AlCrFeCuCoNi high entropy particles were alloyed on Ti-6Al-4V surface using Plasma transferred arc (PTA) process. PTA alloyed surfaces were investigated for their phase formation, microhardness improvement and wear behaviour. The various wear mechanism and their corresponding surface roughness were studied. The results revealed that the dual phase of BCC and FCC microstructure along with some intermetallic compounds were grown in the alloyed region through the PTA technique and good metallurgical bonding of the alloyed region with the base material were achieved. The PTA alloyed region exhibited a hardness of 718 HV0.2 which is 2.2 times higher than the hardness of base material. The PTA alloyed samples showed higher wear resistance due to the solid solution strengthening as the HEA has high entropy of mixing that leads to the reduction of free energy of the alloyed region. It exhibited better interconnection of the coated material and superior metallurgical bonding to the base material. Frictional heat produced during the wear test has promoted the formation of FeO, Cr2O3, CuO, NiO and Al2O3 oxide film on the PTA alloyed sample. These oxide films act as a barrier between two mating surfaces and improve the tribo performance of the PTA alloyed sample.
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