Badania procesu mokrego rozdrabniania mączki kamienia wapiennego oraz wpływu rozdrobnienia na efektywność odsiarczania spalin

Rozdrabnianie jest jedną z operacji jednostkowych często stosowanych w wielu gałęziach przemysłu chemicznego, przemysłu energetycznego, spożywczego, kosmetycznego, farmaceutycznego i innych. Ze względów procesowych cząstki są rozdrabniane do tysięcznych części milimetra, przy czym uzyskanie zdefiniowanego rozkładu ziarnowego surowca ma swe odzwierciedlenie w jakości otrzymanego produktu, w jego właściwościach, jak również wpływa na sposób prowadzenia procesu [1÷4].

One of the interesting areas of uses wet grinding process are reactions with solid sorbent, e.g. as in case of wet process flue gas desulfurization where grinding level influence on sorbent reactivity. The results of researches of wet grinding process and influence of grinding level of lime stone on its reactivity in wet desulfurization process have been introduced in the article. The researches of wet grinding process in hybrid mixer with two eccentric agitators: disc and hybrid paddle agitator have been carried on. Both of equations of energy transmission coefficient and of elementary work ofwet grinding process of lime stone in mixer with two eccentric agitators which the best describes according to Kick's assumptions with constant CK=6175,87 m2/s2 have been developed (1). Whereas the process of wet grinding has been described by equation which enable qualifying the indispensable time of wet grinding for set grinding level: The energy transmission coefficient can be determinate from criterion equation: Size reductions amount of do32/d32=44,08/1,26=35 bring about 5,5 times growth of lime stone suspension reactivity have been obtained during research. Thanks to growth of sorbent reactivity the decrease of thickness of spraying as well as circulation ratio of suspension in absorber in typical installation of desulfurization with capacity of 2100000 Nm3/h is possibility to get. Such situation gives an opportunity to disconnect one of the circulation pump which allowed to save about 900kW energy and in theyear about 2500 t of standard energetic carbon.