The results of investigations on the microstructure of T23 and T24 low-alloy steels as well as P91 and P92 high-chromium steels in the as-received condition and after 70.000 h annealing at 550-650°C are presented. The quantitative analysis of the existing precipitates was performed for representative images of microstructure. The statistical analysis of collected data allowed the parameters of a selected theoretical statistical distribution to be estimated. A forecast of average precipitate diameter and standard deviation of such a distribution for the time of 100,000 hours at 550 and 600°C for T23 and T24 steels and at 600 and 650°C for P91 and P92 steels was calculated. The obtained results of investigations have made it possible to compare changes in the microstructure of various steel grades due to long-term impact of elevated temperature. They have also confirmed the possibility of using, in evaluating the degradation degree of materials in use, the forecasting methods that derive from mathematical statistics, in particular the theory of stochastic processes and forecast by analogy methods. The presented approach allows the development of a forecast of precipitate diameter probability density under the microstructure instability conditions for selected steel grades. The assessment of material condition that takes into consideration, but is not limited to, the precipitate diameter measurement is useful as an assessment component in estimating the time of safe service of power unit elements working under creep conditions.
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