This paper presents results of the research on the efficiency of the Diesel engines of the fleet vehicles fed with the new type of second-generation biofuel BIOXDIESEL at non-stationary and stationary conditions and natural operation on roads. The BIOXDIESEL fuel used for the laboratory testing of physical and chemical properties, engine tests and natural road operation, which is a blend of fatty acid ethyl esters (FAEE) obtained from the waste vegetable and animal fats, bioethanol and Diesel fuel. For the testing, several different types of vehicles have been used: passenger vehicles, small parcel delivery vans, agriculture machines and heavy trucks used for long distance international transport. The results of the vehicles engines testing in non-stationary conditions, results of measurement engines performance on vehicle test bed and results of natural road operation on roads of the vehicles used for testing indicate quasi-identical efficiency of the engines, which were fueled with BIOXDIESEL fuel and standard Diesel. The paper also presents results of initial research, which indicates the direction of future research, which is related to increase the calorific value of the biofuels, which may be obtained by replacement of used bioethanol with the heavier alcohols of renewable resources. Physical and chemical properties of the heavier alcohols indicate the possibility to use them as an additive to the biofuels. The paper presents also results of initial engine tests with a blend of the fuel with different heavier alcohols.
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