Występowanie substancji chloroorganicznych w wodzie po procesie utleniania oraz możliwości ich analizy

Chromatographic analysis GC makes several problems during optimisation and separation of analysed substances. Programming of temperature increase,temperature of feeder and temperature of detector are the most common problems. Than it is neccesary to take into consideration other factors, which will have significant impact on retention time, selectivity of separation of analysed compounds or retention index. The chosen results of the research into the influence of various oxidants on forms and quantity of the occurrence of THM, MX-THAT and the Purgeable Halogenoacetic acids in drinking water have been presented in this paper. As a result of conducted research the influence of chemical composition of water, a dose and a sort of applied oxidant on the quantity of the formed chlororganic substances has been shown. It also has been shown that these substances are also formed as a result of oxidation with compounds not containing chlorine.According to the form of the occurring chlororganic compounds and their concentrationafter hydrogen dioxide oxidation, various toxic compounds are possible to beformed. They are cancerogenic and mutagenic ones. The concentration of by-products of oxidation depends on the presence anda sort of precursors, a sort of disinfectant, temperature, season, time of contact and reactionof solution. The kinds and quantity of oxidation by-products also depend on a kindof oxidant and the concentration of the catalyst. Such catalysts in natural waters areinorganic compounds. The capabilities of their quantification using gas chromatographyhave also been presented.Analysis of real samples showed high repeatability and accuracy of conducteddeterminations. Such analysis required accurate sample purification and comparison ofthree extractants because of high concentration of high molecular substances (fulvic acids).