Municipal WWTPs often receive industrial wastewater including the bakery sewage. The effluent of the bakery industry has a high biological oxygen demand (BOD). In addition to high BOD, this wastewater contains high chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN) and is characterized by a dark color. The effect of bakery wastewater contribution on the COD fraction changes in the municipal sewage is presented in this paper. The study was conducted in July 2016 in a WWTP located in Lipsk, East-North Poland. The sewage receiver is the Biebrza River. The volume contribution of bakery wastewater is 10%. The analytical results were used to compute the percentage value contribution of individual COD fractions in wastewater. During the study, the following fractions were identified: SS – COD of readily-biodegradable dissolved organic matter, SI – COD of non-biodegradable dissolved organic matter, XS – COD of slowly-biodegradable non-soluble organic matter, XI – COD of non-biodegradable non-soluble organic matter. The method used for the COD fraction determination in wastewater was developed based on the ATV 131P guidelines (ATV-DVWK-A131P). The aim of the study was to determine the effect of bakery wastewater contribution on the COD fraction changes during the technical scale biological wastewater treatment with an activated-sludge process. The percentage contributions of individual COD fractions in wastewater were compared with the shares in the wastewater from other food industries (dairy, olive mill, tomato, sugar beet, potato processing, winery). In raw wastewater, the XS fraction was dominant 44.2%. SS fraction was 38.8%. In raw wastewater, the SI, XI fractions ranged from 2.3 to 14.8%. In the effluent the SS fraction was not noted, which is indicative of microorganisms consumption. The WWTP effluents mostly (43.4%) contained slowly-biodegradable non-soluble organic matter (XS). Non-biodegradable dissolved organic matter (SI fraction) had a high share of 42.3%.
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