Both plants and animals in the process of evolution gained the ability to produce
compounds that affect their existence in the wild. These compounds may
affect the organisms producing them, and may also be used by completely different
individuals. Among huge number of molecules characterized by extremely essential
features are, among others, ionones and their derivatives. Ionones are ketones
composed of 13 carbon atoms. They are found in many essential oils being the
products of degradation of carotenoids. Both they and their structural analogues
can play various biological functions such as being deterrent to other individuals
or, conversely, atractant. Compounds found in plants, containing like ionone carbon
skeleton, and having in their structure additional hydroxyl groups or epoxide ring
(4)–(23) often exhibit allelopathic activity [1–15] (Fig. 2–5). Marine animals may
in turn use them as ichtyotoxic compounds (27) and (28) [19] (Fig. 7). A compound
called luciferin Latia (29) is responsible for the bioluminescent properties of marine
snail [20] (Fig. 8). Plants used for centuries in traditional folk medicine of different
countries are a source of glycoside derived α- and β-ionone (37)–(55) [22–31]
(Fig. 11–14). These compounds may also be used in modern medicine, inter alia,
in the regulation of neurodegenerative diseases or for the treatment of osteoporosis.
Because of the potential biological properties of structural analogs of ionones
they are also obtained by chemical synthesis (56)–(69) [32–39] (Fig. 15–18) or
biotransformation (70)–(89) [40–47] (Fig. 19–25), and then subjected to careful
examination of their biological activities. By applying these methods we can also
obtain a molecules whose acquisition from natural sources is unprofitable. We have
received such derivatives which have no counterpart in nature.
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