Effect of Additives on the Densification Processes and Properties of Silica-Based CMCs

The effect of additives on the densification behavior and mechanical properties of pure and additive (Zr, B and Mg)-added silica ceramics were investigated for their application to the matrix phase of a silica fiber reinforced silica (SiO₂ /SiO_2f ) composite. The additives affected the rate of densification and crystallization (or transformation) of the amorphous silica. Among the compositions, pure silica ceramics sintered at 900°C for 1h showed the maximum flexural strength. Based on the results, SiO₂ /SiO_2f was fabricated by a repeated vacuum-assisted infiltration method followed by the heat treatment at 900°C for 1h. The relative density of the composite was 78.2% with a flexural strength of 22.4 MPa. Fractography revealed that the composite was damaged by strong bonding at the fiber/matrix interface and the fracture of fiber.