Influence of Temperature on Critical Fields in $Zn_{x}Sb_{y}Cr_{z}Se_{4}$

The electrical and complex ac dynamic magnetic susceptibility measurements were used to study an influence of temperature on critical fields in single-crystalline $Zn_{x}Sb_{y}Cr_{z}Se_{4}$ spinel system with y = 0.11, 0.16 and 0.20. The p-type conduction and a shift both of the Néel temperature $T_{N}$ to lower temperatures and a susceptibility peak at $T_{m}$ in the paramagnetic region - to higher temperatures were established. Below $T_{N}$ the magnetic field dependence of susceptibility, $χ_{ac}(H)$, shows two peaks. First peak at the critical field $H_{c1}$ slightly decreases with temperature and remains almost constant as Sb content increases. Second peak at the critical field $H_{c2}$ drops rapidly with temperature and remains almost unchanged as Sb content increases. At $T_{N}$ both critical fields disappear.