Study of Magnetic and Structural Properties of Non-Stoichiometric NiZn Ferrites Prepared by Wet Method

An iron-deficient $(Ni_{0.33}Zn_{0.67})_{1 + x}Fe_{2 - x}O_4$ and stoichiometric $Ni_{0.45}Zn_{0.55}Fe_2O_4$ prepared by a wet method were studied using the Mössbauer spectroscopy and thermomagnetic measurements. For the iron-deficient sample the $T_{C}$ is twice as large and the temperature coefficient of initial permeability is two orders of magnitude lower in comparison with the stoichiometric samples. The results are supplemented by the frequency dependence of the complex permeability.