Mechanical Alloying of $Al_{73}Cu_{11}Cr_{16}$ Alloy from Ion Irradiated Powders

$Al_{73}Cu_{11}Cr_{16}$ alloys were prepared by mechanical alloying of the irradiated by $Ar^{+}$ ions elemental powders. Evolution of alloy structure at ball milling, as well as during the further annealing, was investigated using X-ray diffraction and differential scanning calorimetry. It was shown that ball milling leads to the Cu dissolution in Al and Cr and to the formation of $Al_{2}Cu$ intermetallic phase. An increase of the milling duration leads to an increase of the $Al_{2}Cu$ phase content in the samples. Ion irradiation of initial elemental powders results in an increase of their interaction rate at milling. In the case of irradiated powders using as initial materials, a content of $Al_{2}Cu$ phase after milling is higher than in the case of using non-irradiated elemental powders. No effect of irradiation of initial elemental powders on the phase transformation at heating was observed. The annealing results in the decomposition of Al- and Cr-based supersaturated solid solutions. An increase in the $Al_{2}Cu$ phase content at heating was observed only in the samples, which were milled for 4 h. In the samples milled for 14 h, nearly no increase in $Al_{2}Cu$ phase content at heating was observed. Heating up to 500-600°C results in the single-phase decagonal quasicrystalline phase formation for all of the studied samples.