorbate molecule was under restrictions after it adsorption on the coal surface. The coal adsorption method for removing refractory organic pollutants is a great hope for achieving zero emission waste water for a coking plant.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 214-227
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Heterocoagulation of hydrophobized particulates by ionic surfactants
Autorzy:
Çelik, M.
Ozdemir, O.
Powiązania:
https://bibliotekanauki.pl/articles/110782.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
heterocoagulation
coal
flotation
adsorption
ionic surfactants
Opis:
Hydrophobic particulates, i.e. bubbles, precipitates, and coal particles are shown to exhibit similar isoelectric point (iep) values in the presence of ionic surfactants. While coal in anionic surfactant solutions exhibits negative zeta potentials in the entire pH region, coal in cationic surfactant solutions undergoes a charge reversal in alkaline pH. Adsorption and zeta potential measurements together with previously published results indicate that ionic surfactants adsorb on coal through hydrophobic bonding driven by entropy. Physicochemical similarities in the adsorption mechanisms of ionic surfactants onto the bubbles, precipitates, and coal particles are proposed to be responsible for the observed iep values and also heterocoagulation phenomena.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 1; 124-130
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of the degree of polymerization of nonylphenol polyoxyethylene ether on the dewatering of low-rank coal
Autorzy:
Li, Lin
He, Meng
Liu, Mingpu
Lin, Mengyu
Hu, Shanpei
Yu, Hao
Wang, Qingbiao
You, Xiaofang
Powiązania:
https://bibliotekanauki.pl/articles/1449205.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
low-rank coal
NPEO
dewatering
adsorption
long-flame coal
Opis:
In this study, we investigated the effect of the hydrophilic ethylene oxide chain lengths (i.e., degree of polymerization) of nonylphenol polyoxyethylene ether (NPEO-x, x = 8, 10, and 12) on the dewatering of low-rank coal slime through dewatering and adsorption experiments and X-ray photoelectron spectroscopy (XPS) measurements. The dewatering experiments showed that the adsorption of NPEO changed the water content of the low-rank coal slime: NPEO-8 achieved the best effect, followed, in decreasing order, by NPEO-10 and NPEO-12. Adsorption experiments revealed that the adsorption isotherms of NPEO-x on the low-rank coal surface conform with the Langmuir model, and its adsorption kinetics follow the pseudo-second-order kinetic equation. Furthermore, the adsorption is a spontaneous process and controlled by both intraparticle diffusion and liquid film diffusion. The XPS results showed that the adsorption of NPEO-x decreased the content of oxygencontaining groups and, thus, improved the hydrophobicity of the low-rank coal surface. Further, the use of NPEO-x with a low degree of polymerization (x = 8) improves the hydrophobicity of the coal surface and decreases the water content of low-rank coal slime.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 4; 723-736
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selective adsorption of anionic polyacrylamide onto ultra-low ash coal and kaolinite
Autorzy:
Zou, W.
Yu, C.
Sun, C.
Cao, Y.
Powiązania:
https://bibliotekanauki.pl/articles/109333.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
coal
kaolinite
anionic polyacrylamide
adsorption
flotation
Opis:
To study the selectivity of polyacrylamide in the selective floc flotation of fine coal, adsorption of anionic polyacrylamide (PAM A401) onto ultra-low ash coal and kaolinite was studied, including the adsorption thermodynamics, floc size distribution and wettability changes. The thermodynamics of the adsorption process at the low concentration of 0-16 mg/dm3 of PAM A401 were studied at different contact times, doses, temperatures and pH values. Thermodynamic parameters of ΔGo, ΔHo, ΔSo and Ea were evaluated to understand the nature of the adsorption process. The results indicated that PAM A401 was selectively adsorbed onto ultra-low ash coal rather than kaolinite. Physical adsorption was the predominant mechanism, and the adsorption of PAM A401 at 12 mg•dm-3 onto coal was 2.15-fold larger than the adsorption on kaolinite. After the adsorption of PAM A401, the lipophilic hydrophilic ratio (LHR) of coal decreased from 9.23 to 7.28, indicating that the coal became less hydrophobic than before. In contrast, the LHR of kaolinite increased from 1.44 to 1.65. Floc size measurements showed that the d10, d50 and d90 of coal flocculated by PAM A401 (at 12 mg/dm3, pH 6.5) were 3.18, 2.76 and 2.59-fold greater than the corresponding levels of these parameters for kaolinite flocs, respectively.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 738-753
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption behavior and XPS analysis of nonylphenol ethoxylate on low rank coal
Autorzy:
You, Xiaofang
Ma, Chuandong
Li, Zhihao
Lyu, Xianjun
Li, Lin
Powiązania:
https://bibliotekanauki.pl/articles/109627.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
low rank coal
nonylphenol ethoxylate
adsorption isotherm
adsorption kinetics
XPS
Opis:
In this work, low rank coal was used for the removal of nonylphenol ethoxylate with fifteen ethylene oxide groups (NPEO15) from aqueous solutions at different contact times, temperatures, and initial adsorbent concentrations. The adsorption isotherms showed good fit with the Langmuir equation. Maximum adsorption capacities calculated at 308, 318, and 328 K were 23.64, 29.41, and 35.71 mg g–1, respectively. The changes in the free energy of adsorption (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) were calculated in order to predict the nature of adsorption. The results of the thermodynamic analysis indicated that a spontaneous process took place, driven synergistically by both enthalpy and entropy. The adsorption kinetics of NPEO15 were consistent with a pseudo-second order reaction model. XPS results showed that the oxygen functional groups on the low rank coal surface were significantly covered by NPEO15. Furthermore, while the content of C–C/C–H functional groups increased significantly, that of C–O functional groups decreased after absorption. These results clearly indicate that low rank coal is more hydrophobic and displays better floatability.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 3; 721-731
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetic research of quinoline, pyridine and phenol adsorption on modified coking coal
Autorzy:
Sun, X.
Xu, H.
Wang, J.
Ning, K.
Huang, G.
Yu, Y.
Ma, L.
Powiązania:
https://bibliotekanauki.pl/articles/110365.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adsorption kinetics
modification
coking coal
coking wastewater
Opis:
Adsorption is widely used in wastewater treatment. In this work, the removal of quinoline, pyridine and phenol from coking wastewater by using modified coking coal, which was treated by four different modification methods i.e. acidification sodium hydroxide (5 mol/dm3), hydrochloric acid (5 mol/dm3) and acetic acid (5 mol/dm3) and low-temperature (105 oC) oxidation, was investigated. The modified coal was characterized by the surface area analysis, SEM, total acidity and basicity and FT-IR. The results showed that the surface area from high to low follows the order: modification with acetic acid, modification with hydrochloric acid, raw coal, modification with sodium hydroxide and modification with low-temperature. Experimental data were fitted to pseudo-first-order, pseudo-second-order and intra-particle diffusion. The adsorption of all followed pseudo-second-order kinetics. The result showed that the removal efficiency of coal modified by hydrochloric acid and acetic acid are higher than raw coal, while modified by sodium hydroxide and low-temperature are lower than raw coal., The coal modified by hydroxide acid had the best adsorption capacity.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 965-974
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of saline water on the synergistic interaction between diesel and Triton X-100 in the flotation of oxidized coal
Autorzy:
Chang, Ziyong
Diallo, Lancine
Feng, Bo
Powiązania:
https://bibliotekanauki.pl/articles/1448948.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
saline water
surfactants
adsorption
flotation
coal oxidation
Opis:
In this study, the effect of medium saline water on the synergistic interaction between diesel and Triton X-100 in the flotation of oxidized coal was investigated. The results showed that the flotation yield of oxidized coal in saline water was higher than that in de-ionized (DI) water due to the promotion of diesel adsorption, which was attributed to the screening of electrostatic repulsion between diesel droplets and coal particles in saline water. Meanwhile, the flotation of oxidized coal could be significantly improved when Triton X-100 was added with diesel as a composite collector, and less Triton X-100 was required in saline water than that in DI water to achieve the same true flotation yield, indicating that saline water could increase the effectiveness of Triton X-100 in improving oxidized coal flotation. A mechanism study revealed that Triton X-100 was able to promote diesel adsorption on oxidized coal through emulsification, thus increasing the surface hydrophobicity of oxidized coal through hydrogen bonding between the headgroups of Triton X-100 and the oxygenated groups on coal surfaces. The non-ionic characteristic of Triton X-100 ensured its capability of enhancing oxidized coal flotation in both DI water and saline water.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 216-225
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pretreatment of coking wastewater by an adsorption process using fine coking coal
Autorzy:
Gao, L.
Li, S.
Wang, Y.
Gui, X.
Xu, H.
Powiązania:
https://bibliotekanauki.pl/articles/110417.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
coking coal
coking wastewater
adsorption
COD
phenol
Opis:
A new technique for pretreatment of coking wastewater is introduced based on the concept of circular economy. Coal is fed into a coking system after adsorption. This study validates the feasibility of using coking coal to adsorb organic pollutants in coking wastewater. The sorption kinetics and equilibrium sorption isotherms of coking coal for removal of chemical oxygen demand (COD) and phenol from coking wastewater was also discussed in this paper. Gas chromatograph/mass spectroscopy (GC/MS) was used to detect changes in the quality of coking wastewater. The results showed that when coking coal dosage was 120 g/dm3, 65% of COD and 34% of phenol in waste water can be removed after 40 min of agitation. The surface functional groups of coking coal before and after adsorption were observed with a Fourier transform infrared spectrometer. The kinetics of COD and phenol adsorption from coking wastewater by coking coal fitted the pseudo second-order model. The adsorption process of coking coal can be classified into two categories, namely, rapid and slow. The Freundlich isotherm provided a better fit with all adsorption isotherms than the Langmuir isotherm. Coking coal could be a suitable low-cost adsorbent for recalcitrant organic pollutants.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 422-436
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on emulsified tyre pyrolysis oil as a coal flotation collector
Autorzy:
Yang, R.
Shen, L.
Wang, H.
Powiązania:
https://bibliotekanauki.pl/articles/109341.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
pyrolysis oil
coal flotation
contact angle
interaction heat
adsorption
Opis:
In this paper the possibility of using the pyrolysis oil derived from waste tyres as a collector in flotation of coal was evaluated. The pyrolysis oil was obtained at the initial and final pyrolysis temperatures of 400 and 700 oC, respectively, and the heat holding time of 30 min. Flotation results indicated that the pyrolysis oil emulsion showed stronger collecting ability than diesel and the concentrate ash content just slightly increased in comparison to flotation in the presence of diesel. The contact angle measurement and immersion microcalorimetry test correlated well with the flotation data. The Fourier Transform Infrared Spectroscopy results demonstrated that diesel and pyrolysis oil emulsion is physically adsorbed on the coal surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 1; 279-287
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hydrocarbons removal from underground coal gasification water by organic adsorbents
Autorzy:
Lutynski, M.
Suponik, T.
Powiązania:
https://bibliotekanauki.pl/articles/110448.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
underground coal gasification
permeable reactive barrier
Langmuir adsorption isotherm
Opis:
The main problems in the case of the undergorund coal gasificiation process is the possible pollution of surrounding aquifers. The underground gasification cavity is a source of both gaseous and liquid pollutants and these are mainly aromatic hydrocarbons, phenols, heavy metals and others. In order to prevent underground water from pollution a permeable reactive barrier was proposed. The filling was granulated activated carbon and SPILL-SORB (peat) – two commonly available sorbents adequate for hydrocarbons removal. The wastewater (synthetic solution which simulated groundwater contaminated with the UCG products) was prepared by mixing distilled water with desired amounts of substances such as phenols, benzene, toluene, xylene, naphthalene etc. Batch tests were performed in order to measure sorption of phenols and benzene from the post-UCG water on the mentioned sorbents. Experimental results were fitted with linear and non-linear Freundlich and Langmuir isotherm models. The obtained data showed that removal of phenols and benzene in case of GAC was much more efficient. However, sorption was lower than in the case of literature data and can be explained by complex composition of the solution and pre-treatment of the samples. The Langmuir model gave a better fit in the case of GAC, whereas Freundlich isotherm model was matching the data better in case of SPILL-SORB.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 1; 289-298
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Coalification as a process determining the methane adsorption ability of coal seams
Autorzy:
Dutka, Barbara
Godyń, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/1853877.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
metan
petrografia
adsorpcja
coal bed methane
degree of coalification
petrography
adsorption capacity
Opis:
The paper presents the results of a study of methane adsorption on coal samples with various degrees of metamorphism, coming from the Polish and Czech parts of the Upper Silesian Coal Basin (USCB). The range of coalification of the samples was from bituminous with vitrinite reflectance Ro equal to about 0.5% to para-anthracite coals with Ro equal to over 2%. The methane adsorption capacity was determined at the temperature 303 K for each of the studied coal seams. Methane adsorption isotherms were approximated using the Langmuir model. The relationship between the Langmuir isotherm parameters (am and PL) and the degree of coalification was presented. It was shown that the degree of coalification of the coal substance affects the adsorption ability of coal with respect to methane and determines the value of the Langmuir isotherm parameters. The study was conducted in order to present the distribution of adsorption capacity of Upper Silesian coals in relation to improving work safety in active mines as well as designing technologies that use coal bed methane (CBM) from balance and off-balance resources.
Źródło:
Archives of Mining Sciences; 2021, 66, 2; 181-195
0860-7001
Pojawia się w:
Archives of Mining Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Enhancing low-rank coal flotation using a mixture of dodecane and n-valeraldehyde as a collector
Autorzy:
Liu, Zechen
Liao, Yinfei
An, Maoyan
Lai, Qingteng
Ma, Longfei
Qiu, Yuliang
Powiązania:
https://bibliotekanauki.pl/articles/109432.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
mixed collector
oxygen-containing functional groups
adsorption mechanism
low rank coal
flotation
Opis:
Low-rank coals are difficult to float using common hydrocarbon oily collectors, such as dodecane and diesel. In this investigation, a mixture of dodecane and n-valeraldehyde was used as a collector to enhance low-rank coal flotation. The changes of the contact angle and surface functional groups of low-rank coal were measured before and after different collectors’ adsorption to indicate its absorption mechanism. Surface tension of different collectors was also measured to identify its spreading performance. The results showed that the flotation performance using the mixture as a collector was much better than that using dodecane or n-valeraldehyde solely. When used the mixture of dodecane and n-valeraldehyde as collector, dodecane primarily covers the hydrophobic sites while n-valeraldehyde primarily covered the hydrophilic sites by hydrogen bond promoting adsorption of dodecane at these sites. There existed synergistic effect between dodecane and n-valeraldehyde. Additionally, n-valeraldehyde can reduce the surface tensions to improve the spreading performance of mixed collector on low-rank coal surface. The improvement both in adsorption and spreading was responsible for the enhancement of low-rank coal flotation by using the mixture.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 49-57
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of the oxygen-containing functional group on the adsorption of hydrocarbon oily collectors on coal surfaces
Autorzy:
Wan, He
Hu, Xianglin
Luukkanen, Saija
Qu, Juanping
Zhang, Chonghui
Xue, Jiwei
Li, Hui
Yang, Wei
Yang, Shenghong
Bu, Xianzhong
Powiązania:
https://bibliotekanauki.pl/articles/2146920.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
oxygen-containing functional groups
hydrocarbon oily collectors
molecular dynamics simulation
coal surfaces
adsorption
Opis:
The oxygen-containing functional groups (OCFG) on the coal surface affect the adsorption effect of hydrocarbon oily collectors (HOC). An investigation of the interaction between the HOC and OCFG in the absence and presence of water is conducive to understanding the effect of OCFG type on the adsorption of HOC on the coal surface. In this paper, FTIR analysis was used to analyze the OCFG type of coal surface. The adsorption behavior of HOC on different OCFG surfaces was investigated using molecular dynamics simulation. The results indicated the presence of OCFG such as -OH, -COOH, -C=O, and -COCH3 on the coal surface. In conditions without water, the effect of OCFG on HOC adsorption capability follows the order -COOH > -C=O > -OH > -COCH3. In an aqueous solution, the effect of OCFG on HOC adsorption capability follows the order -C=O>-COCH3>-OH>-COOH. Moreover, the hydrophilicity of OCFG is the key factor that affects the adsorption effect of HOC. In other words, the adsorption effect of HOC on the coal surface in an aqueous solution does not depend on the strength of the interaction between the OCFG and HOC in the absence of water, but on the hydrophilicity of the OCFG. The -COOH and -OH on the coal surface are not conducive to the adsorption of HOC onto the coal surface. Masking the -COOH and -OH of the coal surface is beneficial in improving the coal flotation performance with HOC as a collector.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 149937
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 23

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