The Ni-Al-Hf Multiphase Diffusion

The generalized Darken method was applied to simulate the diffusion between γ-Ni| γ’-Ni₃Al and γ’-Ni₃Al|β-NiAl interfaces. The results of calculations were compared with the experimental concentration’s profiles of nickel, aluminum and hafnium in aluminide and hafnium doped aluminide coatings deposited by the CVD and PVD methods on pure nickel. The method deals with the Wagner’s integral diffusion coefficients and thermodynamic data - activities of components. The experimental results agree with the simulated ones.