Valence Band Electronic Structure of HgMSe (M=Mn, Fe, Co)

The synchrotron radiation in the energy range between 40 and 80 eV was applied to investigate the electronic structure of Hg$\text{}_{0.7}$Mn$\text{}_{0.3}$Se, Hg$\text{}_{0.88}$Fe$\text{}_{0.12}$Se and Hg$\text{}_{0.93}$Co$\text{}_{0.07}$Se crystals by means of the resonant photoemission spectroscopy. The set of energy distribution curves was measured in the region near the M (M = Mn 3d$\text{}^{5}$, Fe 3d$\text{}^{6}$, Co 3d$\text{}^{7}$) 3p-3d transitions. In order to determine thoroughly the Fano type resonance energy the constant initial states curves were measured.